Potential temperature
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The potential temperature of a parcel of fluid at pressure P is the temperature that the parcel would attain if
adiabatically Adiabatic (from ''Gr.'' ἀ ''negative'' + διάβασις ''passage; transference'') refers to any process that occurs without heat transfer. This concept is used in many areas of physics and engineering. Notable examples are listed below. A ...
brought to a standard reference pressure P_, usually . The potential temperature is denoted \theta and, for a gas well-approximated as
ideal Ideal may refer to: Philosophy * Ideal (ethics), values that one actively pursues as goals * Platonic ideal, a philosophical idea of trueness of form, associated with Plato Mathematics * Ideal (ring theory), special subsets of a ring considered ...
, is given by : \theta = T \left(\frac\right)^, where T is the current absolute
temperature Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measured with a thermometer. Thermometers are calibrated in various temperature scales that historically have relied o ...
(in K) of the parcel, R is the gas constant of air, and c_p is the
specific heat In thermodynamics, the specific heat capacity (symbol ) of a substance is the heat capacity of a sample of the substance divided by the mass of the sample, also sometimes referred to as massic heat capacity. Informally, it is the amount of heat t ...
capacity at a constant pressure. R/c_p = 0.286 for air (meteorology). The reference point for potential temperature in the ocean is usually at the ocean's surface which has a water pressure of 0 dbar. The potential temperature in the ocean doesn't account for the varying heat capacities of seawater, therefore it is not a conservative measure of heat content. Graphical representation of potential temperature will always be less than the actual temperature line in a temperature vs depth graph.


Contexts

The concept of potential temperature applies to any stratified fluid. It is most frequently used in the
atmospheric sciences Atmospheric science is the study of the Earth's atmosphere and its various inner-working physical processes. Meteorology includes atmospheric chemistry and atmospheric physics with a major focus on weather forecasting. Climatology is the study ...
and
oceanography Oceanography (), also known as oceanology and ocean science, is the scientific study of the oceans. It is an Earth science, which covers a wide range of topics, including ecosystem dynamics; ocean currents, waves, and geophysical fluid dynami ...
. The reason that it is used in both fields is that changes in pressure can result in warmer fluid residing under colder fluid – examples being dropping air temperature with altitude and increasing water temperature with depth in very deep ocean trenches and within the ocean mixed layer. When the potential temperature is used instead, these apparently unstable conditions vanish as a parcel of fluid is invariant along its isolines. In the oceans, the potential temperature referenced to the surface will be slightly less than the in-situ temperature (the temperature that a water volume has at the specific depth that the instrument measured it in) since the expansion due to reduction in pressure leads to cooling. The numeric difference between the in situ and potential temperature is almost always less than 1.5 degrees Celsius. However, it's important to use potential temperature when comparing temperatures of water from very different depths.


Comments

Potential temperature is a more dynamically important quantity than the actual temperature. This is because it is not affected by the physical lifting or sinking associated with flow over obstacles or large-scale atmospheric turbulence. A parcel of air moving over a small mountain will expand and cool as it ascends the slope, then compress and warm as it descends on the other side- but the potential temperature will not change in the absence of heating, cooling, evaporation, or condensation (processes that exclude these effects are referred to as dry adiabatic). Since parcels with the same potential temperature can be exchanged without work or heating being required, lines of constant potential temperature are natural flow pathways. Under almost all circumstances, potential temperature increases upwards in the atmosphere, unlike actual temperature which may increase or decrease. Potential temperature is conserved for all dry adiabatic processes, and as such is an important quantity in the planetary boundary layer (which is often very close to being dry adiabatic). Potential temperature is a useful measure of the static stability of the unsaturated atmosphere. Under normal, stably stratified conditions, the potential temperature increases with height, : \frac > 0 and vertical motions are suppressed. If the potential temperature decreases with height, :\frac < 0 the atmosphere is unstable to vertical motions, and
convection Convection is single or multiphase fluid flow that occurs spontaneously due to the combined effects of material property heterogeneity and body forces on a fluid, most commonly density and gravity (see buoyancy). When the cause of the c ...
is likely. Since convection acts to quickly mix the atmosphere and return to a stably stratified state, observations of decreasing potential temperature with height are uncommon, except while vigorous convection is underway or during periods of strong
insolation Solar irradiance is the power per unit area ( surface power density) received from the Sun in the form of electromagnetic radiation in the wavelength range of the measuring instrument. Solar irradiance is measured in watts per square metre ...
. Situations in which the equivalent potential temperature decreases with height, indicating instability in saturated air, are much more common. Since potential temperature is conserved under adiabatic or isentropic air motions, in steady, adiabatic flow lines or surfaces of constant potential temperature act as streamlines or flow surfaces, respectively. This fact is used in
isentropic analysis Isentropic analysis in meteorology is a technique to find the vertical and horizontal motion of airmasses during an adiabatic process above the planetary boundary layer. The change of state of air parcels following isentropic surfaces does not inv ...
, a form of synoptic analysis which allows visualization of air motions and in particular analysis of large-scale vertical motion.


Potential temperature perturbations

The
atmospheric boundary layer In meteorology, the planetary boundary layer (PBL), also known as the atmospheric boundary layer (ABL) or peplosphere, is the lowest part of the atmosphere and its behaviour is directly influenced by its contact with a planetary surface. On Ear ...
(ABL) potential temperature perturbation is defined as the difference between the potential temperature of the ABL and the potential temperature of the free atmosphere above the ABL. This value is called the potential temperature deficit in the case of a
katabatic A katabasis or catabasis ( grc, κατάβασις, from "down" and "go") is a journey to the underworld. Its original sense is usually associated with Greek mythology and Classical mythology more broadly, where the protagonist visits the Gree ...
flow, because the surface will always be colder than the free atmosphere and the PT perturbation will be negative.


Derivation

The
enthalpy Enthalpy , a property of a thermodynamic system, is the sum of the system's internal energy and the product of its pressure and volume. It is a state function used in many measurements in chemical, biological, and physical systems at a constant ...
form of the first law of
thermodynamics Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws ...
can be written as: : dh = T \, ds + v \, dp, where dh denotes the
enthalpy Enthalpy , a property of a thermodynamic system, is the sum of the system's internal energy and the product of its pressure and volume. It is a state function used in many measurements in chemical, biological, and physical systems at a constant ...
change, T the temperature, ds the change in
entropy Entropy is a scientific concept, as well as a measurable physical property, that is most commonly associated with a state of disorder, randomness, or uncertainty. The term and the concept are used in diverse fields, from classical thermodyna ...
, v the specific volume, and p the pressure. For adiabatic processes, the change in entropy is 0 and the 1st law simplifies to: : dh = v \, dp. For approximately ideal gases, such as the dry air in the Earth's atmosphere, the
equation of state In physics, chemistry, and thermodynamics, an equation of state is a thermodynamic equation relating state variables, which describe the state of matter under a given set of physical conditions, such as pressure, volume, temperature, or intern ...
, pv = RT can be substituted into the 1st law yielding, after some rearrangement: : \frac = , where the dh = c_dT was used and both terms were divided by the product pv Integrating yields: : \left(\frac\right)^ = \frac, and solving for T_, the temperature a parcel would acquire if moved adiabatically to the pressure level p_, you get: : T_0 = T_1 \left(\frac\right)^ \equiv \theta.


Potential virtual temperature

The potential virtual temperature \theta_, defined by : \theta_v = \theta \left( 1 + 0.61 r - r_L \right), is the theoretical potential temperature of the dry air which would have the same density as the humid air at a standard pressure P0. It is used as a practical substitute for density in buoyancy calculations. In this definition \theta is the potential temperature, r is the mixing ratio of water vapor, and r_L is the mixing ratio of liquid water in the air.


Related quantities

The Brunt–Väisälä frequency is a closely related quantity that uses potential temperature and is used extensively in investigations of atmospheric stability.


See also

*
Wet-bulb potential temperature Wet-bulb potential temperature, sometimes referred to as pseudo wet-bulb potential temperature, is the temperature that a parcel of air at any level would have if, starting at the wet-bulb temperature, it were brought at the saturated adiabatic ...
*
Atmospheric thermodynamics Atmospheric thermodynamics is the study of heat-to- work transformations (and their reverse) that take place in the earth's atmosphere and manifest as weather or climate. Atmospheric thermodynamics use the laws of classical thermodynamics, to des ...
*
Conservative temperature Conservative temperature (\Theta) is a thermodynamic property of seawater. It is derived from the potential enthalpy and is recommended under the TEOS-10 standard (Thermodynamic Equation of Seawater - 2010) as a replacement for potential tempera ...
* Equivalent potential temperature


References


Bibliography

* M K Yau and R.R. Rogers, ''Short Course in Cloud Physics, Third Edition'', published by Butterworth-Heinemann, January 1, 1989, 304 pages.


External links


Eric Weisstein's World of Physics
at Wolfram Research {{Meteorological variables Atmospheric thermodynamics Physical oceanography