Period 3 element

A period 3 element is one of the chemical elements in the third row (or period) of the periodic table of the chemical elements. The periodic table is laid out in rows to illustrate recurring (periodic) trends in the chemical behaviour of the elements as their atomic number increases: a new row is begun when the periodic table skips a row and a chemical behaviour begins to repeat, meaning that elements with similar behaviour fall into the same vertical columns. The third period contains eight elements: sodium, magnesium, aluminium, silicon, phosphorus, sulfur, chlorine, and argon. The first two, sodium and magnesium, are members of the s-block of the periodic table, while the others are members of the p-block. All of the period 3 elements occur in nature and have at least one stable isotope.

Atomic structure

In a quantum mechanical description of atomic structure, this period corresponds to the buildup of electrons in the third () shell, more specifically filling its 3s and 3p subshells. There is a 3d subshell, but—in compliance with the Aufbau principle—it is not filled until period 4. This makes all eight elements analogs of the period 2 elements in the same exact sequence. The octet rule generally applies to period 3 in the same way as to period 2 elements, because the 3d subshell is normally non-acting.

Elements

Sodium

''Sodium'' (symbol Na) is a soft, silvery-white, highly reactive metal and is a member of the alkali metals; its only stable isotope is ²³Na. It is an abundant element that exists in numerous minerals such as feldspars, sodalite and rock salt. Many salts of sodium are highly soluble in water and are thus present in significant quantities in the Earth's bodies of water, most abundantly in the oceans as sodium chloride.

Many sodium compounds are useful, such as sodium hydroxide (lye) for soapmaking, and sodium chloride for use as a deicing agent and a nutrient. The same ion is also a component of many minerals, such as sodium nitrate.

The free metal, elemental sodium, does not occur in nature but must be prepared from sodium compounds. Elemental sodium was first isolated by Humphry Davy in 1807 by the electrolysis of sodium hydroxide.

Magnesium

''Magnesium'' (symbol Mg) is an alkaline earth metal and has common oxidation number +2. It is the eighth most abundant element in the Earth's crust and the ninth in the known universe as a whole. Magnesium is the fourth most common element in the Earth as a whole (behind iron, oxygen and silicon), making up 13% of the planet's mass and a large fraction of the planet's mantle. It is relatively abundant because it is easily built up in supernova stars by sequential additions of three helium nuclei to carbon (which in turn is made from three helium nuclei). Due to the magnesium ion's high solubility in water, it is the third most abundant element dissolved in seawater.

The free element (metal) is not found naturally on Earth, as it is highly reactive (though once produced, it is coated in a thin layer of oxide passivation.html" ;"title="Passivation_(chemistry).html" ;"title="ee Passivation (chemistry)">passivation">Passivation_(chemistry).html" ;"title="ee Passivation (chemistry)">passivation which partly masks this reactivity). The free metal burns with a characteristic brilliant white light, making it a useful ingredient in flares. The metal is now mainly obtained by electrolysis of magnesium salts obtained from brine. Commercially, the chief use for the metal is as an alloying agent to make aluminium-magnesium alloys, sometimes called "magnalium" or "magnelium". Since magnesium is less dense than aluminium, these alloys are prized for their relative lightness and strength.

Magnesium ions are sour to the taste, and in low concentrations help to impart a natural tartness to fresh mineral waters.

Aluminium

''Aluminium'' (symbol Al) or ''aluminum'' (American English) is a silvery white member of the boron group of chemical elements and a p-block metal classified by some chemists as a post-transition metal.Huheey JE, Keiter EA & Keiter RL 1993, ''Principles of Structure & Reactivity,'' 4th ed., HarperCollins College Publishers, , p. 28 It is not soluble in water under normal circumstances. Aluminium is the third most abundant element (after oxygen and silicon), and the most abundant metal, in the Earth's crust. It makes up about 8% by weight of the Earth's solid surface. Aluminium metal is too reactive chemically to occur natively. Instead, it is found combined in over 270 different minerals. The chief ore of aluminium is bauxite.

Aluminium is remarkable for the metal's low density and for its ability to resist corrosion due to the phenomenon of passivation. Structural components made from aluminium and its alloys are vital to the aerospace industry and are important in other areas of transportation and structural materials. The most useful compounds of aluminium, at least on a weight basis, are the oxides and sulfates.

Silicon

''Silicon'' (symbol Si) is a group 14 metalloid. It is less reactive than its chemical analog carbon, the nonmetal directly above it in the periodic table, but more reactive than germanium, the metalloid directly below it in the table. Controversy about silicon's character dates from its discovery: silicon was first prepared and characterized in pure form in 1824, and given the name silicium (from la, silicis, flints), with an -ium word-ending to suggest a metal. However, its final name, suggested in 1831, reflects the more chemically similar elements carbon and boron.

Silicon is the eighth most common element in the universe by mass, but very rarely occurs as the pure free element in nature. It is most widely distributed in dusts, sands, planetoids, and planets as various forms of silicon dioxide (silica) or silicates. Over 90% of the Earth's crust is composed of silicate minerals, making silicon the second most abundant element in the Earth's crust (about 28% by mass) after oxygen.

Most silicon is used commercially without being separated, and indeed often with little processing of compounds from nature. These include direct industrial building use of clays, silica sand and stone. Silica is used in ceramic brick. Silicate goes into Portland cement for mortar and stucco, and combined with silica sand and gravel, to make concrete. Silicates are also in whiteware ceramics such as porcelain, and in traditional quartz-based soda-lime glass. More modern silicon compounds such as silicon carbide form abrasives and high-strength ceramics. Silicon is the basis of the ubiquitous synthetic silicon-based polymers called silicones.

Elemental silicon also has a large impact on the modern world economy. Although most free silicon is used in the steel refining, aluminum-casting, and fine chemical industries (often to make fumed silica), the relatively small portion of very highly purified silicon that is used in semiconductor electronics (< 10%) is perhaps even more critical. Because of wide use of silicon in integrated circuits, the basis of most computers, a great deal of modern technology depends on it.

Phosphorus

''Phosphorus'' (symbol P) is a multivalent nonmetal of the nitrogen group, phosphorus as a mineral is almost always present in its maximally oxidized ( pentavalent) state, as inorganic phosphate rocks. Elemental phosphorus exists in two major forms—white phosphorus and red phosphorus—but due to its high reactivity, phosphorus is never found as a free element on Earth.

The first form of elemental phosphorus to be produced (white phosphorus, in 1669) emits a faint glow upon exposure to oxygen – hence its name given from Greek mythology, meaning "light-bearer" (Latin ''Lucifer''), referring to the " Morning Star", the planet Venus. Although the term "phosphorescence", meaning glow after illumination, derives from this property of phosphorus, the glow of phosphorus originates from oxidation of the white (but not red) phosphorus and should be called chemiluminescence. It is also the lightest element to easily produce stable exceptions to the octet rule.

The vast majority of phosphorus compounds are consumed as fertilizers. Other applications include the role of organophosphorus compounds in detergents, pesticides and nerve agents, and matches.

Sulfur

''Sulfur'' (symbol S) is an abundant multivalent nonmetal, one of chalcogens. Under normal conditions, sulfur atoms form cyclic octatomic molecules with chemical formula S₈. Elemental sulfur is a bright yellow crystalline solid when at room temperature. Chemically, sulfur can react as either an oxidant or a reducing agent. It oxidizes most metals and several nonmetals, including carbon, which leads to its negative charge in most organosulfur compounds, but it reduces several strong oxidants, such as oxygen and fluorine.

In nature, sulfur can be found as the pure element and as sulfide and sulfate minerals. Elemental sulfur crystals are commonly sought after by mineral collectors for their brightly-colored polyhedron shapes. Being abundant in native form, sulfur was known in ancient times, mentioned for its uses in ancient Greece, China and Egypt. Sulfur fumes were used as fumigants, and sulfur-containing medicinal mixtures were used as balms and antiparasitics. Sulfur is referenced in the Bible as brimstone in English, with this name still used in several nonscientific terms.Greenwood, N. N.; & Earnshaw, A. (1997). Chemistry of the Elements (2nd Edn.), Oxford:Butterworth-Heinemann. . Sulfur was considered important enough to receive its own alchemical symbol. It was needed to make the best quality of black gunpowder, and the bright yellow powder was hypothesized by alchemists to contain some of the properties of gold, which they sought to synthesize from it. In 1777, Antoine Lavoisier

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