Moissanite
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Moissanite () is naturally occurring
silicon carbide Silicon carbide (SiC), also known as carborundum (), is a hard chemical compound containing silicon and carbon. A semiconductor, it occurs in nature as the extremely rare mineral moissanite, but has been mass-produced as a powder and crystal sin ...
and its various crystalline polymorphs. It has the chemical formula SiC and is a rare
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. ( ...
, discovered by the French chemist
Henri Moissan Ferdinand Frédéric Henri Moissan (28 September 1852 – 20 February 1907) was a French chemist and pharmacist who won the 1906 Nobel Prize in Chemistry for his work in isolating fluorine from its compounds. Moissan was one of the original mem ...
in 1893. Silicon carbide is useful for commercial and industrial applications due to its
hardness In materials science, hardness (antonym: softness) is a measure of the resistance to localized plastic deformation induced by either mechanical indentation or abrasion. In general, different materials differ in their hardness; for example hard ...
,
optical properties The optical properties of a material define how it interacts with light. The optical properties of matter are studied in optical physics, a subfield of optics. The optical properties of matter include: *Refractive index * Dispersion *Transmittance a ...
and
thermal conductivity The thermal conductivity of a material is a measure of its ability to conduct heat. It is commonly denoted by k, \lambda, or \kappa. Heat transfer occurs at a lower rate in materials of low thermal conductivity than in materials of high thermal ...
.


Background

The mineral moissanite was discovered by Henri Moissan while examining rock samples from a
meteor crater Meteor Crater, or Barringer Crater, is a meteorite impact crater about east of Flagstaff and west of Winslow in the desert of northern Arizona, United States. The site had several earlier names, and fragments of the meteorite are official ...
located in Canyon Diablo,
Arizona Arizona ( ; nv, Hoozdo Hahoodzo ; ood, Alĭ ṣonak ) is a state in the Southwestern United States. It is the 6th largest and the 14th most populous of the 50 states. Its capital and largest city is Phoenix. Arizona is part of the Fou ...
, in 1893. At first, he mistakenly identified the crystals as
diamond Diamond is a Allotropes of carbon, solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. Another solid form of carbon known as graphite is the Chemical stability, chemically stable form of car ...
s, but in 1904 he identified the crystals as silicon carbide. Artificial silicon carbide had been synthesized in the lab by Edward G. Acheson just two years before Moissan's discovery. The mineral form of silicon carbide was named in honor of Moissan later on in his life.


Geological occurrence

In its natural form moissanite remains very rare. Until the 1950s, no other source for moissanite other than as
presolar grains Presolar grains are interstellar solid matter in the form of tiny solid grains that originated at a time before the Sun was formed. Presolar stardust grains formed within outflowing and cooling gases from earlier presolar stars. The stellar nucl ...
in carbonaceous chondrite
meteorites A meteorite is a solid piece of debris from an object, such as a comet, asteroid, or meteoroid, that originates in outer space and survives its passage through the atmosphere to reach the surface of a planet or moon. When the original object en ...
had been encountered. Then, in 1958, moissanite was found in the
upper mantle The upper mantle of Earth is a very thick layer of rock inside the planet, which begins just beneath the crust (at about under the oceans and about under the continents) and ends at the top of the lower mantle at . Temperatures range from appr ...
Green River Formation The Green River Formation is an Eocene geologic formation that records the sedimentation in a group of intermountain lakes in three basins along the present-day Green River in Colorado, Wyoming, and Utah. The sediments are deposited in very fine ...
in
Wyoming Wyoming () is a U.S. state, state in the Mountain states, Mountain West subregion of the Western United States. It is bordered by Montana to the north and northwest, South Dakota and Nebraska to the east, Idaho to the west, Utah to the south ...
and, the following year, as inclusions in the
ultramafic rock Ultramafic rocks (also referred to as ultrabasic rocks, although the terms are not wholly equivalent) are igneous and meta-igneous rocks with a very low silica content (less than 45%), generally >18% MgO, high FeO, low potassium, and are composed ...
kimberlite Kimberlite is an igneous rock and a rare variant of peridotite. It is most commonly known to be the main host matrix for diamonds. It is named after the town of Kimberley in South Africa, where the discovery of an diamond called the Star of ...
from a diamond mine in
Yakutia Sakha, officially the Republic of Sakha (Yakutia),, is the largest republic of Russia, located in the Russian Far East, along the Arctic Ocean, with a population of roughly 1 million. Sakha comprises half of the area of its governing Far Eas ...
in the Russian Far East. Yet the existence of moissanite in nature was questioned as late as 1986 by the American geologist Charles Milton. Discoveries show that it occurs naturally as inclusions in diamonds,
xenolith A xenolith ("foreign rock") is a rock fragment ( country rock) that becomes enveloped in a larger rock during the latter's development and solidification. In geology, the term ''xenolith'' is almost exclusively used to describe inclusions in ig ...
s, and such other ultramafic rock such as
lamproite Lamproite is an ultrapotassic mantle-derived volcanic or subvolcanic rock. It has low CaO, Al2O3, Na2O, high K2O/Al2O3, a relatively high MgO content and extreme enrichment in incompatible elements. Lamproites are geographically widespread ...
.


Meteorites

Analysis of silicon carbide grains found in the
Murchison meteorite The Murchison meteorite is a meteorite that fell in Australia in 1969 near Murchison, Victoria. It belongs to the carbonaceous chondrite class, a group of meteorites rich in organic compounds. Due to its mass (over ) and the fact that it was an ...
has revealed anomalous
isotopic ratio In physics, natural abundance (NA) refers to the abundance of isotopes of a chemical element as naturally found on a planet. The relative atomic mass (a weighted average, weighted by mole-fraction abundance figures) of these isotopes is the atomi ...
s of carbon and silicon, indicating an extraterrestrial origin from outside the
Solar System The Solar SystemCapitalization of the name varies. The International Astronomical Union, the authoritative body regarding astronomical nomenclature, specifies capitalizing the names of all individual astronomical objects but uses mixed "Solar S ...
. 99% of these silicon carbide grains originate around carbon-rich
asymptotic giant branch The asymptotic giant branch (AGB) is a region of the Hertzsprung–Russell diagram populated by evolved cool luminous stars. This is a period of stellar evolution undertaken by all low- to intermediate-mass stars (about 0.5 to 8 solar masses) lat ...
stars. Silicon carbide is commonly found around these stars, as deduced from their infrared spectra. The discovery of silicon carbide in the
Canyon Diablo meteorite The Canyon Diablo meteorite refers to the many fragments of the asteroid that created Meteor Crater (also called Barringer Crater), Arizona, United States. Meteorites have been found around the crater rim, and are named for nearby Canyon Diabl ...
and other places was challenged for a long time as carborundum (SiC) contamination had occurred from man-made abrasive tools.


Physical properties

The crystalline structure is held together with strong
covalent bonding A covalent bond is a chemical bond that involves the sharing of electrons to form electron pairs between atoms. These electron pairs are known as shared pairs or bonding pairs. The stable balance of attractive and repulsive forces between atoms ...
similar to diamonds, that allows moissanite to withstand high pressures up to 52.1
gigapascal The pascal (symbol: Pa) is the unit of pressure in the International System of Units (SI), and is also used to quantify internal pressure, stress, Young's modulus, and ultimate tensile strength. The unit, named after Blaise Pascal, is defined as ...
s. Colors vary widely and are graded from D to K range on the diamond color grading scale.


Sources

All applications of silicon carbide today use synthetic material, as the natural material is very scarce. The idea that a silicon-carbon bond might in fact exist in nature was first proposed by the Swedish chemist Jöns Jacob Berzelius as early as 1824, (Berzelius 1824). In 1891,
Edward Goodrich Acheson Edward Goodrich Acheson (March 9, 1856 – July 6, 1931) was an American chemist. Born in Washington, Pennsylvania, he was the inventor of the Acheson process, which is still used to make Silicon carbide (carborundum) and later a manufacturer of ...
produced viable minerals that could substitute for diamond as an abrasive and cutting material. This was possible, as moissanite is one of the hardest substances known, with a hardness just below that of
diamond Diamond is a Allotropes of carbon, solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. Another solid form of carbon known as graphite is the Chemical stability, chemically stable form of car ...
and comparable with those of cubic
boron nitride Boron nitride is a thermally and chemically resistant refractory compound of boron and nitrogen with the chemical formula BN. It exists in various crystalline forms that are isoelectronic to a similarly structured carbon lattice. The hexagonal ...
and
boron Boron is a chemical element with the symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the ''boron group'' it has th ...
. Pure synthetic moissanite can also be made from
thermal decomposition Thermal decomposition, or thermolysis, is a chemical decomposition caused by heat. The decomposition temperature of a substance is the temperature at which the substance chemically decomposes. The reaction is usually endothermic as heat is req ...
of the preceramic polymer poly(methylsilyne), requiring no binding matrix, ''e.g.'', cobalt metal powder. Single-crystalline silicon carbide, in certain forms, has been used for the fabrication of high-performance semiconductor devices. As natural sources of silicon carbide are rare, and only certain atomic arrangements are useful for gemological applications, North Carolina-based Cree Research, Inc., founded in 1987, developed a commercial process for producing large single crystals of silicon carbide. Cree is the world leader in the growth of single crystal silicon carbide, mostly for electronics use. In 1995 C3 Inc., a company helmed by Charles Eric Hunter, formed Charles & Colvard Ltd. (later changed to Charles & Colvard) to market gem quality moissanite. Charles & Colvard was the first company to produce and sell synthetic moissanite under U.S. patent US5723391 A, first filed by C3 Inc. in North Carolina.


Applications

Moissanite was introduced to the jewelry market as a
diamond alternative A diamond simulant, diamond imitation or imitation diamond is an object or material with gemological characteristics similar to those of a diamond. Simulants are distinct from synthetic diamonds, which are actual diamonds exhibiting the same mat ...
in 1998 after Charles & Colvard (formerly known as C3 Inc.) received patents to create and market lab-grown silicon carbide gemstones, becoming the first firm to do so. By 2018 all patents on the original process world-wide had expired. Charles & Colvard currently makes and distributes moissanite jewelry and loose gems under the trademarks ''Forever One'', ''Forever Brilliant'', and ''Forever Classic''. Other manufacturers market silicon carbide gemstones under trademarked names such as ''Amora''. On the
Mohs scale of mineral hardness The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. The scale was introduced in 1812 by th ...
(with diamond as the upper extreme, 10) moissanite is rated as 9.25. As a diamond alternative Moissanite has some optical properties exceeding those of diamond. It is marketed as a lower price alternative to diamond that does not involve the expensive mining practices used for the extraction of natural diamonds. As some of its properties are quite similar to diamond, moissanite may be used as counterfeit diamond. Testing equipment based on measuring
thermal conductivity The thermal conductivity of a material is a measure of its ability to conduct heat. It is commonly denoted by k, \lambda, or \kappa. Heat transfer occurs at a lower rate in materials of low thermal conductivity than in materials of high thermal ...
in particular may give results similar to diamond. In contrast to diamond, moissanite exhibits a
thermochromism Thermochromism is the property of substances to change color due to a change in temperature. A mood ring is an excellent example of this phenomenon, but thermochromism also has more practical uses, such as baby bottles which change to a differe ...
, such that heating it gradually will cause it to temporarily change color, starting at around . A more practical test is a measurement of
electrical conductivity Electrical resistivity (also called specific electrical resistance or volume resistivity) is a fundamental property of a material that measures how strongly it resists electric current. A low resistivity indicates a material that readily allow ...
, which will show higher values for moissanite. Moissanite is
birefringent Birefringence is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are said to be birefringent (or birefractive). The birefring ...
(i.e., light sent through the material splits into separate beams that depend on the source polarization), which can be easily seen, and diamond is not. Because of its hardness, it can be used in high-pressure experiments, as a replacement for diamond (see
diamond anvil cell A diamond anvil cell (DAC) is a high-pressure device used in geology, engineering, and materials science experiments. It enables the compression of a small (sub-millimeter-sized) piece of material to extreme pressures, typically up to around 1 ...
). Since large diamonds are usually too expensive to be used as anvils, moissanite is more often used in large-volume experiments. Synthetic moissanite is also interesting for
electronic Electronic may refer to: *Electronics, the science of how to control electric energy in semiconductor * ''Electronics'' (magazine), a defunct American trade journal *Electronic storage, the storage of data using an electronic device *Electronic co ...
and thermal applications because its thermal conductivity is similar to that of diamonds. High power silicon carbide electronic devices are expected to find use in the design of protection circuits used for motors,
actuator An actuator is a component of a machine that is responsible for moving and controlling a mechanism or system, for example by opening a valve. In simple terms, it is a "mover". An actuator requires a control device (controlled by control signal) a ...
s, and energy storage or pulse power systems. It also exhibits
thermoluminescence Thermoluminescence is a form of luminescence that is exhibited by certain crystalline materials, such as some minerals, when previously absorbed energy from electromagnetic radiation or other ionizing radiation is re-emitted as light upon he ...
, making it useful in radiation
dosimetry Radiation dosimetry in the fields of health physics and radiation protection is the measurement, calculation and assessment of the ionizing radiation dose absorbed by an object, usually the human body. This applies both internally, due to ingested ...
.


See also

* Charles & Colvard *
Cubic zirconia Cubic zirconia (CZ) is the cubic crystalline form of zirconium dioxide (ZrO2). The synthesized material is hard and usually colorless, but may be made in a variety of different colors. It should not be confused with zircon, which is a zirco ...
*
Diamond Diamond is a Allotropes of carbon, solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. Another solid form of carbon known as graphite is the Chemical stability, chemically stable form of car ...
* Engagement ring *
Fair trade Fair trade is an arrangement designed to help producers in developing countries achieve sustainable and equitable trade relationships. The fair trade movement combines the payment of higher prices to exporters with improved social and enviro ...
*
Glossary of meteoritics This is a glossary of terms used in meteoritics, the science of meteorites. # * 2 Pallas – an asteroid from the asteroid belt and one of the likely parent bodies of the CR meteorites. * 4 Vesta – second-largest asteroid in the asteroid b ...


References


External links

* {{Meteorites Carbide minerals Hexagonal minerals Minerals in space group 186 Meteorite minerals Native element minerals Gemstones