In chemistry, a mixed oxide is a somewhat informal name for an oxide that contains cations of more than one chemical element or cations of a single element in several Oxidation state, states of oxidation.
[Advanced Inorganic Chemistry, F. Albert Cotton, F. A. Cotton, G. Wilkinson, Interscience, 2d Edition, 1966]
The term is usually applied to solid ionic compounds that contain the oxide anion and two or more element cations. Typical examples are ilmenite (), a mixed oxide of iron () and titanium () cations, perovskite and garnet.The cations may be the same element in different ionization states: a notable example is magnetite , which is also known as ferrosoferric oxide , contains the cations Fe(2+) ("ferrous" iron) and ("ferric" iron) in 1:2 ratio. Other notable examples include lead(II,IV) oxide, red lead , the ferrite (magnet), ferrites,
[Alex Goldman (1990), ''Modern ferrite technology''] and the yttrium aluminum garnet ,
[K. Byrappa, Masahiro Yoshimura (2001), ''Handbook of hydrothermal technology''. William Andrew. 870 pages.] used in lasers.
The term is sometimes also applied to compounds of oxygen and two or more other elements, where some or all of the oxygen atoms are covalently bound into oxyanions. In sodium zincate , for example, the oxygens are bound to the zinc atoms forming zincate anions.
[D. Trinschek, M. Jansen (1996): ", ein neues Natriumzinkat". ''Zeitschrift für Naturforschung B'', volume 51, issue 5, pages 711-714. ] (On the other hand, strontium titanate , despite its name, contains cations and not the anion.)
Sometimes the term is applied loosely to solid solutions of metal oxides rather than chemical compounds, or to fine mixtures of two or more oxides.
Mixed oxide minerals are plentiful in nature. Synthetic mixed oxides are components of many ceramics with remarkable properties and important advanced technological applications, such as strong magnets, fine optics, lasers, semiconductors, piezoelectrics, superconductors, catalysts, refractory, refractories, gas mantles, MOX fuel, nuclear fuels, and more. Piezoelectric mixed oxides, in particular, are extensively used in pressure gauge, pressure and strain gauges, microphones, ultrasound transducers, micromanipulators, Analog delay line, delay lines, etc..
See also
* Double salt
References
Oxides,
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