Microcline
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Microcline (KAlSi3O8) is an important
igneous rock Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rock is formed through the cooling and solidification of magma o ...
-forming
tectosilicate Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually consid ...
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2 ...
. It is a
potassium Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosph ...
-rich alkali feldspar. Microcline typically contains minor amounts of
sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable ...
. It is common in
granite Granite () is a coarse-grained ( phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies under ...
and pegmatites. Microcline forms during slow cooling of
orthoclase Orthoclase, or orthoclase feldspar ( endmember formula K Al Si3 O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture," because its two cleavage planes are at right angles ...
; it is more stable at lower temperatures than orthoclase.
Sanidine Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal sys ...
is a polymorph of alkali feldspar stable at yet higher temperature. Microcline may be clear, white, pale-yellow, brick-red, or green; it is generally characterized by cross-hatch twinning that forms as a result of the transformation of
monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic s ...
orthoclase into
triclinic 180px, Triclinic (a ≠ b ≠ c and α ≠ β ≠ γ ) In crystallography, the triclinic (or anorthic) crystal system is one of the 7 crystal systems. A crystal system is described by three basis vectors. In the triclinic system, the crystal i ...
microcline. The chemical compound name is potassium aluminium silicate, and it is known as E number reference E555.


Geology

Microcline may be chemically the same as
monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic s ...
orthoclase Orthoclase, or orthoclase feldspar ( endmember formula K Al Si3 O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture," because its two cleavage planes are at right angles ...
, but because it belongs to the
triclinic 180px, Triclinic (a ≠ b ≠ c and α ≠ β ≠ γ ) In crystallography, the triclinic (or anorthic) crystal system is one of the 7 crystal systems. A crystal system is described by three basis vectors. In the triclinic system, the crystal i ...
crystal system, the prism angle is slightly less than right angles; hence the name "microcline" from the
Greek Greek may refer to: Greece Anything of, from, or related to Greece, a country in Southern Europe: *Greeks, an ethnic group. *Greek language, a branch of the Indo-European language family. **Proto-Greek language, the assumed last common ancestor ...
"small slope." It is a fully ordered
triclinic 180px, Triclinic (a ≠ b ≠ c and α ≠ β ≠ γ ) In crystallography, the triclinic (or anorthic) crystal system is one of the 7 crystal systems. A crystal system is described by three basis vectors. In the triclinic system, the crystal i ...
modification of
potassium Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosph ...
feldspar Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) felds ...
and is dimorphous with
orthoclase Orthoclase, or orthoclase feldspar ( endmember formula K Al Si3 O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture," because its two cleavage planes are at right angles ...
. Microcline is identical to orthoclase in many physical properties, and can be distinguished by x-ray or optical examination. When viewed under a
polarizing microscope A petrographic microscope is a type of optical microscope used in petrology and optical mineralogy to identify Rock (geology), rocks and minerals in thin sections. The microscope is used in optical mineralogy and petrography, a branch of ...
, microcline exhibits a minute multiple twinning which forms a grating-like structure that is unmistakable. Perthite is either microcline or orthoclase with thin lamellae of exsolved albite. Amazon stone, or
amazonite Amazonite, also known as Amazonstone, is a green tectosilicate mineral, a variety of the potassium feldspar called microcline. Its chemical formula is KAlSi3O8, which is polymorphic to orthoclase. Its name is taken from that of the Amazon Rive ...
, is a green variety of microcline. It is not found anywhere in the Amazon Basin, however. The
Spanish Spanish might refer to: * Items from or related to Spain: **Spaniards are a nation and ethnic group indigenous to Spain **Spanish language, spoken in Spain and many Latin American countries **Spanish cuisine Other places * Spanish, Ontario, Can ...
explorers who named it apparently confused it with another green mineral from that region. The largest documented single crystals of microcline were found in Devils Hole Beryl Mine,
Colorado Colorado (, other variants) is a state in the Mountain states, Mountain West subregion of the Western United States. It encompasses most of the Southern Rocky Mountains, as well as the northeastern portion of the Colorado Plateau and the wes ...
, US and measured ~50x36x14 m. This could be one of the largest crystals of any material found so far. Microcline is commonly used for the manufacturing of porcelain.


As food additive

The chemical compound name is potassium aluminium silicate, and it is known as E number reference E555. It was the subject in 2018 of a Call for technical and toxicological data from the
EFSA The European Food Safety Authority (EFSA) is the agency of the European Union (EU) that provides independent scientific advice and communicates on existing and emerging risks associated with the food chain. EFSA was established in February 2002, ...
. In 2008, it (along with other Aluminum compounds) was the subject of a Scientific Opinion of the Panel on Food Additives, Flavourings, Processing Aids and Food Contact Materials from the EFSA.


See also

*
List of minerals This is a list of minerals for which there are articles on Wikipedia. Minerals are distinguished by various chemical and physical properties. Differences in chemical composition and crystal structure distinguish the various ''species''. Within a m ...


References

{{reflist
Alkali feldspars U. Texas
Potassium minerals Aluminium minerals Tectosilicates Triclinic minerals Feldspar Luminescent minerals E-number additives Minerals in space group 2