Mesoscopic physics
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Mesoscopic physics is a subdiscipline of condensed matter physics that deals with materials of an intermediate size. These materials range in size between the
nanoscale The nanoscopic scale (or nanoscale) usually refers to structures with a length scale applicable to nanotechnology, usually cited as 1–100 nanometers (nm). A nanometer is a billionth of a meter. The nanoscopic scale is (roughly speaking) a lo ...
for a quantity of
atom Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas, ...
s (such as a
molecule A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and bioche ...
) and of materials measuring micrometres. The lower limit can also be defined as being the size of individual atoms. At the micrometre level are bulk materials. Both mesoscopic and
macroscopic The macroscopic scale is the length scale on which objects or phenomena are large enough to be visible with the naked eye, without magnifying optical instruments. It is the opposite of microscopic. Overview When applied to physical phenomena a ...
objects contain many atoms. Whereas average properties derived from constituent materials describe macroscopic objects, as they usually obey the laws of
classical mechanics Classical mechanics is a physical theory describing the motion of macroscopic objects, from projectiles to parts of machinery, and astronomical objects, such as spacecraft, planets, stars, and galaxies. For objects governed by classi ...
, a mesoscopic object, by contrast, is affected by thermal fluctuations around the average, and its electronic behavior may require modeling at the level of
quantum mechanics Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistr ...
.Sci-Tech Dictionary. McGraw-Hill Dictionary of Scientific and Technical Terms. 2003. McGraw-Hill Companies, Inc A macroscopic electronic device, when scaled down to a meso-size, starts revealing quantum mechanical properties. For example, at the macroscopic level the conductance of a wire increases continuously with its diameter. However, at the mesoscopic level, the wire's conductance is quantized: the increases occur in discrete, or individual, whole steps. During research, mesoscopic devices are constructed, measured and observed
experiment An experiment is a procedure carried out to support or refute a hypothesis, or determine the efficacy or likelihood of something previously untried. Experiments provide insight into Causality, cause-and-effect by demonstrating what outcome oc ...
ally and
theoretical A theory is a rational type of abstract thinking about a phenomenon, or the results of such thinking. The process of contemplative and rational thinking is often associated with such processes as observational study or research. Theories may be ...
ly in order to advance understanding of the
physics Physics is the natural science that studies matter, its fundamental constituents, its motion and behavior through space and time, and the related entities of energy and force. "Physical science is that department of knowledge which r ...
of
insulators Insulator may refer to: * Insulator (electricity), a substance that resists electricity ** Pin insulator, a device that isolates a wire from a physical support such as a pin on a utility pole ** Strain insulator, a device that is designed to work ...
,
semiconductor A semiconductor is a material which has an electrical conductivity value falling between that of a conductor, such as copper, and an insulator, such as glass. Its resistivity falls as its temperature rises; metals behave in the opposite way. ...
s,
metal A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typicall ...
s and superconductors. The applied science of mesoscopic physics deals with the potential of building nanodevices. ''Mesoscopic physics'' also addresses fundamental practical problems which occur when a macroscopic object is miniaturized, as with the miniaturization of
transistor upright=1.4, gate (G), body (B), source (S) and drain (D) terminals. The gate is separated from the body by an insulating layer (pink). A transistor is a semiconductor device used to Electronic amplifier, amplify or electronic switch, switch ...
s in
semiconductor A semiconductor is a material which has an electrical conductivity value falling between that of a conductor, such as copper, and an insulator, such as glass. Its resistivity falls as its temperature rises; metals behave in the opposite way. ...
electronics. The mechanical, chemical, and electronic properties of materials change as their size approaches the
nanoscale The nanoscopic scale (or nanoscale) usually refers to structures with a length scale applicable to nanotechnology, usually cited as 1–100 nanometers (nm). A nanometer is a billionth of a meter. The nanoscopic scale is (roughly speaking) a lo ...
, where the percentage of atoms at the surface of the material becomes significant. For bulk materials larger than one micrometre, the percentage of atoms at the surface is insignificant in relation to the number of atoms in the entire material. The subdiscipline has dealt primarily with artificial structures of metal or semiconducting material which have been fabricated by the techniques employed for producing
microelectronic Microelectronics is a subfield of electronics. As the name suggests, microelectronics relates to the study and manufacture (or microfabrication) of very small electronic designs and components. Usually, but not always, this means micrometre-sc ...
circuits. There is no rigid definition for ''mesoscopic physics'' but the systems studied are normally in the range of 100 nm (the size of a typical
virus A virus is a submicroscopic infectious agent that replicates only inside the living cells of an organism. Viruses infect all life forms, from animals and plants to microorganisms, including bacteria and archaea. Since Dmitri Ivanovsk ...
) to 1 000 nm (the size of a typical bacterium): 100 nanometers is the approximate upper limit for a
nanoparticle A nanoparticle or ultrafine particle is usually defined as a particle of matter that is between 1 and 100 nanometres (nm) in diameter. The term is sometimes used for larger particles, up to 500 nm, or fibers and tubes that are less than 10 ...
. Thus, mesoscopic physics has a close connection to the fields of
nanofabrication Nanolithography (NL) is a growing field of techniques within nanotechnology dealing with the engineering (patterning e.g. etching, depositing, writing, printing etc) of nanometer-scale structures on various materials. The modern term reflects on a ...
and nanotechnology. Devices used in nanotechnology are examples of mesoscopic systems. Three categories of new electronic phenomena in such systems are interference effects, quantum confinement effects and charging effects."Mesoscopic physics." McGraw-Hill Encyclopedia of Science and Technology. The McGraw-Hill Companies, Inc., 2005. Answers.com 25 Jan 2010. http://www.answers.com/topic/mesoscopic-physics-1


Quantum confinement effects

Quantum confinement A potential well is the region surrounding a local minimum of potential energy. Energy captured in a potential well is unable to convert to another type of energy (kinetic energy in the case of a gravitational potential well) because it is capt ...
effects describe electrons in terms of energy levels,
potential well A potential well is the region surrounding a local minimum of potential energy. Energy captured in a potential well is unable to convert to another type of energy (kinetic energy in the case of a gravitational potential well) because it is cap ...
s,
valence band In solid-state physics, the valence band and conduction band are the bands closest to the Fermi level, and thus determine the electrical conductivity of the solid. In nonmetals, the valence band is the highest range of electron energies in w ...
s, conduction bands, and electron energy
band gap In solid-state physics, a band gap, also called an energy gap, is an energy range in a solid where no electronic states can exist. In graphs of the electronic band structure of solids, the band gap generally refers to the energy difference ( ...
s. Electrons in bulk
dielectric In electromagnetism, a dielectric (or dielectric medium) is an electrical insulator that can be polarised by an applied electric field. When a dielectric material is placed in an electric field, electric charges do not flow through the mate ...
materials (larger than 10 nm) can be described by energy bands or electron energy levels.
Electron The electron ( or ) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary particles because they have no ...
s exist at different energy levels or bands. In bulk materials these energy levels are described as continuous because the difference in energy is negligible. As electrons stabilize at various energy levels, most vibrate in
valence band In solid-state physics, the valence band and conduction band are the bands closest to the Fermi level, and thus determine the electrical conductivity of the solid. In nonmetals, the valence band is the highest range of electron energies in w ...
s below a forbidden energy level, named the
band gap In solid-state physics, a band gap, also called an energy gap, is an energy range in a solid where no electronic states can exist. In graphs of the electronic band structure of solids, the band gap generally refers to the energy difference ( ...
. This region is an energy range in which no electron states exist. A smaller amount have energy levels above the forbidden gap, and this is the conduction band. The quantum confinement effect can be observed once the diameter of the particle is of the same magnitude as the
wavelength In physics, the wavelength is the spatial period of a periodic wave—the distance over which the wave's shape repeats. It is the distance between consecutive corresponding points of the same phase on the wave, such as two adjacent crests, t ...
of the electron's
wave function A wave function in quantum physics is a mathematical description of the quantum state of an isolated quantum system. The wave function is a complex-valued probability amplitude, and the probabilities for the possible results of measurements ...
. When materials are this small, their electronic and optical properties deviate substantially from those of bulk materials. As the material is miniaturized towards nano-scale the confining dimension naturally decreases. The characteristics are no longer averaged by bulk, and hence continuous, but are at the level of quanta and thus discrete. In other words, the energy
spectrum A spectrum (plural ''spectra'' or ''spectrums'') is a condition that is not limited to a specific set of values but can vary, without gaps, across a continuum. The word was first used scientifically in optics to describe the rainbow of colors ...
becomes discrete, measured as quanta, rather than continuous as in bulk materials. As a result, the
bandgap In solid-state physics, a band gap, also called an energy gap, is an energy range in a solid where no electronic states can exist. In graphs of the electronic band structure of solids, the band gap generally refers to the energy difference (i ...
asserts itself: there is a small and finite separation between energy levels. This situation of discrete energy levels is called ''quantum confinement''. In addition, quantum confinement effects consist of isolated islands of electrons that may be formed at the patterned interface between two different semiconducting materials. The electrons typically are confined to disk-shaped regions termed
quantum dots Quantum dots (QDs) are semiconductor particles a few nanometres in size, having optical and electronic properties that differ from those of larger particles as a result of quantum mechanics. They are a central topic in nanotechnology. When the ...
. The confinement of the electrons in these systems changes their interaction with electromagnetic radiation significantly, as noted above. Because the electron energy levels of quantum dots are discrete rather than continuous, the addition or subtraction of just a few atoms to the quantum dot has the effect of altering the boundaries of the bandgap. Changing the geometry of the surface of the quantum dot also changes the bandgap energy, owing again to the small size of the dot, and the effects of quantum confinement.Quantum dots
. 2008 Evident Technologies, Inc.


Interference effects

In the mesoscopic regime, scattering from defects – such as impurities – induces interference effects which modulate the flow of electrons. The experimental signature of mesoscopic interference effects is the appearance of reproducible fluctuations in physical quantities. For example, the conductance of a given specimen oscillates in an apparently random manner as a function of fluctuations in experimental parameters. However, the same pattern may be retraced if the experimental parameters are cycled back to their original values; in fact, the patterns observed are reproducible over a period of days. These are known as universal conductance fluctuations.


Time-resolved mesoscopic dynamics

Time-resolved experiments in mesoscopic dynamics: the observation and study, at nanoscales, of condensed phase dynamics such as crack formation in solids, phase separation, and rapid fluctuations in the liquid state or in biologically relevant environments; and the observation and study, at nanoscales, of the ultrafast dynamics of non-crystalline materials.


Related

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References


External links

* * * {{Branches of physics Condensed matter physics Quantum mechanics