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In materials science Functionally Graded Materials (FGMs) may be characterized by the variation in composition and structure gradually over volume, resulting in corresponding changes in the properties of the material. The materials can be designed for specific function and applications. Various approaches based on the bulk (particulate processing), preform processing, layer processing and melt processing are used to fabricate the functionally graded materials.


History

The concept of FGM was first considered in Japan in 1984 during a space plane project, where a combination of materials used would serve the purpose of a thermal barrier capable of withstanding a surface temperature of 2000 K and a temperature gradient of 1000 K across a 10 mm section. In recent years this concept has become more popular in Europe, particularly in Germany. A transregional collaborative research center (SFB Transregio) is funded since 2006 in order to exploit the potential of grading monomaterials, such as steel, aluminium and polypropylen, by using thermomechanically coupled manufacturing processes.


General information

The basic structural units of FGMs are elements or material ingredients represented by ''maxel''. The term maxel was introduced in 2005 by Rajeev Dwivedi and
Radovan Kovacevic Radovan Kovacevic is a Serbian-American university professor. He is the director of the Southern Methodist University , mottoeng = "The truth will make you free" , established = , type = Private research university , accreditation = SA ...
at
Research Center for Advanced Manufacturing Research is " creative and systematic work undertaken to increase the stock of knowledge". It involves the collection, organization and analysis of evidence to increase understanding of a topic, characterized by a particular attentiveness ...
(RCAM). The attributes of maxel include the location and volume fraction of individual material components. A maxel is also used in the context of the
additive manufacturing 3D printing or additive manufacturing is the construction of a three-dimensional object from a CAD model or a digital 3D model. It can be done in a variety of processes in which material is deposited, joined or solidified under computer co ...
processes (such as
stereolithography Stereolithography (SLA or SL; also known as vat photopolymerisation, optical fabrication, photo-solidification, or resin printing) is a form of 3D printing technology used for creating models, prototypes, patterns, and production parts in a lay ...
, selective laser
sintering Clinker nodules produced by sintering Sintering or frittage is the process of compacting and forming a solid mass of material by pressure or heat without melting it to the point of liquefaction. Sintering happens as part of a manufacturing ...
, fused deposition modeling, etc.) to describe a physical
voxel In 3D computer graphics, a voxel represents a value on a regular grid in three-dimensional space. As with pixels in a 2D bitmap, voxels themselves do not typically have their position (i.e. coordinates) explicitly encoded with their values. Ins ...
(a portmanteau of the words 'volume' and 'element'), which defines the build resolution of either a rapid prototyping or rapid manufacturing process, or the resolution of a design produced by such fabrication means.


Applications

There are many areas of application for FGM. The concept is to make a composite material by varying the microstructure from one material to another material with a specific gradient. This enables the material to have the best of both materials. If it is for thermal, or corrosive resistance or malleability and toughness both strengths of the material may be used to avoid corrosion, fatigue, fracture and stress corrosion cracking. The transition between the two materials can usually be approximated by means of a power series. The aircraft and aerospace industry and the computer circuit industry are very interested in the possibility of materials that can withstand very high thermal gradients. This is normally achieved by using a ceramic layer connected with a metallic layer. The Air Vehicles Directorate has conducted a Quasi-static bending test results of functionally graded titanium/
titanium boride Titanium diboride (TiB2) is an extremely hard ceramic which has excellent heat conductivity, oxidation stability and wear resistance. TiB2 is also a reasonable electrical conductor,J. Schmidt et al. "Preparation of titanium diboride TiB2 by spark p ...
test specimens which can be seen below. The test correlated to the finite element analysis (FEA) using a quadrilateral mesh with each element having its own structural and thermal properties. Advanced Materials and Processes Strategic Research Programme (AMPSRA) have done analysis on producing a thermal barrier coating using Zr02 and NiCoCrAlY. Their results have proved successful but no results of the analytical model are published. The rendition of the term that relates to the additive fabrication processes has its origins at the RMRG (Rapid Manufacturing Research Group) at
Loughborough University Loughborough University (abbreviated as ''Lough'' or ''Lboro'' for post-nominals) is a public research university in the market town of Loughborough, Leicestershire, England. It has been a university since 1966, but it dates back to 1909, when L ...
in the
United Kingdom The United Kingdom of Great Britain and Northern Ireland, commonly known as the United Kingdom (UK) or Britain, is a country in Europe, off the north-western coast of the continental mainland. It comprises England, Scotland, Wales and North ...
. The term forms a part of a descriptive
taxonomy Taxonomy is the practice and science of categorization or classification. A taxonomy (or taxonomical classification) is a scheme of classification, especially a hierarchical classification, in which things are organized into groups or types. ...
of terms relating directly to various particulars relating to the additive
CAD Computer-aided design (CAD) is the use of computers (or ) to aid in the creation, modification, analysis, or optimization of a design. This software is used to increase the productivity of the designer, improve the quality of design, improve co ...
-
CAM Calmodulin (CaM) (an abbreviation for calcium-modulated protein) is a multifunctional intermediate calcium-binding messenger protein expressed in all eukaryotic cells. It is an intracellular target of the secondary messenger Ca2+, and the bind ...
manufacturing processes, originally established as a part of the research conducted by architect Thomas Modeen into the application of the aforementioned techniques in the context of architecture. Gradient of elastic modulus essentially changes the fracture toughness of adhesive contacts.


Modeling and simulation

Numerical methods have been developed for modelling the mechanical response of FGMs, with the finite element method being the most popular one. Initially, the variation of material properties was introduced by means of rows (or columns) of homogeneous elements, leading to a discontinuous step-type variation in the mechanical properties. Later, Santare and Lambros developed functionally graded finite elements, where the mechanical property variation takes place at the element level. Martínez-Pañeda and Gallego extended this approach to commercial finite element software. Contact properties of FGM can be simulated using the Boundary Element Method (which can be applied both to non-adhesive and adhesive contacts). Molecular dynamics simulation has also been implemented to study functionally graded materials. M. Islam studied the mechanical and vibrational properties of functionally graded Cu-Ni nanowires using molecular dynamics simulation. Mechanics of functionally graded material structures was considered by many authors.Elishakoff, I., Zaza, N., Curtin, J., Hashemi, J., Apparently First Closed-Form Solution for Vibration of Functionally Graded Rotating Beams”, AIAA Journal, Vol. 52(11), 2587-2593, 2014


References

{{Reflist Materials science Loughborough University Composite materials