MTBE controversy
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Methyl tert-butyl ether Methyl ''tertiary''-butyl ether (MTBE), also known as methyl tert-butyl ether and ''tert''-butyl methyl ether, is an organic compound with a structural formula (CH3)3COCH3. MTBE is a volatile, flammable, and colorless liquid that is sparingly sol ...
(MTBE) is a gasoline additive that replaced
tetraethyllead Tetraethyllead (commonly styled tetraethyl lead), abbreviated TEL, is an organolead compound with the formula Pb( C2H5)4. It is a fuel additive, first being mixed with gasoline beginning in the 1920s as a patented octane rating booster that ...
. MTBE is an
oxygenate Oxygenated chemical compounds contain oxygen as a part of their chemical structure. The term usually refers to oxygenated chemical compounds added to fuels. Oxygenates are usually employed as gasoline additives to reduce carbon monoxide and soot ...
and raises gasoline's octane number. Its use declined in the United States in response to environmental and health concerns. It has polluted groundwater due to MTBE-containing gasoline being spilled or leaked at gas stations. MTBE spreads more easily underground than other gasoline components due to its higher solubility in water. Cost estimates for removing MTBE from groundwater and contaminated soil range from $1
billion Billion is a word for a large number, and it has two distinct definitions: *1,000,000,000, i.e. one thousand million, or (ten to the ninth power), as defined on the short scale. This is its only current meaning in English. * 1,000,000,000,000, i. ...
to $30 billion, including removing the compound from aquifers and municipal water supplies, and replacing leaky underground oil tanks. Who will pay for remediation is controversial. In one case, the cost to oil companies to clean up the MTBE in wells belonging to the city of
Santa Monica Santa Monica (; Spanish: ''Santa Mónica'') is a city in Los Angeles County, situated along Santa Monica Bay on California's South Coast. Santa Monica's 2020 U.S. Census population was 93,076. Santa Monica is a popular resort town, owing to i ...
, California is estimated to exceed $200 million. Some U.S. states banned MTBE in gasoline.
California California is a state in the Western United States, located along the Pacific Coast. With nearly 39.2million residents across a total area of approximately , it is the most populous U.S. state and the 3rd largest by area. It is also the m ...
and New York, which together accounted for 40% of U.S. MTBE consumption, banned usage of the chemical in gasoline, effective 2002 and 2004, respectively. As of 2007, 25 states had issued complete or partial bans on the use of MTBE. The Energy Policy Act of 2005 prompted gasoline refiners to replace MTBE with ethanol.


Notable incidents in the United States


Fallston, Maryland

Harford County Harford County is located in the U.S. state of Maryland. As of the 2020 census, the population was 260,924. Its county seat is Bel Air. Harford County is included in the Baltimore-Columbia-Towson, MD Metropolitan Statistical Area, which is al ...
, Maryland, found MTBE in wells near several of its
filling station A filling station, also known as a gas station () or petrol station (), is a facility that sells fuel and engine lubricants for motor vehicles. The most common fuels sold in the 2010s were gasoline (or petrol) and diesel fuel. Ga ...
s beginning in 2004. This led the state of Maryland to make moves to ban MTBE. In 2005, an Exxon-Mobil station in Fallston, Maryland, was found to be leaking MTBE into the local wells. The discovery resulted in the station being abruptly closed. Exxon-Mobil referred to the closure as a "business decision". Following the closure, MTBE levels in the area dropped. In September 2004, Harford County placed a six-month moratorium on construction of filling stations.


Jacksonville, Maryland

In 2006, the wells of a neighborhood in
Jacksonville Jacksonville is a city located on the Atlantic coast of northeast Florida, the most populous city proper in the state and is the List of United States cities by area, largest city by area in the contiguous United States as of 2020. It is the co ...
, Maryland, were contaminated by a spill of 26,000 gallons of gasoline from an Exxon-Mobil station in the area, resulting in an ongoing court battle. The suit has been filed by the state of
Maryland Maryland ( ) is a state in the Mid-Atlantic region of the United States. It shares borders with Virginia, West Virginia, and the District of Columbia to its south and west; Pennsylvania to its north; and Delaware and the Atlantic Ocean to ...
's Department of the Environment on behalf of the area's residents, seeking millions of dollars in damages from Exxon-Mobil. Many residents also filed their own separate lawsuits. The case began in 2006, when a gasoline tank sprang a leak that was not detected for 34 days. Testing of 120 wells resulted in dangerously high levels of MTBE being found. Residents were put in danger by the spill, and in order to prevent further health problems, they required bottled water for cooking, drinking, and brushing teeth. Residents of Jacksonville continue to use bottled water for all activities despite having MTBE filters and alarms installed in their homes. Home values also dropped as a result of the spill. In September 2008, Exxon-Mobil settled the case with the state by agreeing to pay a $4 million fine, and face an additional $1 million in penalties annually if they did not work to clean up the spill. In March 2009, a jury awarded $150 million in damages to some of the area's residents. The jury did not assess any punitive damages in the case, finding that Exxon Mobil did not act fraudulently. A separate case including over 150 property owners as plaintiffs began in early 2011. Punitive damages were awarded to the second group of plaintiffs, on the basis that Exxon acted fraudulently, however this decision was later reversed.


Santa Monica, California

In 1995 high levels of MTBE were unexpectedly discovered in the
water well A well is an excavation or structure created in the ground by digging, driving, or drilling to access liquid resources, usually water. The oldest and most common kind of well is a water well, to access groundwater in underground aquifers. T ...
s of
Santa Monica Santa Monica (; Spanish: ''Santa Mónica'') is a city in Los Angeles County, situated along Santa Monica Bay on California's South Coast. Santa Monica's 2020 U.S. Census population was 93,076. Santa Monica is a popular resort town, owing to i ...
, California, and the
U.S. Geological Survey The United States Geological Survey (USGS), formerly simply known as the Geological Survey, is a scientific agency of the United States government. The scientists of the USGS study the landscape of the United States, its natural resources, and ...
reported detections. Subsequent U.S. findings indicate tens of thousands of contaminated sites in water wells distributed across the country. As per toxicity alone, MTBE is not classified as a hazard for the environment, but it imparts an unpleasant taste to water even at very low concentrations. The maximum contaminant level of MTBE in drinking water has not yet been established by the
United States Environmental Protection Agency The Environmental Protection Agency (EPA) is an independent executive agency of the United States federal government tasked with environmental protection matters. President Richard Nixon proposed the establishment of EPA on July 9, 1970; it ...
(EPA). The leakage problem is partially attributed to the lack of effective regulations for underground storage tanks, but spillage from overfilling is also a contributor. As an ingredient in unleaded gasoline, MTBE is the most water-soluble component. When dissolved in groundwater, MTBE will lead the contaminant plume with the remaining components such as
benzene Benzene is an organic chemical compound with the molecular formula C6H6. The benzene molecule is composed of six carbon atoms joined in a planar ring with one hydrogen atom attached to each. Because it contains only carbon and hydrogen atoms ...
and
toluene Toluene (), also known as toluol (), is a substituted aromatic hydrocarbon. It is a colorless, water-insoluble liquid with the smell associated with paint thinners. It is a mono-substituted benzene derivative, consisting of a methyl group (CH3) a ...
following. Thus the discovery of MTBE in public groundwater wells indicates that the contaminant source was a gasoline release. Its criticism and subsequent decreased usage, some claim, is more a product of its easy detectability (taste) in extremely low concentrations (ppb) than its toxicity. The MTBE concentrations used in the EU (usually 1.0–1.6%) and allowed (maximum 5%) in Europe are lower than in California.
Chevron Chevron (often relating to V-shaped patterns) may refer to: Science and technology * Chevron (aerospace), sawtooth patterns on some jet engines * Chevron (anatomy), a bone * '' Eulithis testata'', a moth * Chevron (geology), a fold in rock ...
, BP, and other oil companies agreed to settle with Santa Monica for $423 million on May 7, 2008.


Regulation in the United States


Restrictions on MTBE manufacturing and usage

In 2000, EPA drafted plans to phase out the use of MTBE nationwide over four years.. Some states enacted MTBE prohibitions without waiting for federal restrictions. California banned MTBE as a gasoline additive in 2002. The State of New York banned the use of MTBE as a "fuel additive", effective in 2004. MTBE use is still legal in the state for other industrial uses. The federal Energy Policy Act of 2005 removed the oxygenate requirement for reformulated gasoline and established a renewable fuel standard. The lack of MTBE liability protection in the law also prompted refiners to substitute ethanol for MTBE as a gasoline additive.


Drinking water regulations

EPA issued a drinking water health advisory for MTBE, a guidance document for water utilities and the public, in 1997. The Agency first listed MTBE in 1998 as a candidate for development of a national Maximum Contaminant Level (MCL) standard in drinking water. As of 2020 EPA has not announced whether it will develop an MCL. EPA uses toxicity data in developing MCLs for public water systems. California established a state-level MCL for MTBE in 2000.


See also

*
List of environmental issues This is an alphabetical list of environmental issues, harmful aspects of human activity on the biophysical environment. They are loosely divided into causes, effects and mitigation, noting that effects are interconnected and can cause new effects. ...
*
Environmental issues in the United States Environmental issues in the United States include climate change, energy, species conservation, invasive species, deforestation, mining, nuclear accidents, pesticides, pollution, waste and over-population. Despite taking hundreds of measures, t ...


References

{{motor fuel Filling stations Antiknock agents Environmental controversies Water pollution in the United States Soil contamination