Lead difluoride
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Lead(II) fluoride is the
inorganic compound In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemis ...
with the formula Pb F2. It is a white solid. It exists as both an
orthorhombic In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with ...
and cubic
forms Form is the shape, visual appearance, or configuration of an object. In a wider sense, the form is the way something happens. Form also refers to: *Form (document), a document (printed or electronic) with spaces in which to write or enter data * ...
.


Uses

Lead(II) fluoride is used in low melting
glass Glass is a non- crystalline, often transparent, amorphous solid that has widespread practical, technological, and decorative use in, for example, window panes, tableware, and optics. Glass is most often formed by rapid cooling (quenchin ...
es, in glass coatings to reflect
infrared Infrared (IR), sometimes called infrared light, is electromagnetic radiation (EMR) with wavelengths longer than those of Light, visible light. It is therefore invisible to the human eye. IR is generally understood to encompass wavelengths from ...
rays, in phosphors for television-tube screens, and as a catalyst for the manufacture of picoline. The Muon g−2 experiment uses scintillators in conjunction with silicon
photomultiplier A photomultiplier is a device that converts incident photons into an electrical signal. Kinds of photomultiplier include: * Photomultiplier tube, a vacuum tube converting incident photons into an electric signal. Photomultiplier tubes (PMTs for sh ...
s.Via inSPIRE
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Preparation

Lead(II) fluoride can be prepared by treating
lead(II) hydroxide Lead(II) hydroxide, Pb(OH)2, is a hydroxide of lead, with lead in oxidation state +2. In 1964 it was believed that such a simple compound did not exist, as lead basic carbonate (2PbCO3·Pb(OH)2) or lead(II) oxide (PbO) was encountered where lead ...
or
lead(II) carbonate Lead(II) carbonate is the chemical compound with the chemical formula . It is a white solid with several practical uses, despite its toxicity. It occurs naturally as the mineral cerussite. Structure Like all metal carbonates, lead(II) carbonate a ...
with
hydrofluoric acid Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. Solutions of HF are colourless, acidic and highly corrosive. It is used to make most fluorine-containing compounds; examples include the commonly used pharmaceutical antidepres ...
: : Pb(OH)2 + 2 HF → PbF2 + 2 H2O Alternatively, it is precipitated by adding hydrofluoric acid to a lead(II) salt solution, or by adding potassium fluoride to a
lead(II) nitrate Lead(II) nitrate is an inorganic compound with the chemical formula Pb( NO3)2. It commonly occurs as a colourless crystal or white powder and, unlike most other lead(II) salts, is soluble in water. Known since the Middle Ages by the name plumbu ...
solution.Arnold Hollemann, Egon Wiberg, 101st ed., de Gruyter 1995 Berlin; : 2 KF + Pb(NO3)2 → PbF2 + 2 KNO3 It appears as the very rare mineral fluorocronite.


References

Fluorides Lead(II) compounds Metal halides Phosphors and scintillators Reagents for organic chemistry Glass compositions {{inorganic-compound-stub