Lamproite is an ultrapotassic mantle-derived

volcanic A volcano is a rupture in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface. On Earth, volcanoes are most often found where tectonic plates a ...

or subvolcanic rock. It has low

CaO Cao or CAO may refer to: Mythology *Cao (bull), a legendary bull in Meitei mythology Companies or organizations * Air China Cargo, ICAO airline designator CAO *CA Oradea, Romanian football club *CA Osasuna, Spanish football club *Canadian Assoc ...

, Al₂O₃, Na₂O, high K₂O/Al₂O₃, a relatively high

MgO Magnesium oxide ( Mg O), or magnesia, is a white hygroscopic solid mineral that occurs naturally as periclase and is a source of magnesium (see also oxide). It has an empirical formula of MgO and consists of a lattice of Mg2+ ions and O2− ions ...

content and extreme enrichment in

incompatible element In petrology and geochemistry, an incompatible element is one that is unsuitable in size and/or charge to the cation sites of the minerals of which it is included. It is defined by the partition coefficient between rock-forming minerals and melt b ...

s. Lamproites are geographically widespread yet are volumetrically insignificant. Unlike

kimberlite Kimberlite is an igneous rock and a rare variant of peridotite. It is most commonly known to be the main host matrix for diamonds. It is named after the town of Kimberley in South Africa, where the discovery of an diamond called the Star of S ...

s, which are found exclusively in Archaean

craton A craton (, , or ; from grc-gre, κράτος "strength") is an old and stable part of the continental lithosphere, which consists of Earth's two topmost layers, the crust and the uppermost mantle. Having often survived cycles of merging an ...

s, lamproites are found in terrains of varying age, ranging from Archaean in Western Australia, to Palaeozoic and Mesozoic in southern Spain. They also vary widely in age, from Proterozoic to

Pleistocene The Pleistocene ( , often referred to as the ''Ice age'') is the geological epoch that lasted from about 2,580,000 to 11,700 years ago, spanning the Earth's most recent period of repeated glaciations. Before a change was finally confirmed in ...

, the youngest known example from

Gaussberg Gaussberg (or Schwarzen Berg, Mount Gauss) is an extinct, high volcanic cone in East Antarctica fronting on Davis Sea immediately west of Posadowsky Glacier. It is ice-free and conical in nature, having formed subglacially about 55,000 ...

in Antarctica being 56,000 ± 5,000 years old. Lamproite volcanology is varied, with both

diatreme A diatreme, sometimes known as a maar-diatreme volcano, is a volcanic pipe formed by a gaseous explosion. When magma rises up through a crack in Earth's crust and makes contact with a shallow body of groundwater, rapid expansion of heated wate ...

styles and cinder cone or cone edifices known.

Petrology

Lamproites form from partially melted mantle at depths exceeding 150 km. The molten material is forced to the surface in

volcanic pipe Volcanic pipes or volcanic conduits are subterranean geological structures formed by the violent, supersonic eruption of deep-origin volcanoes. They are considered to be a type of ''diatreme''. Volcanic pipes are composed of a deep, narrow cone o ...

s, bringing with it

xenolith A xenolith ("foreign rock") is a rock fragment ( country rock) that becomes enveloped in a larger rock during the latter's development and solidification. In geology, the term ''xenolith'' is almost exclusively used to describe inclusions in ig ...

s and diamonds from the harzburgitic peridotite or

eclogite Eclogite () is a metamorphic rock containing garnet (almandine- pyrope) hosted in a matrix of sodium-rich pyroxene (omphacite). Accessory minerals include kyanite, rutile, quartz, lawsonite, coesite, amphibole, phengite, paragonite, ...

mantle regions where diamond formation is stabilized. Recent research, for example on the lamproites at Gaussberg in Antarctica, and lead-lead

isotope geochemistry Isotope geochemistry is an aspect of geology based upon the study of natural variations in the relative abundances of isotopes of various elements. Variations in isotopic abundance are measured by isotope ratio mass spectrometry, and can reveal ...

have revealed that the source of lamproites may be transition zone melts of subducted lithosphere which has become trapped at the base of the lithospheric mantle. This observation also reconciles the depth of melting with the peculiar geochemistry, which is most easily explained by melting of already felsic material under deep mantle conditions.

Mineralogy

The mineralogy of lamproites is controlled by their peculiar

geochemistry Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the ...

, with a predominance of rare silica-deficient mineral species and rare, mantle-derived minerals predominating. Minerals typical of lamproites include: forsteritic olivine; high

iron Iron () is a chemical element with Symbol (chemistry), symbol Fe (from la, Wikt:ferrum, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 element, group 8 of the periodic table. It is, Abundanc ...

leucite Leucite is a rock-forming mineral of the feldspathoid group, silica-undersaturated and composed of potassium and aluminium tectosilicate KAlSi2O6. Crystals have the form of cubic icositetrahedra but, as first observed by Sir David Brewster in ...

;

titanium Titanium is a chemical element with the Symbol (chemistry), symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resista ...

-rich

aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...

-poor

phlogopite Phlogopite is a yellow, greenish, or reddish-brown member of the mica family of phyllosilicates. It is also known as magnesium mica. Phlogopite is the magnesium endmember of the biotite solid solution series, with the chemical formula KMg3AlSi3O ...

;

potassium Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosph ...

- and titanium-rich richterite; low aluminium

diopside Diopside is a monoclinic pyroxene mineral with composition . It forms complete solid solution series with hedenbergite () and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull ...

; and iron-rich

sanidine Sanidine is the high temperature form of potassium feldspar with a general formula K(AlSi3O8). Sanidine is found most typically in felsic volcanic rocks such as obsidian, rhyolite and trachyte. Sanidine crystallizes in the monoclinic crystal sys ...

. A variety of rare trace minerals occur. The rocks are high in potassium with 6 to 8%

potassium oxide Potassium oxide ( K O) is an ionic compound of potassium and oxygen. It is a base. This pale yellow solid is the simplest oxide of potassium. It is a highly reactive compound that is rarely encountered. Some industrial materials, such as fertili ...

. High chromium and

nickel Nickel is a chemical element with symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive but large pieces are slow ...

content is typical. The rocks commonly are altered to

talc Talc, or talcum, is a clay mineral, composed of hydrated magnesium silicate with the chemical formula Mg3Si4O10(OH)2. Talc in powdered form, often combined with corn starch, is used as baby powder. This mineral is used as a thickening agent a ...

with

carbonate A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate ...

or serpentine, chlorite, and

magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With th ...

Zeolite Zeolites are microporous, crystalline aluminosilicate materials commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula ･y where is either a metal ion or H+. These p ...

s and

quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical ...

may also occur. Lamproites are characterized by the presence of widely varying amounts (5-90 vol.%) of the following primary phases (Mitchell & Bergman, 1991): * titanian (2-10 wt% TiO₂), aluminium-poor (5-12 wt% Al₂O₃) phenocrystic phlogopite * titanian (5-10 wt% TiO₂) groundmass poikilitic "tetraferriphlogopite" * titanian (3-5 wt% TiO₂) potassium (4-6 wt% K₂O) richterite * forsteritic olivine * aluminium-poor (<1 wt% Al₂O₃), sodium-poor (<1 wt% Na₂O) diopside * nonstoichiometric iron-rich (1-4 wt% Fe₂O₃) leucite, and * iron-rich sanidine (typically 1-5 wt% Fe₂O₃)). The presence of all the above phases is not required in order to classify a rock as a lamproite. Any one mineral may be dominant, and this, together with the two or three other major minerals present, suffices to determine the petrographic name. The presence of the following minerals precludes a rock from being classified as a lamproite: primary

plagioclase Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more pro ...

melilite Melilite refers to a mineral of the melilite group. Minerals of the group are solid solutions of several endmembers, the most important of which are gehlenite and åkermanite. A generalized formula for common melilite is ( Ca, Na)2( Al, Mg, ...

monticellite Monticellite and kirschsteinite (commonly also spelled kirschteinite Klein and Hurlbut ''Manual of Mineralogy'' 20th ed., p. 373) are gray silicate minerals of the olivine group with compositions Ca Mg Si O4 and Ca FeSiO4, respectively. Most mont ...

kalsilite Kalsilite ( K Al Si O4) is a vitreous white to grey feldspathoidal mineral that is found in some potassium-rich lavas, such as from Chamengo Crater in Uganda. It has a relative hardness In materials science, hardness (antonym: softness) is a ...

nepheline Nepheline, also called nephelite (), is a rock-forming mineral in the feldspathoid groupa silica-undersaturated aluminosilicate, Na3 K Al4 Si4 O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatite ...

, Na-rich alkali feldspar,

sodalite Sodalite ( ) is a tectosilicate mineral with the formula , with royal blue varieties widely used as an ornamental gemstone. Although massive sodalite samples are opaque, crystals are usually transparent to translucent. Sodalite is a member of t ...

nosean Nosean, also known as noselite, is a mineral of the feldspathoid group with formula: Na8 Al6 Si6 O24( SO4). H2O. It forms isometric crystals of variable color: white, grey, blue, green, to brown. It has a Mohs hardness of 5.5 to 6 and a specific ...

hauyne Hauyne or haüyne, also called hauynite or haüynite ( ), is a tectosilicate sulfate mineral with endmember formula . As much as 5 wt % may be present, and also and Cl. It is a feldspathoid and a member of the sodalite group. Hauyne was fir ...

melanite Andradite is a mineral species of the garnet group. It is a nesosilicate, with formula Ca3Fe2Si3O12. Andradite includes three varieties: * ''Melanite'': Black in color, referred to as "titanian andradite".schorlomite or kimzeyite.

Geochemistry

Lamproites conform to the following chemical characteristics: * molar K₂O/Na₂O > 3, i.e., ultrapotassic * molar K₂O/Al₂O₃> 0.8 and commonly > 1 * molar K₂O + Na₂O/ Al₂O₃ typically > 1 i.e., peralkaline * typically <10 wt% each of FeO and CaO, TiO₂ 1-7 wt%, >2000 and commonly >5000 ppm Ba, >500 ppm Zr, >1000 ppm Sr and >200 ppm La.

Economic importance

The economic significance of lamproite became known with the discovery of Ellendale E4 and E9 lamproite pipes and better known 1979 discovery of the Argyle diamond pipe in

Western Australia Western Australia (commonly abbreviated as WA) is a state of Australia occupying the western percent of the land area of Australia excluding external territories. It is bounded by the Indian Ocean to the north and west, the Southern Ocean to th ...

. This discovery led to the intense study and re-evaluation of other known lamproite occurrences worldwide; previously only

pipes were considered economically viable sources of

diamond Diamond is a solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. Another solid form of carbon known as graphite is the chemically stable form of carbon at room temperature and pressure, ...

s. The Argyle diamond mine remains the only economically viable source of lamproite diamonds. This deposit differs markedly by having a high content of diamonds but low quality of most stones. Research at Argyle diamond have shown that most stones are of E-type; they originate from

source rocks and were formed under high temperature ~. The Argyle diamond mine is the main source of rare pink diamonds.

Olivine The mineral olivine () is a magnesium iron silicate with the chemical formula . It is a type of nesosilicate or orthosilicate. The primary component of the Earth's upper mantle, it is a common mineral in Earth's subsurface, but weathers quickl ...

lamproite pyroclastic rocks and

dikes Dyke (UK) or dike (US) may refer to: General uses * Dyke (slang), a slang word meaning "lesbian" * Dike (geology), a subvertical sheet-like intrusion of magma or sediment * Dike (mythology), ''Dikē'', the Greek goddess of moral justice * Dikes ...

are sometimes hosts for

s. The diamonds occur as

xenocryst A xenolith ("foreign rock") is a rock fragment ( country rock) that becomes enveloped in a larger rock during the latter's development and solidification. In geology, the term ''xenolith'' is almost exclusively used to describe inclusions in ign ...

s that have been carried to the surface or to shallow depths by the lamproite diapiric intrusions. The diamonds of

Crater of Diamonds State Park Crater of Diamonds State Park is a Arkansas state park in Pike County, Arkansas, in the United States. The park features a 37.5-acre (15.2 ha) plowed field, the world's only diamond-bearing site accessible to the public. Diamonds have continuou ...

near

Murfreesboro, Arkansas Murfreesboro is a city in, and the county seat of, Pike County, Arkansas, United States. Its population was 1,641 at the 2010 census. The city is known for the Crater of Diamonds State Park located south of the city. History In 1906, diamond ...

are found in a lamproite host.

Nomenclature

Lamproites, as a group, were known by a variety of localised names due to the fact their mineralogy is quite variable and because of their rarity often few examples of the following lamproite variants were known. Modern terminology classes all as lamproites but modifies this term with the mineral abundances as per the standard IUGS rules.

Related rock types

* * *

References

External links

LAMPROITE-HOSTED DIAMONDS
retrieved June 7, 2005

retrieved June 7, 2005

retrieved June 7, 2005

{{Authority control Ultrapotassic rocks Economic geology Igneous petrology Volcanic rocks Subvolcanic rocks