Iron(III) phosphate, also ferric phosphate, is the

inorganic compound In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemis ...

with the formula Fe PO₄. Several related materials are known, including four polymorphs of FePO₄ and two polymorphs of the dihydrate FePO₄·(H₂O)₂. These materials find few technical applications as well as occurring in the mineral kingdom.

Structure

The most common form of FePO₄ adopts the structure of α-

quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical f ...

. As such the material consists of tetrahedral Fe(III) and phosphate sites. As such the P and Fe have

tetrahedral molecular geometry In a tetrahedral molecular geometry, a central atom is located at the center with four substituents that are located at the corners of a tetrahedron. The bond angles are cos−1(−) = 109.4712206...° ≈ 109.5° when all four substituents a ...

. At high pressures, a phase change occurs to a more dense structure with octahedral Fe centres. Two orthorhombic structures and a monoclinic phase are also known. In the two polymorphs of the dihydrate, the Fe centre is octahedral with two mutually cis water

ligand In coordination chemistry, a ligand is an ion or molecule (functional group) that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one or more of the ligand's elect ...

Uses

Iron(III) phosphate can be used in steel and metal manufacturing processes. When bonded to a metal surface, iron phosphate prevents further oxidation of the metal. Its presence is partially responsible for the corrosion resistance of the iron pillar of Delhi. Iron phosphate coatings are commonly used in preparation for painting or powder coating, in order to increase

adhesion Adhesion is the tendency of dissimilar particles or surfaces to cling to one another ( cohesion refers to the tendency of similar or identical particles/surfaces to cling to one another). The forces that cause adhesion and cohesion can ...

to the iron or

steel Steel is an alloy made up of iron with added carbon to improve its strength and fracture resistance compared to other forms of iron. Many other elements may be present or added. Stainless steels that are corrosion- and oxidation-resistan ...

substrate, and prevent corrosion, which can cause premature failure of subsequent coating processes. It can also be used for bonding

fabrics Textile is an umbrella term that includes various fiber-based materials, including fibers, yarns, filaments, threads, different fabric types, etc. At first, the word "textiles" only referred to woven fabrics. However, weaving is not the ...

wood Wood is a porous and fibrous structural tissue found in the stems and roots of trees and other woody plants. It is an organic materiala natural composite of cellulose fibers that are strong in tension and embedded in a matrix of lignin ...

, and other materials to iron or steel surfaces. Anhydrous iron phosphate has been investigated as an intercalation electrode in a

lithium-ion battery A lithium-ion or Li-ion battery is a type of rechargeable battery which uses the reversible reduction of lithium ions to store energy. It is the predominant battery type used in portable consumer electronics and electric vehicles. It also s ...

despite having low electronic conductivity.

Pesticide

Iron phosphate is one of the few

molluscicide Molluscicides () – also known as snail baits, snail pellets, or slug pellets – are pesticides against molluscs, which are usually used in agriculture or gardening, in order to control gastropod pests specifically slugs and snails which damag ...

s approved for use in the practice of

organic farming Organic farming, also known as ecological farming or biological farming,Labelling, article 30 o''Regulation (EU) 2018/848 of the European Parliament and of the Council of 30 May 2018 on organic production and labelling of organic products and re ...

. Pesticide pellets contain iron phosphate plus a chelating agent, such as

EDTA Ethylenediaminetetraacetic acid (EDTA) is an aminopolycarboxylic acid with the formula H2N(CH2CO2H)2sub>2. This white, water-soluble solid is widely used to bind to iron (Fe2+/Fe3+) and calcium ions (Ca2+), forming water-soluble complexes ev ...

. The

Research Institute of Organic Agriculture The Research Institute of Organic Agriculture (German: ''Forschungsinstitut für biologischen Landbau'', in short: FiBL), is an organic farming information and research centres. As an independent and non-profit organization, it promotes researc ...

(FiBL) reported the EDTA content and stated products were likely to be no safer than

metaldehyde Metaldehyde is an organic compound with the formula (C8H16O4). It is used as a pesticide against slugs, snails, and other gastropods. It is the cyclic tetramer of acetaldehyde. Production and properties Metaldehyde is flammable, toxic if in ...

baits. Ferric phosphate slug and snail baits marketed in the U.S. contain EDTA.

Legislation

Iron(III) phosphate is not allowed as food additive in the European Union. It was withdrawn from the list of allowed substances in the directive 2002/46/EC in 2007.

References

External links