Iron(II) iodide
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Iron(II) iodide is an
inorganic compound In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemis ...
with the
chemical formula In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, ...
FeI2.University of Akron Chemical Database
It is used as a catalyst in organic reactions.


Preparation

Iron(II) iodide can be synthesised from the elements, i.e. by the reaction of
iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in ...
with
iodine Iodine is a chemical element with the Symbol (chemistry), symbol I and atomic number 53. The heaviest of the stable halogens, it exists as a semi-lustrous, non-metallic solid at standard conditions that melts to form a deep violet liquid at , ...
. :Fe + I2 → FeI2 This is in contrast to the other iron(II) halides, which are best prepared by reaction of heated iron with the appropriate
hydrohalic acid In chemistry, hydrogen halides (hydrohalic acids when in the aqueous phase) are diatomic, inorganic compounds that function as Arrhenius acids. The formula is HX where X is one of the halogens: fluorine, chlorine, bromine, iodine, or astatine. A ...
. :Fe + 2HX → FeX2 + H2 In contrast to the ferrous fluoride, chloride and bromide, which form known hydrates, the diiodide is speculated to form a stable tetrahydrate but it not been characterized directly.


Structure

Iron(II) iodide adopts the same
crystal structure In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric pattern ...
as
cadmium iodide Cadmium iodide is the inorganic compound with the formula CdI2. It is a white hygroscopic solid. It also can be obtained as a mono- and tetrahydrate. It has few applications. It is notable for its crystal structure, which is typical for compoun ...
(CdI2).


Reactions

Iron(II) iodide dissolves in water. Dissolving iron metal in
hydroiodic acid Hydroiodic acid (or hydriodic acid) is an aqueous solution of hydrogen iodide (HI). It is a strong acid, one that is ionized completely in an aqueous solution. It is colorless. Concentrated solutions are usually 48% to 57% HI. Reactions Hy ...
is another route to aqueous solutions of iron(II) iodide. Crystalline hydrates precipitate from these solutions.


See also

*
Iron(III) iodide Iron(III) iodide is an inorganic compound with the chemical formula FeI3. It is a thermodynamically unstable compound that is difficult to prepare. Nevertheless, iron(III) iodide has been synthesised in small quantities in the absence of air and ...
, FeI3


References

Iron(II) compounds Iodides Antianemic preparations {{Inorganic-compound-stub