Ingredients of cosmetics
   HOME

TheInfoList



OR:

Cosmetics ingredients come from a variety of sources but, unlike the ingredients of food, are often not considered by most consumers.
Cosmetics Cosmetics are constituted mixtures of chemical compounds derived from either natural sources, or synthetically created ones. Cosmetics have various purposes. Those designed for personal care and skin care can be used to cleanse or protec ...
often use vibrant
color Color (American English) or colour (British English) is the visual perceptual property deriving from the spectrum of light interacting with the photoreceptor cells of the eyes. Color categories and physical specifications of color are associ ...
s that are derived from a wide variety of sources, ranging from crushed insects to rust.Schneider, Günther ''et al'' (2005). "Skin Cosmetics" in ''Ullmann's Encyclopedia of Industrial Chemistry'', Wiley-VCH, Weinheim. Cosmetics in a variety of forms date back to early civilizations, with the need to improve ones personal appearance being an important factor in attracting a mate. Over the years the ingredients have changed dramatically as we discovered how to manufacture our own scents and cosmetic formulas. The realization of the dangers of many common ingredients also greatly affected the growing industry. Ancient Egyptian aristocracy made use of minerals to provide colour and definition to their facial features. During the era of the Greek Empire it was common to use face paints, while cosmetics in ancient Rome contained
starch Starch or amylum is a polymeric carbohydrate consisting of numerous glucose units joined by glycosidic bonds. This polysaccharide is produced by most green plants for energy storage. Worldwide, it is the most common carbohydrate in human die ...
,
olive oil Olive oil is a liquid fat obtained from olives (the fruit of ''Olea europaea''; family Oleaceae), a traditional tree crop of the Mediterranean Basin, produced by pressing whole olives and extracting the oil. It is commonly used in cooking: ...
,
beeswax Beeswax (''cera alba'') is a natural wax produced by honey bees of the genus ''Apis''. The wax is formed into scales by eight wax-producing glands in the abdominal segments of worker bees, which discard it in or at the hive. The hive work ...
,
saffron Saffron () is a spice derived from the flower of ''Crocus sativus'', commonly known as the "saffron crocus". The vivid crimson stigma (botany), stigma and stigma (botany)#style, styles, called threads, are collected and dried for use mainly ...
,
rose water Rose water ( fa, گلاب) is a flavoured water made by steeping rose petals in water. It is the hydrosol portion of the distillate of rose petals, a by-product of the production of rose oil for use in perfume. Rose water is also used to fla ...
, and
lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, ...
.


Common ingredients

Castor oil Castor oil is a vegetable oil pressed from castor beans. It is a colourless or pale yellow liquid with a distinct taste and odor. Its boiling point is and its density is 0.961 g/cm3. It includes a mixture of triglycerides in which about ...
and its derivatives are found in many cosmetics as it is "non-comedogenic" (does not exacerbate or contribute to acne).International Castor Oil Association.
ICOA Technical Bulletins - Effect on Skin
". Accessed 27 January 2007.
Cerebrosides (cells from the nervous systems of cattle or swine) were once used in some high-end skin-care products to increase moisture retention and to create a smooth skin surface, Adams, Cecil. 31 March 2000.
Does lipstick contain fish scales?
. Accessed 24 January 2007.
however the BSE controversy has put an end to this practice. In many countries colors in cosmetics are listed as numbers from the
Colour Index International Colour Index International is a reference database jointly maintained by the Society of Dyers and Colourists and the American Association of Textile Chemists and Colorists. It currently contains over 27,000 individual products listed under 13,0 ...
. The scheme covers colors used in food, personal care products, cosmetics, household products and fabric dyeing. For example,
tartrazine Tartrazine is a synthetic lemon yellow azo dye primarily used as a food coloring. It is also known as E number E102, C.I. 19140, FD&C Yellow 5, Yellow 5 Lake, Acid Yellow 23, Food Yellow 4, and trisodium 1-(4-sulfonatophenyl)-4-(4-sulfonatop ...
is not normally listed as such in lipstick ingredients, but as C.I. 19140. Erythrosine will be listed as C.I. 45430, and so on. In US and Canada colors are listed as FD & C colors. Tartrazine (E102) is FD & C Yellow 5 and erythrosine (E127) is FD & C Red 3.


Visual effects

Strong red colors for eye products have been produced using the
dye A dye is a colored substance that chemically bonds to the substrate to which it is being applied. This distinguishes dyes from pigments which do not chemically bind to the material they color. Dye is generally applied in an aqueous solution and ...
carmine Carmine ()also called cochineal (when it is extracted from the cochineal insect), cochineal extract, crimson lake, or carmine lake is a pigment of a bright-red color obtained from the aluminium complex derived from carminic acid. Specific code ...
, made from
carminic acid Carminic acid (C22H20O13) is a red glucosidal hydroxyanthrapurin that occurs naturally in some scale insects, such as the cochineal, Armenian cochineal, and Polish cochineal. The insects produce the acid as a deterrent to predators. An aluminum s ...
extracted from the crushed bodies of the
cochineal The cochineal ( , ; ''Dactylopius coccus'') is a scale insect in the suborder Sternorrhyncha, from which the natural dye carmine is derived. A primarily sessile parasite native to tropical and subtropical South America through North America ...
insect. Carmine was once the only bright red color permitted by the FDA for use around the eye. Pearlescence, also sometimes spelled as "pearl essence", is a shine or gloss effect commonly used in a wide variety of cosmetic products. The most usual source of pearlescence is the natural
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2 ...
mica Micas ( ) are a group of silicate minerals whose outstanding physical characteristic is that individual mica crystals can easily be split into extremely thin elastic plates. This characteristic is described as perfect basal cleavage. Mica is ...
covered by a thin layer of
titanium dioxide Titanium dioxide, also known as titanium(IV) oxide or titania , is the inorganic compound with the chemical formula . When used as a pigment, it is called titanium white, Pigment White 6 (PW6), or CI 77891. It is a white solid that is insolu ...
. This coating causes
goniochromism Iridescence (also known as goniochromism) is the phenomenon of certain surfaces that appear to gradually change color as the angle of view or the angle of illumination changes. Examples of iridescence include soap bubbles, feathers, butterfly ...
– the color appears through interference effects with the naturally translucent mica, and varying the thickness of the titanium dioxide changes the color.Weingrod, Carmi. 2005.
Three-Dimensional Color – Unlocking the Secrets of Interference Pigments
. Accessed 24 January 2007.
Alternatives exist, including the suspension of tiny flakes of a suitable material within the product, often a wax such as
glycol distearate Glycol distearate is the diester of stearic acid and ethylene glycol. It is mostly commonly encountered in personal care products and cosmetics where it is used to produce pearlescent effects as well as a moisturizer. Synthesis Glycol disteara ...
. A shimmery substance found on
fish scales A fish scale is a small rigid plate that grows out of the skin of a fish. The skin of most jawed fishes is covered with these protective scales, which can also provide effective camouflage through the use of reflection and colouration, as w ...
, most usually obtained from
herring Herring are forage fish, mostly belonging to the family of Clupeidae. Herring often move in large schools around fishing banks and near the coast, found particularly in shallow, temperate waters of the North Pacific and North Atlantic Ocean ...
and one of many by-products of commercial
fish processing The term fish processing refers to the processes associated with fish and fish products between the time fish are caught or harvested, and the time the final product is delivered to the customer. Although the term refers specifically to fish, in ...
, can also be used for pearlescent effects, primarily in nail polish, but is now rarely used due to its high cost, bismuth oxychloride flakes being used as a substitute instead.


Types of cosmetics


Facial cosmetics

The
Romans Roman or Romans most often refers to: *Rome, the capital city of Italy * Ancient Rome, Roman civilization from 8th century BC to 5th century AD *Roman people, the people of ancient Rome *''Epistle to the Romans'', shortened to ''Romans'', a lette ...
and ancient
Egyptians Egyptians ( arz, المَصرِيُون, translit=al-Maṣriyyūn, ; arz, المَصرِيِين, translit=al-Maṣriyyīn, ; cop, ⲣⲉⲙⲛ̀ⲭⲏⲙⲓ, remenkhēmi) are an ethnic group native to the Nile, Nile Valley in Egypt. Egyptian ...
used cosmetics containing mercury.


Foundation

Women of Roman Britain used a foundation made from animal fat, starch and tin oxide.
BBC News BBC News is an operational business division of the British Broadcasting Corporation (BBC) responsible for the gathering and broadcasting of news and current affairs in the UK and around the world. The department is the world's largest broadc ...
. 3 November 2004.
Roman cosmetic secrets revealed
. Accessed 27 January 2007.
Today foundations come in a wide variety of formulas and finishes, most are either water, silicone, or mineral based. Foundations on today's market come in cream, liquid, pressed powder, loose powder, or mineral form. They also come in different finishes such as matte or satin depending upon the desired look.


Lipstick

Lipstick is known to have been used around 5000 years ago in ancient
Babylon ''Bābili(m)'' * sux, 𒆍𒀭𒊏𒆠 * arc, 𐡁𐡁𐡋 ''Bāḇel'' * syc, ܒܒܠ ''Bāḇel'' * grc-gre, Βαβυλών ''Babylṓn'' * he, בָּבֶל ''Bāvel'' * peo, 𐎲𐎠𐎲𐎡𐎽𐎢 ''Bābiru'' * elx, 𒀸𒁀𒉿𒇷 ''Babi ...
, when semi-precious jewels were crushed and applied to the lips and occasionally around the eyes. Ancient Egyptians extracted purplish-red dye from fucus-algin, 0.01%
iodine Iodine is a chemical element with the Symbol (chemistry), symbol I and atomic number 53. The heaviest of the stable halogens, it exists as a semi-lustrous, non-metallic solid at standard conditions that melts to form a deep violet liquid at , ...
, and some
bromine Bromine is a chemical element with the symbol Br and atomic number 35. It is the third-lightest element in group 17 of the periodic table ( halogens) and is a volatile red-brown liquid at room temperature that evaporates readily to form a simi ...
mannite, which resulted in serious illness.
Cleopatra Cleopatra VII Philopator ( grc-gre, Κλεοπάτρα Φιλοπάτωρ}, "Cleopatra the father-beloved"; 69 BC10 August 30 BC) was Queen of the Ptolemaic Kingdom of Egypt from 51 to 30 BC, and its last active ruler.She was also a ...
had her lipstick made from crushed
carmine Carmine ()also called cochineal (when it is extracted from the cochineal insect), cochineal extract, crimson lake, or carmine lake is a pigment of a bright-red color obtained from the aluminium complex derived from carminic acid. Specific code ...
beetles Beetles are insects that form the order Coleoptera (), in the superorder Endopterygota. Their front pair of wings are hardened into wing-cases, elytra, distinguishing them from most other insects. The Coleoptera, with about 400,000 describe ...
, which gave a deep red pigment, and ants for a base. The red color of modern lipstick can come from synthetically derived pure
iron oxide Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of wh ...
(common iron rust), however most leading brands use the more economical synthetic colors. In the United States, every batch of synthetic dye and pigment must have a sample sent to the US FDA for testing and certification that the batch is pure and its contaminants are below the levels specified by law. Synthetic colors are listed in the ingredients as a code (e.g.: F &D red no 6) and may contain up to 10 parts per million of lead / 3 parts per million of arsenic. There is some controversy over the presence of these trace ingredients, especially since makeup worn on the lips is not just absorbed through the skin, but also swallowed with drinking and eating. Since lowering these levels would make the production and sale of practically all lipstick illegal, and since the FDA has determined that the existing levels are safe, the cosmetic industry continues to produce and sell lipstick. Typically, the pigment is crushed very finely (7 to 10
micrometres The micrometre ( international spelling as used by the International Bureau of Weights and Measures; SI symbol: μm) or micrometer (American spelling), also commonly known as a micron, is a unit of length in the International System of Unit ...
) while being mixed with
castor oil Castor oil is a vegetable oil pressed from castor beans. It is a colourless or pale yellow liquid with a distinct taste and odor. Its boiling point is and its density is 0.961 g/cm3. It includes a mixture of triglycerides in which about ...
and is then mixed with a wax base to form a finished lipstick. Lipsticks may be sheer or dense, matte or shiny. In their thinnest and most fluid consistency they are given their own category, lipgloss.


Perfume

Islamic cultures contributed significantly in the development of western
perfume Perfume (, ; french: parfum) is a mixture of fragrant essential oils or aroma compounds (fragrances), fixatives and solvents, usually in liquid form, used to give the human body, animals, food, objects, and living-spaces an agreeable scent ...
ry in both perfecting the extraction of fragrances through steam distillation and introducing new, raw ingredients. Both of the raw ingredients and distillation technology significantly influenced western perfumery and
scientific Science is a systematic endeavor that builds and organizes knowledge in the form of testable explanations and predictions about the universe. Science may be as old as the human species, and some of the earliest archeological evidence for ...
developments, particularly
chemistry Chemistry is the scientific study of the properties and behavior of matter. It is a natural science that covers the elements that make up matter to the compounds made of atoms, molecules and ions: their composition, structure, proper ...
. As traders, Islamic cultures such as the Arabs and Persians had wider access to different spices, herbals, and other fragrance material. In addition to trading them, many of these exotic materials were cultivated by the Muslims such that they can be successfully grown outside of their native climates. Two examples of this include jasmine, which is native to South and Southeast Asia, and various citrus, which are native to East Asia. Both of these ingredients are still highly important in modern perfumery. The
Crusaders The Crusades were a series of religious wars initiated, supported, and sometimes directed by the Latin Church in the medieval period. The best known of these Crusades are those to the Holy Land in the period between 1095 and 1291 that were in ...
brought
alcohol Alcohol most commonly refers to: * Alcohol (chemistry), an organic compound in which a hydroxyl group is bound to a carbon atom * Alcohol (drug), an intoxicant found in alcoholic drinks Alcohol may also refer to: Chemicals * Ethanol, one of sev ...
-based perfumes back to
Europe Europe is a large peninsula conventionally considered a continent in its own right because of its great physical size and the weight of its history and traditions. Europe is also considered a Continent#Subcontinents, subcontinent of Eurasia ...
from the Middle East in the 13th Century.Ad*Access. 1999.
Brief History of Beauty and Hygiene Products
. Accessed 27 January 2007.
The first modern perfume, made of scented oils blended in an alcohol solution, was made in 1370 at the command of Queen Elizabeth of Hungary and was known throughout Europe as Hungary Water.
France France (), officially the French Republic ( ), is a country primarily located in Western Europe. It also comprises of Overseas France, overseas regions and territories in the Americas and the Atlantic Ocean, Atlantic, Pacific Ocean, Pac ...
quickly became the European center of perfume and cosmetic manufacture, cultivating vast amounts of flowers for their essence. By the 18th century, aromatic plants were being specifically grown in the
Grasse Grasse (; Provençal oc, Grassa in classical norm or in Mistralian norm ; traditional it, Grassa) is the only subprefecture of the Alpes-Maritimes department in the Provence-Alpes-Côte-d'Azur region on the French Riviera. In 2017, the c ...
region of
France France (), officially the French Republic ( ), is a country primarily located in Western Europe. It also comprises of Overseas France, overseas regions and territories in the Americas and the Atlantic Ocean, Atlantic, Pacific Ocean, Pac ...
to provide the growing perfume industry with raw materials.


Deodorants and antiperspirants

Perfume has been used to mask body odor for many hundreds of years, but in the late 19th century the ability to reduce such odour was developed. The original active ingredient of antiperspirants was
aluminium chloride Aluminium chloride, also known as aluminium trichloride, is an inorganic compound with the formula . It forms hexahydrate with the formula , containing six water molecules of hydration. Both are colourless crystals, but samples are often contam ...
but complaints of skin irritation led to the increased use of
aluminium chlorohydrate Aluminium chlorohydrate is a group of water-soluble, specific aluminium salts having the general formula Aln Cl(3n-m)( OH)m. It is used in cosmetics as an antiperspirant and as a coagulant in water purification. In water purification, this compou ...
as an alternative. Aluminium has been established as a
neurotoxin Neurotoxins are toxins that are destructive to nerve tissue (causing neurotoxicity). Neurotoxins are an extensive class of exogenous chemical neurological insultsSpencer 2000 that can adversely affect function in both developing and mature nerv ...
and has been shown to adversely affect the
blood–brain barrier The blood–brain barrier (BBB) is a highly selective semipermeable border of endothelial cells that prevents solutes in the circulating blood from ''non-selectively'' crossing into the extracellular fluid of the central nervous system where ne ...
, cause DNA damage, and have adverse
epigenetic In biology, epigenetics is the study of stable phenotypic changes (known as ''marks'') that do not involve alterations in the DNA sequence. The Greek prefix '' epi-'' ( "over, outside of, around") in ''epigenetics'' implies features that are ...
effects. Research has shown that the aluminum salts used in antiperspirants have detrimental effects to a number of species such as non-human
primates Primates are a diverse order of mammals. They are divided into the strepsirrhines, which include the lemurs, galagos, and lorisids, and the haplorhines, which include the tarsiers and the simians ( monkeys and apes, the latter including ...
,
mice A mouse ( : mice) is a small rodent. Characteristically, mice are known to have a pointed snout, small rounded ears, a body-length scaly tail, and a high breeding rate. The best known mouse species is the common house mouse (''Mus musculus'' ...
, dogs and others. An experiment with mice found that applying an aqueous solution of aluminum chloride to the skin resulted in "a significant increase in urine, serum, and whole brain aluminium." Other experiments on pregnant mice showed transplacental passage of aluminum chloride.


Regulation

Legislation varies from country to country but most countries have some sort of formal legislation that either restrict or prohibit certain ingredients or products. There are two main sources for cosmetics safety: the EU Cosmetics Regulation 1223/2009 and the Canadian Cosmetic Ingredient Hotlist. Regulation in the United States by the FDA is particularly weak. A new version of the EU's Cosmetics Directive was adopted by the
European Parliament The European Parliament (EP) is one of the Legislature, legislative bodies of the European Union and one of its seven Institutions of the European Union, institutions. Together with the Council of the European Union (known as the Council and in ...
, 24 March 2009. It includes new rules concerning the use of
nanoparticle A nanoparticle or ultrafine particle is usually defined as a particle of matter that is between 1 and 100 nanometres (nm) in diameter. The term is sometimes used for larger particles, up to 500 nm, or fibers and tubes that are less than 10 ...
s in cosmetics and includes stricter rules on animal testing of cosmetics. In the European Union, all cosmetic products must be notified through the Cosmetic Products Notification Portal (CPNP) before being placed on the EU market. The presence of a nanomaterial in a cosmetic product must be explicitly stated in the notification to the European Commission. A list of nanomaterial cosmetics ingredients was published by the European Commission, and the European Union Observatory for Nanomaterials (EUON) provides further information on these ingredients, including information derived from the application of the REACH regulation on chemicals. Cosmetic colorants, with the exception of hair colorants in the United States, are highly regulated. Each country or group of countries has their own regulatory agency that controls what can go into cosmetics. In the United States, the regulating body is the
Food and Drug Administration The United States Food and Drug Administration (FDA or US FDA) is a federal agency of the Department of Health and Human Services. The FDA is responsible for protecting and promoting public health through the control and supervision of food ...
. Aside from color additives, cosmetic products and their ingredients are not subject to FDA regulation prior to their release into the market. It is only when a product is found to violate Federal Food, Drug, and Cosmetic Act (FD&C Act) and Fair Packaging and Labeling Act (FPLA) after its release that the FDA may start taking action against this violation. The FDA may request a recall if the company refuses to remove an unsafe product from the market, work with the Department of Justice to remove contaminated or misbranded products, request a restraining order to prevent further shipments of contaminated or misbranded products, and take action against the company violating the law. A company may use any ingredient, other than color additives and those ingredients banned from use in cosmetics through regulation, as long the completed product and its ingredients is safe, is properly labeled, and isn't contaminated or misbranded under the FD&C Act and the FPLA. FDA can and does perform inspections.


Potential dangers

The search for new ingredients and products often brings controversy, typically over ingredients whose function is unproven or disputed. There are a few potential dangers regarding the use of cosmetics. One such danger is the use of old mascara. Some mascaras contain an ingredient that breaks down to produce
formaldehyde Formaldehyde ( , ) ( systematic name methanal) is a naturally occurring organic compound with the formula and structure . The pure compound is a pungent, colourless gas that polymerises spontaneously into paraformaldehyde (refer to section ...
. The formaldehyde prevents the growth of bacteria. Aged mascara, however, may no longer be producing formaldehyde, allowing bacteria to proliferate. For this reason, it is often recommended to replace a tube of mascara every few months. In one well-known case,
Buddy Ebsen Buddy Ebsen (born Christian Ludolf Ebsen Jr., April 2, 1908 – July 6, 2003), also known as Frank "Buddy" Ebsen, was an American actor and dancer, whose career spanned seven decades. One of his most famous roles was as Jed Clampett in the CBS ...
was originally cast as the "Tin Man" in '' The Wizard of Oz''. Aluminum dust was used to create a tin effect. As the result of an allergic reaction, he was hospitalized and
Jack Haley John Joseph Haley Jr. (August 10, 1897 – June 6, 1979) was an American actor, comedian, dancer, radio host, singer and vaudevillian. He was best known for his portrayal of the Tin Man and his farmhand counterpart Hickory in the 1939 Metro-G ...
replaced him. Aluminum dust was, instead, added to a paste.


See also

* List of cosmetic ingredients *
List of vegetable oils Vegetable oils are triglycerides extracted from plants. Some of these oils have been part of human culture for millennia. Edible vegetable oils are used in food, both in cooking and as supplements. Many oils, edible and otherwise, are burned as ...
*
Palm oil Palm oil is an edible vegetable oil derived from the mesocarp (reddish pulp) of the fruit of the oil palms. The oil is used in food manufacturing, in beauty products, and as biofuel. Palm oil accounted for about 33% of global oils produced fr ...
* International Nomenclature of Cosmetic Ingredients (INCI) *
Testing cosmetics on animals Cosmetic testing on animals is a type of animal testing used to test the safety and hypoallergenic properties of cosmetic products for use by humans. Since this type of animal testing is often harmful to the animal subjects, it is opposed by an ...


References


External links


Cosmetic Safety Database
{{DEFAULTSORT:Ingredients Of Cosmetics History of cosmetics