Hydroxyl-terminated polybutadiene (HTPB) is an

oligomer In chemistry and biochemistry, an oligomer () is a molecule that consists of a few repeating units which could be derived, actually or conceptually, from smaller molecules, monomers.Quote: ''Oligomer molecule: A molecule of intermediate relativ ...

butadiene 1,3-Butadiene () is the organic compound with the formula (CH2=CH)2. It is a colorless gas that is easily condensed to a liquid. It is important industrially as a precursor to synthetic rubber. The molecule can be viewed as the union of two viny ...

terminated at each end with a

hydroxyl In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical formula and composed of one oxygen atom covalently bonded to one hydrogen atom. In organic chemistry, alcohols and carboxylic acids contain one or more hydroxy ...

functional group In organic chemistry, a functional group is a substituent or moiety in a molecule that causes the molecule's characteristic chemical reactions. The same functional group will undergo the same or similar chemical reactions regardless of the rest ...

. It reacts with

isocyanates In organic chemistry, isocyanate is the functional group with the formula . Organic compounds that contain an isocyanate group are referred to as isocyanates. An organic compound with two isocyanate groups is known as a diisocyanate. Diisocyan ...

to form polyurethane polymers. HTPB is a translucent liquid with a color similar to wax paper and a viscosity similar to corn syrup. The properties vary because HTPB is a

mixture In chemistry, a mixture is a material made up of two or more different chemical substances which are not chemically bonded. A mixture is the physical combination of two or more substances in which the identities are retained and are mixed in the ...

rather than a pure compound, and it is manufactured to meet customers' specific requirements. A typical HTPB is R-45HTLO. This product consists of oligomeric units typically containing 40–50 butadiene molecules bonded together, with each end of the chain terminated with a hydroxyl Hgroup: 1,3-Butadiene Polymerization

R-45HTLO has a functionality of 2.4-2.6, which means that there is (approximately) one additional hydroxyl group located along the chain for every two oligomeric units. This provides side-to-side linkage for a stronger cured product. HTPB is usually cured by an addition reaction with di- or poly- isocyanate compounds.

Uses

Materials Production

Polyurethanes prepared from HTPB can be engineered for specific physical properties; polyurethanes may be highly elastic or tough and rigid. Some products include: rigid foam insulation panels; durable elastomeric wheels and tires (used for

roller coaster A roller coaster, or rollercoaster, is a type of amusement ride that employs a form of elevated railroad track designed with tight turns, steep slopes, and sometimes inversions. Passengers ride along the track in open cars, and the rides are o ...

escalator An escalator is a moving staircase which carries people between floors of a building or structure. It consists of a motor-driven chain of individually linked steps on a track which cycle on a pair of tracks which keep the step tread horizo ...

s, skateboards, etc.); automotive suspension bushings; electrical potting compounds; high-performance

adhesive Adhesive, also known as glue, cement, mucilage, or paste, is any non-metallic substance applied to one or both surfaces of two separate items that binds them together and resists their separation. The use of adhesives offers certain advant ...

s; surface coatings and surface sealants;

synthetic fibers Synthetic fibers or synthetic fibres (in British English; see spelling differences) are fibers made by humans through chemical synthesis, as opposed to natural fibers that are directly derived from living organisms, such as plants (like cotton) ...

(e.g., Spandex);

carpet A carpet is a textile floor covering typically consisting of an upper layer of pile attached to a backing. The pile was traditionally made from wool, but since the 20th century synthetic fibers such as polypropylene, nylon, or polyester hav ...

underlay; hard-plastic parts (e.g., for electronic instruments).

Rocket Propellant

An important application of HTPB is in solid rocket propellant. It binds the

oxidizing agent An oxidizing agent (also known as an oxidant, oxidizer, electron recipient, or electron acceptor) is a substance in a redox chemical reaction that gains or "Electron acceptor, accepts"/"receives" an electron from a (called the , , or ). In ot ...

, fuel and other ingredients into a solid but elastic mass in most composite propellant systems. The cured polyurethane acts as a fuel in such mixtures. For example, HTPB is used in all 3/4 stages of the Japanese M-5 rocket satellite launchers and PSLV rocket developed by

ISRO The Indian Space Research Organisation (ISRO; ) is the national space agency of India, headquartered in Bengaluru. It operates under the Department of Space (DOS) which is directly overseen by the Prime Minister of India, while the Chairman ...

for satellite launches.

JAXA The is the Japanese national air and space agency. Through the merger of three previously independent organizations, JAXA was formed on 1 October 2003. JAXA is responsible for research, technology development and launch of satellites into orb ...

describes the propellant as "HTPB/AP/Al=12/68/20", which means, proportioned by mass, HTPB plus curative 12% (binder and fuel),

ammonium perchlorate Ammonium perchlorate ("AP") is an inorganic compound with the formula NH4 ClO4. It is a colorless or white solid that is soluble in water. It is a powerful oxidizer. Combined with a fuel, it can be used as a rocket propellant called ammonium pe ...

68% (oxidizer), and

aluminum Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It has ...

powder 20% (fuel). Similar propellants, often referred to as APCP (

ammonium perchlorate composite propellant Ammonium perchlorate composite propellant (APCP) is a solid-propellant rocket fuel. It differs from many traditional solid rocket propellants such as black powder or zinc-sulfur, not only in chemical composition and overall performance but also ...

) are used in larger model rockets. A typical APCP produces 2–3 times the specific impulse of the

black powder Gunpowder, also commonly known as black powder to distinguish it from modern smokeless powder, is the earliest known chemical explosive. It consists of a mixture of sulfur, carbon (in the form of charcoal) and potassium nitrate (saltpeter). Th ...

propellant used in most smaller rocket motors.

Rocketry Rocketry may refer to: Science and technology * The design and construction of rockets ** The hobbyist or (semi-)professional use of model rockets * Aerospace engineering, also known as rocket science * Amateur rocketry, a hobby in which partici ...

is an important factor for the sale of HTPB. While used in

Solid-propellant rocket A solid-propellant rocket or solid rocket is a rocket with a rocket engine that uses Rocket propellant#Solid chemical propellants, solid propellants (fuel/oxidizer). The earliest rockets were solid-fuel rockets powered by gunpowder; they were u ...

's the Rocket Propellant is also moderately used as a hybrid rocket fuel. When combined with Nitrous Oxide, as the

Oxidizer An oxidizing agent (also known as an oxidant, oxidizer, electron recipient, or electron acceptor) is a substance in a redox chemical reaction that gains or " accepts"/"receives" an electron from a (called the , , or ). In other words, an oxid ...

it can be used for both land vehicles and rockets. HTPB is also used as a hybrid rocket fuel. With N₂O (

nitrous oxide Nitrous oxide (dinitrogen oxide or dinitrogen monoxide), commonly known as laughing gas, nitrous, or nos, is a chemical compound, an oxide of nitrogen with the formula . At room temperature, it is a colourless non-flammable gas, and has a ...

, or "laughing gas") as the oxidizer, it is used to power the

SpaceShipTwo The Scaled Composites Model 339 SpaceShipTwo (SS2) is an air-launched suborbital spaceplane type designed for space tourism. It is manufactured by The Spaceship Company, a California-based company owned by Virgin Galactic. SpaceShipTwo is car ...

hybrid rocket motor developed by SpaceDev. The land speed record attempt Bloodhound SSC was to have used HTPB with a

high-test peroxide High-test peroxide (HTP) is a highly concentrated (85 to 98%) solution of hydrogen peroxide, with the remainder consisting predominantly of water. In contact with a catalyst, it decomposes into a high-temperature mixture of steam and oxygen, with n ...

oxidizer, but that plan was altered in 2017.

References

External links

{{Commons category
US Patent 5159123
description of synthesis and other details. Polyols Organic polymers Rocket fuels