Hydrometer
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A hydrometer or lactometer is an instrument used for measuring density or
relative density Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water at its densest ...
of liquids based on the concept of
buoyancy Buoyancy (), or upthrust, is an upward force exerted by a fluid that opposes the weight of a partially or fully immersed object. In a column of fluid, pressure increases with depth as a result of the weight of the overlying fluid. Thus the ...
. They are typically calibrated and graduated with one or more scales such as
specific gravity Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water at its dens ...
. A hydrometer usually consists of a sealed hollow glass tube with a wider bottom portion for
buoyancy Buoyancy (), or upthrust, is an upward force exerted by a fluid that opposes the weight of a partially or fully immersed object. In a column of fluid, pressure increases with depth as a result of the weight of the overlying fluid. Thus the ...
, a ballast such as
lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, ...
or mercury for stability, and a narrow stem with graduations for measuring. The liquid to test is poured into a tall container, often a graduated cylinder, and the hydrometer is gently lowered into the liquid until it floats freely. The point at which the surface of the liquid touches the stem of the hydrometer correlates to relative density. Hydrometers can contain any number of scales along the stem corresponding to properties correlating to the density. Hydrometers are calibrated for different uses, such as a lactometer for measuring the density (creaminess) of milk, a saccharometer for measuring the density of sugar in a liquid, or an alcoholometer for measuring higher levels of alcohol in spirits. The hydrometer makes use of Archimedes' principle: a solid suspended in a fluid is buoyed by a force equal to the weight of the fluid displaced by the submerged part of the suspended solid. The lower the density of the fluid, the deeper a hydrometer of a given weight sinks; the stem is calibrated to give a numerical reading.


History

upright=0.6, Hydrometer from Practical Physics The hydrometer probably dates back to the Greek philosopher
Archimedes Archimedes of Syracuse (;; ) was a Greek mathematician, physicist, engineer, astronomer, and inventor from the ancient city of Syracuse in Sicily. Although few details of his life are known, he is regarded as one of the leading scientis ...
(3rd century BC) who used its principles to find the density of various liquids. An early description of a hydrometer comes from a Latin poem, written in the 2nd century AD by Remnius, who compared the use of a hydrometer to the method of fluid displacement used by Archimedes to determine the gold content of Hiero II's crown. Hypatia of Alexandria (4th-5th century AD), an important female Greek mathematician, is the first person traditionally associated with the hydrometer. In a letter,
Synesius of Cyrene Synesius (; el, Συνέσιος; c. 373 – c. 414), was a Greek bishop of Ptolemais in ancient Libya, a part of the Western Pentapolis of Cyrenaica after 410. He was born of wealthy parents at Balagrae (now Bayda, Libya) near Cyrene between ...
asks Hypatia, his teacher, to make a hydrometer for him:
The instrument in question is a cylindrical tube, which has the shape of a flute and is about the same size. It has notches in a perpendicular line, by means of which we are able to test the weight of the waters. A cone forms a lid at one of the extremities, closely fitted to the tube. The cone and the tube have one base only. This is called the baryllium. Whenever you place the tube in water, it remains erect. You can then count the notches at your ease, and in this way ascertain the weight of the water.
According to the ''Encyclopedia of the History of Arabic Science'', it was used by Abū Rayhān al-Bīrūnī in the 11th century and described by Al-Khazini in the 12th century. It was rediscovered in 1612 by Galileo and his circle of friends, and used in experiments especially at the Accademia del Cimento. It appeared again in the 1675 work of Robert Boyle (who coined the name ''"hydrometer"''), with types devised by
Antoine Baumé Antoine Baumé (26 February 172815 October 1804) was a French chemist. Life He was born at Senlis. He was apprenticed to the chemist Claude Joseph Geoffroy, and in 1752 was admitted a member of the École de Pharmacie, where in the same year h ...
(the Baumé scale), William Nicholson, and Jacques Alexandre César Charles in the late 18th century, more or less contemporarily with
Benjamin Sikes Bartholomew Sikes (died 1803) was an officer in the employ of HM Excise who in the late 18th century perfected a device by which the alcoholic content of a liquid can be measured. The success of the device caused his name to be immortalised in an ...
' discovery of the device by which the alcoholic content of a liquid can be automatically determined. The use of the Sikes device was made obligatory by British law in 1818.


Ranges

The hydrometer sinks deeper in low-density liquids such as
kerosene Kerosene, paraffin, or lamp oil is a combustible hydrocarbon liquid which is derived from petroleum. It is widely used as a fuel in aviation as well as households. Its name derives from el, κηρός (''keros'') meaning " wax", and was re ...
,
gasoline Gasoline (; ) or petrol (; ) (see ) is a transparent, petroleum-derived flammable liquid that is used primarily as a fuel in most spark-ignited internal combustion engines (also known as petrol engines). It consists mostly of organic c ...
, and alcohol, and less deep in high-density liquids such as brine,
milk Milk is a white liquid food produced by the mammary glands of mammals. It is the primary source of nutrition for young mammals (including breastfed human infants) before they are able to digest solid food. Immune factors and immune-modulat ...
, and acids. It is usual for hydrometers to be used with dense liquids to have the mark 1.000 (for water) near the top of the stem, and those for use with lighter liquids to have 1.000 near the bottom. In many industries a set of hydrometers is used (1.0–0.95, 0.95–.) to have instruments covering the range of specific gravities that may be encountered.


Scales

Modern hydrometers usually measure
specific gravity Relative density, or specific gravity, is the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for liquids is nearly always measured with respect to water at its dens ...
but different scales were (and sometimes still are) used in certain industries. Examples include: *
API gravity The American Petroleum Institute gravity, or API gravity, is a measure of how heavy or light a petroleum liquid is compared to water: if its API gravity is greater than 10, it is lighter and floats on water; if less than 10, it is heavier and sink ...
, universally used worldwide by the petroleum industry. * Baumé scale, formerly used in industrial chemistry and pharmacology *
Brix Degrees Brix (symbol °Bx) is a measure of the dissolved solids in a liquid, and is commonly used to measure dissolved sugar content of an aqueous solution. One degree Brix is 1 gram of sucrose in 100 grams of solution and represents the strength ...
scale, primarily used in fruit juice, wine making and the sugar industry * Oechsle scale, used for measuring the density of grape must * Plato scale, primarily used in
brewing Brewing is the production of beer by steeping a starch source (commonly cereal grains, the most popular of which is barley) in water and fermenting the resulting sweet liquid with yeast. It may be done in a brewery by a commercial brewer ...
*
Twaddell scale The Twaddell scale is a hydrometer scale for reporting the measured specific gravity of a liquid relative to water. On this scale, a specific gravity of 1.000 is reported as 0, and 2.000 reports as 200. Concentrated sulfuric acid with a specific gr ...
, formerly used in the bleaching and dyeing industries


Specialized hydrometers

Specialized hydrometers are frequently named for their use: a lactometer, for example, is a hydrometer designed especially for use with dairy products. They are sometimes referred to by this specific name, sometimes as hydrometers.


Alcoholometer

An alcoholmeter is a hydrometer that indicates the alcoholic strength of liquids which are essentially a mixture of alcohol and water. It is also known as a ''proof and Tralles hydrometer'' (after
Johann Georg Tralles Johann Georg Tralles (15 October 1763 – 19 November 1822) was a German mathematician and physicist. He was born in Hamburg, Germany and was educated at the University of Göttingen beginning in 1783. He became a professor at the University ...
, but commonly misspelled as traille and tralle). It measures the density of the fluid. Where no sugar or other dissolved substances are present, the specific gravity of a solution of ethanol in water can be directly correlated to the concentration of alcohol. Saccharometers for measuring sugar-water mixtures measure densities greater than water. Many have scales marked with volume percents of "potential alcohol", based on a pre-calculated specific gravity. A higher "potential alcohol" reading on this scale is caused by a greater specific gravity, assumed to be caused by the introduction of dissolved sugars or carbohydrate based material. A reading is taken before and after fermentation and approximate alcohol content is determined by subtracting the post fermentation reading from the pre-fermentation reading.


Lactometer

A lactometer is used to check purity of cow's milk. The specific gravity of milk does not give a conclusive indication of its composition since milk contains a variety of substances that are either heavier or lighter than water. Additional tests for fat content are necessary to determine overall composition. The instrument is graduated into a hundred parts. Milk is poured in and allowed to stand until the cream has formed, then the depth of the cream deposit in degrees determines the quality of the milk. If the milk sample is pure, the lactometer floats; if it is adulterated or impure, the lactometer sinks.


Saccharometer

A saccharometer is a hydrometer used for determining the amount of sugar in a solution, invented by
Thomas Thomson Thomas Thomson may refer to: * Tom Thomson (1877–1917), Canadian painter * Thomas Thomson (apothecary) (died 1572), Scottish apothecary * Thomas Thomson (advocate) (1768–1852), Scottish lawyer * Thomas Thomson (botanist) (1817–1878), Scottish ...
. It is used primarily by winemakers and brewers, and it can also be used in making sorbets and ice-creams. The first brewers' saccharometer was constructed by Benjamin Martin (with distillation in mind), and initially used for brewing by James Baverstock Sr in 1770. Henry Thrale adopted its use and it was later popularized by John Richardson in 1784. It consists of a large weighted glass bulb with a thin stem rising from the top with calibrated markings. The sugar level can be determined by reading the value where the surface of the liquid crosses the scale. The higher the sugar content, the denser the solution, and thus the higher the bulb will float.


Thermohydrometer

A thermohydrometer is a hydrometer that has a
thermometer A thermometer is a device that measures temperature or a temperature gradient (the degree of hotness or coldness of an object). A thermometer has two important elements: (1) a temperature sensor (e.g. the bulb of a mercury-in-glass thermometer ...
enclosed in the float section. For measuring the density of petroleum products, such as fuel oils, the specimen is usually heated in a temperature jacket with a thermometer placed behind it since density is dependent on temperature. Light oils are placed in cooling jackets, typically at 15 °C. Very light oils with many volatile components are measured in a variable volume container using a floating piston sampling device to minimize light end losses.


Battery hydrometer

The state of charge of a lead-acid battery can be estimated from the density of the sulfuric acid solution used as electrolyte. A hydrometer calibrated to read specific gravity relative to water at is a standard tool for servicing automobile batteries. Tables are used to correct the reading to the standard temperature. Hydrometers are also used for maintenance of wet-cell nickel-cadmium batteries to ensure the electrolyte is of the proper strength for the application; for this battery chemistry the specific gravity of the electrolyte is not related to the state of charge of the battery. A battery hydrometer with thermometer (thermohydrometer) measures the temperature-compensated specific gravity and electrolyte temperature.


Antifreeze tester

Another automotive use of hydrometers is testing the quality of the antifreeze solution used for engine cooling. The degree of freeze protection can be related to the density (and so concentration) of the antifreeze; different types of antifreeze have different relations between measured density and freezing point.


Acidometer

An acidometer (sometimes spelled acidimeter) is a hydrometer used to measure the specific gravity of an acid.


Barkometer

A barkometer is calibrated to test the strength of tanning liquors used in tanning
leather Leather is a strong, flexible and durable material obtained from the tanning, or chemical treatment, of animal skins and hides to prevent decay. The most common leathers come from cattle, sheep, goats, equine animals, buffalo, pigs and hog ...
.


Salinometer

A salinometer is a hydrometer used to measure the salt content of the feed water to a marine steam boiler.


Urinometer

A
urinometer An Urinometer is a simple piece of equipment for determining urine specific gravity. Description A typical urinometer is composed of a float, a weight, and a stem. The float is an air-filled glass tube, ending in the weight on the left and the s ...
is a medical hydrometer designed for
urinalysis Urinalysis, a portmanteau of the words ''urine'' and ''analysis'', is a panel of medical tests that includes physical (macroscopic) examination of the urine, chemical evaluation using urine test strips, and microscopic examination. Macroscopic e ...
. As urine's specific gravity is dictated by its ratio of solutes (wastes) to water, a urinometer makes it possible to quickly assess a patient's overall level of hydration.


Gallery

Hydrometer in a still (cropped).jpg, An alcohol meter in a still. Densimetro o galattometro con custodia - Musei del cibo - Parmigiano - 314a.jpg, Lactometer Battery condition indicator.jpg, Battery condition indicator to measure the charge of the battery (~1985). Coolant indicator.jpg, Antifreeze tester measures the freezing point of engine coolant.


Use in soil analysis

A hydrometer analysis is the process by which fine-grained soils,
silt Silt is granular material of a size between sand and clay and composed mostly of broken grains of quartz. Silt may occur as a soil (often mixed with sand or clay) or as sediment mixed in suspension with water. Silt usually has a floury feel ...
s and
clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay pa ...
s, are graded. Hydrometer analysis is performed if the grain sizes are too small for sieve analysis. The basis for this test is Stoke's Law for falling spheres in a viscous fluid in which the terminal velocity of fall depends on the grain diameter and the densities of the grain in suspension and of the fluid. The grain diameter thus can be calculated from a knowledge of the distance and time of fall. The hydrometer also determines the specific gravity (or density) of the suspension, and this enables the percentage of particles of a certain equivalent particle diameter to be calculated.Fakhry A. Assaad, Philip Elmer LaMoreaux, Travis H. Hughes (ed.), '' Field Methods for Geologists and Hydrogeologists'', Springer Science & Business Media, 2004 , p.299


See also

* Density meter * Densitometer * Dasymeter *
Elevator paradox (physics) {{about, the elevator paradox in the hydrometer, the elevator paradox in the transportation device, Elevator paradox The elevator paradox relates to a hydrometer placed on an "elevator" or vertical conveyor that, by moving to different elevations, ...
*
Fahrenheit hydrometer The Fahrenheit hydrometer is a device used to measure the density of a liquid. It was invented by Daniel Gabriel Fahrenheit (1686–1736), better known for his work in thermometry. Operation The Fahrenheit hydrometer is a constant-volume de ...
*
Gravity (beer) Gravity, in the context of fermenting alcoholic beverages, refers to the specific gravity (abbreviated SG), or relative density compared to water, of the wort or must at various stages in the fermentation. The concept is used in the brewing and ...
* Hydrostatic bubbles * Oscillating U-tube * Pyknometer


References


Sources


Hypatia of AlexandriaHydrometer InformationGuide to Brewing Hydrometers
*Jurjen Draaijer

''Milk Producer Group Resource Book'', Food and Agriculture Organization of the United Nations
Using Your Hydrometer
Winemaking Home Page.

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