Hydrogen vehicle
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A hydrogen vehicle is a vehicle that uses hydrogen fuel for motive power. Hydrogen vehicles include hydrogen-fueled
space rocket A launch vehicle or carrier rocket is a rocket designed to carry a payload (spacecraft or satellites) from the Earth's surface to outer space. Most launch vehicles operate from a launch pads, supported by a launch control center and system ...
s, as well as
ship A ship is a large watercraft that travels the world's oceans and other sufficiently deep waterways, carrying cargo or passengers, or in support of specialized missions, such as defense, research, and fishing. Ships are generally distinguished ...
s and
aircraft An aircraft is a vehicle that is able to flight, fly by gaining support from the Atmosphere of Earth, air. It counters the force of gravity by using either Buoyancy, static lift or by using the Lift (force), dynamic lift of an airfoil, or in ...
. Power is generated by converting the
chemical energy Chemical energy is the energy of chemical substances that is released when they undergo a chemical reaction and transform into other substances. Some examples of storage media of chemical energy include batteries, Schmidt-Rohr, K. (2018). "How ...
of hydrogen to mechanical energy, either by reacting hydrogen with oxygen in a fuel cell to power
electric motor An electric motor is an electrical machine that converts electrical energy into mechanical energy. Most electric motors operate through the interaction between the motor's magnetic field and electric current in a wire winding to generate f ...
s or, less commonly, by burning hydrogen in an internal combustion engine. , there are two models of hydrogen cars publicly available in select markets: the
Toyota Mirai The (from , Japanese for 'future') is a mid-size hydrogen fuel cell vehicle (FCV) manufactured by Toyota, and is one of the first FCV automobiles to be mass-produced and sold commercially. The Mirai was unveiled at the November 2014 Los Ang ...
(2014–), which is the world's first mass-produced dedicated fuel cell electric vehicle (FCEV), and the Hyundai Nexo (2018–). There are also fuel cell buses. Hydrogen aircraft are not expected to carry many passengers long haul before the 2030s at the earliest. As of 2019, 98% of hydrogen is produced by
steam methane reforming Steam reforming or steam methane reforming (SMR) is a method for producing syngas ( hydrogen and carbon monoxide) by reaction of hydrocarbons with water. Commonly natural gas is the feedstock. The main purpose of this technology is hydrogen prod ...
, which emits carbon dioxide. It can be produced by electrolysis of water, or by
thermochemical Thermochemistry is the study of the heat energy which is associated with chemical reactions and/or phase changes such as melting and boiling. A reaction may release or absorb energy, and a phase change may do the same. Thermochemistry focuses on ...
or pyrolytic means using renewable feedstocks, but the processes are currently expensive.Romm, Joseph
Tesla Trumps Toyota: Why Hydrogen Cars Can’t Compete With Pure Electric Cars"
,
ThinkProgress ''ThinkProgress'' was an American progressive news website that was active from 2005 to 2019. It was a project of the Center for American Progress Action Fund (CAP Action), a progressive public policy research and advocacy organization. Founded ...
, August 5, 2014.
Various technologies are being developed that aim to deliver costs low enough, and quantities great enough, to compete with hydrogen production using natural gas. Vehicles running on hydrogen technology benefit from a long range on a single refuelling, but are subject to several drawbacks: high carbon emissions when hydrogen is produced from natural gas, capital cost burden, low energy content per unit volume at ambient conditions, production and compression of hydrogen, the investment required to build refuelling infrastructure around the world to dispense hydrogen, and transportation of hydrogen.Cox, Julian
"Time To Come Clean About Hydrogen Fuel Cell Vehicles"
, CleanTechnica.com, June 4, 2014


Vehicles

Automobiles,
buses A bus (contracted from omnibus, with variants multibus, motorbus, autobus, etc.) is a road vehicle that carries significantly more passengers than an average car or van. It is most commonly used in public transport, but is also in use for char ...
, forklifts, trains,
canal boats Canals or artificial waterways are waterways or engineered channels built for drainage management (e.g. flood control and irrigation) or for conveyancing water transport vehicles (e.g. water taxi). They carry free, calm surface flow un ...
, ships, aeroplanes,
submarine A submarine (or sub) is a watercraft capable of independent operation underwater. It differs from a submersible, which has more limited underwater capability. The term is also sometimes used historically or colloquially to refer to remotely op ...
s, and
rocket A rocket (from it, rocchetto, , bobbin/spool) is a vehicle that uses jet propulsion to accelerate without using the surrounding air. A rocket engine produces thrust by reaction to exhaust expelled at high speed. Rocket engines work entir ...
s can run on hydrogen, in various forms.
NASA The National Aeronautics and Space Administration (NASA ) is an independent agency of the US federal government responsible for the civil space program, aeronautics research, and space research. NASA was established in 1958, succeedin ...
used hydrogen to launch
Space Shuttle The Space Shuttle is a retired, partially reusable low Earth orbital spacecraft system operated from 1981 to 2011 by the U.S. National Aeronautics and Space Administration (NASA) as part of the Space Shuttle program. Its official program n ...
s into space. A working toy model car runs on solar power, using a regenerative fuel cell to store energy in the form of hydrogen and
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements ...
gas. It can then convert the fuel back into water to release the solar energy.


Aeroplanes

Companies such as
Boeing The Boeing Company () is an American multinational corporation that designs, manufactures, and sells airplanes, rotorcraft, rockets, satellites, telecommunications equipment, and missiles worldwide. The company also provides leasing and ...
,
Lange Aviation Lange Aviation GmbH is a German company that manufactures gliders and develops electric power-plants for other aircraft. It was founded by its present managing director, Axel Lange, in 1996 as Lange Flugzeugbau GmbH in Zweibrücken. The company cu ...
, and the German Aerospace Center pursue hydrogen as fuel for crewed and uncrewed aeroplanes. In February 2008 Boeing tested a crewed flight of a small aircraft powered by a hydrogen fuel cell. Uncrewed hydrogen planes have also been tested. For large passenger aeroplanes, ''
The Times ''The Times'' is a British daily national newspaper based in London. It began in 1785 under the title ''The Daily Universal Register'', adopting its current name on 1 January 1788. ''The Times'' and its sister paper '' The Sunday Times'' ( ...
'' reported that "Boeing said that hydrogen fuel cells were unlikely to power the engines of large passenger jet aeroplanes but could be used as backup or auxiliary power units onboard." In July 2010, Boeing unveiled its hydrogen-powered Phantom Eye
UAV An unmanned aerial vehicle (UAV), commonly known as a drone, is an aircraft without any human pilot, crew, or passengers on board. UAVs are a component of an unmanned aircraft system (UAS), which includes adding a ground-based controller ...
, powered by two Ford internal-combustion engines that have been converted to run on hydrogen. In Britain, the Reaction Engines A2 has been proposed to use the thermodynamic properties of
liquid hydrogen Liquid hydrogen (LH2 or LH2) is the liquid state of the element hydrogen. Hydrogen is found naturally in the molecular H2 form. To exist as a liquid, H2 must be cooled below its critical point of 33  K. However, for it to be in a fully l ...
to achieve very high speed, long distance (antipodal) flight by burning it in a precooled jet engine.


Automobiles

, there are two hydrogen cars publicly available in select markets: the
Toyota Mirai The (from , Japanese for 'future') is a mid-size hydrogen fuel cell vehicle (FCV) manufactured by Toyota, and is one of the first FCV automobiles to be mass-produced and sold commercially. The Mirai was unveiled at the November 2014 Los Ang ...
and the Hyundai Nexo. The
Honda Clarity The Honda Clarity is a nameplate used by Honda on alternative fuel vehicles. It was initially used only on hydrogen fuel-cell electric vehicles such as the 2008 Honda FCX Clarity, but in 2017 the nameplate was expanded to include the battery-el ...
was produced from 2016 to 2021. In 2013 the
Hyundai Tucson FCEV The Hyundai ix35 FCEV or Tucson FCEV is a hydrogen fuel cell electric vehicle developed by Hyundai. The model is a left-hand drive only conversion to the SUV platform it is based on and was the first of its type to be mass-produced and sold comm ...
was launched, it was a conversion of the Tucson and available in left-hand drive only and became the first commercially mass-produced vehicle of its type in the world. Hyundai Nexo, which succeeded the Tucson in 2018, was selected as the "safest SUV" by the Euro NCAP in 2018 and was rated as "Good" in a side crash test conducted by the Insurance Institute for Highway Safety (IIHS) Toyota launched the world's first dedicated mass-produced fuel cell vehicle (FCV), the Mirai, in Japan at the end of 2014 and began sales in California, mainly the Los Angeles area and also in selected markets in Europe, the UK, Germany and Denmark later in 2015.Voelcker, John
"Decades Of Promises: 'Dude, Where's My Hydrogen Fuel-Cell Car?'"
, Yahoo.com, March 31, 2015
The car has a range of and takes about five minutes to refill its hydrogen tank. The initial sale price in Japan was about 7 million yen ($69,000). Former European Parliament President
Pat Cox Patrick Cox (born 28 November 1952) is a former Irish Fine Gael politician, journalist and television current affairs presenter who served as President of the European Parliament from 2002 to 2004 and Leader of the European Liberal Democrat a ...
estimated that Toyota would initially lose about $100,000 on each Mirai sold.Ayre, James
"Toyota To Lose $100,000 On Every Hydrogen FCV Sold?"
, CleanTechnica.com, November 19, 2014; and Blanco, Sebastian
"Bibendum 2014: Former EU President says Toyota could lose 100,000 euros per hydrogen FCV sedan"
, GreenAutoblog.com, November 12, 2014
At the end of 2019, Toyota had sold over 10,000 Mirais."Realising the hydrogen economy"
''Power Technology'', 11 October 2019
Many automobile companies have introduced demonstration models in limited numbers (see List of fuel cell vehicles and List of hydrogen internal combustion engine vehicles).Whoriskey, Peter
"The Hydrogen Car Gets Its Fuel Back"
, ''Washington Post'', October 17, 2009
In 2013 BMW leased hydrogen technology from Toyota, and a group formed by
Ford Motor Company Ford Motor Company (commonly known as Ford) is an American multinational automobile manufacturer headquartered in Dearborn, Michigan, United States. It was founded by Henry Ford and incorporated on June 16, 1903. The company sells automobi ...
,
Daimler AG The Mercedes-Benz Group AG (previously named Daimler-Benz, DaimlerChrysler and Daimler) is a German multinational automotive corporation headquartered in Stuttgart, Baden-Württemberg, Germany. It is one of the world's leading car manufactu ...
, and Nissan announced a collaboration on hydrogen technology development. By 2017, however, Daimler had abandoned hydrogen vehicle development, and most of the automobile companies developing hydrogen cars had switched their focus to battery electric vehicles. By 2020, all but three automobile companies had abandoned plans to manufacture hydrogen cars.Morris, Charles
"Why Are 3 Automakers Still Hyping Hydrogen Fuel Cell Vehicles?"
CleanTechnica, October 14, 2021


Auto racing

A record of was set by a prototype Ford Fusion Hydrogen 999 Fuel Cell Race Car at the Bonneville Salt Flats, in August 2007, using a large compressed oxygen tank to increase power. The land-speed record for a hydrogen-powered vehicle of was set by
Ohio State University The Ohio State University, commonly called Ohio State or OSU, is a public land-grant research university in Columbus, Ohio. A member of the University System of Ohio, it has been ranked by major institutional rankings among the best pub ...
's
Buckeye Bullet 2 The Buckeye Bullet is a series of four experimental electric cars created by students from Ohio State University ( the Buckeyes) as a joint project with Venturi. The cars were designed to break the land speed record on the Bonneville Speedway, a ...
, which achieved a "flying-mile" speed of at the Bonneville Salt Flats in August 2008. In 2007, the Hydrogen Electric Racing Federation was formed as a racing organization for hydrogen fuel cell-powered vehicles. The organization sponsored the Hydrogen 500, a 500-mile race.


Buses

Fuel-cell buses have been trialed by several manufacturers in different locations, for example, the Ursus Lublin. Solaris Bus & Coach introduced its Urbino 12 hydrogen electric buses in 2019. Several dozen were ordered. In 2022, the city of Montpellier, France, cancelled a contract to procure 51 buses powered by hydrogen fuel cells, when it found that "the cost of operation for hydrogen usesis 6 times the cost of electricity".


Trams and trains

In March 2015, China South Rail Corporation (CSR) demonstrated the world's first hydrogen fuel cell-powered tramcar at an assembly facility in Qingdao. Tracks for the new vehicle have been built in seven Chinese cities. In northern Germany in 2018 the first fuel-cell powered
Coradia iLint The Alstom Coradia LINT is an articulated railcar manufactured by Alstom since 1999, offered in diesel and hydrogen fuel models. The acronym ''LINT'' is short for the German ''"leichter innovativer Nahverkehrstriebwagen"'' (light innovative local ...
trains were placed into service; excess power is stored in lithium-ion batteries.


Ships

Hydrogen fuel cells are not suitable for propulsion in large long-distance ships, but they are being considered as a range-extender for smaller, short-distance, low-speed electric vessels, such as ferries. Hydrogen in
ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous ...
is being considered as a long-distance fuel.


Bicycles

In 2007, Pearl Hydrogen Power Source Technology Co of
Shanghai Shanghai (; , , Standard Chinese, Standard Mandarin pronunciation: ) is one of the four Direct-administered municipalities of China, direct-administered municipalities of the China, People's Republic of China (PRC). The city is located on the ...
, China, demonstrated a PHB hydrogen bicycle. In 2014, Australian scientists from the University of New South Wales presented their Hy-Cycle model. The same year,
Canyon Bicycles Canyon Bicycles GmbH (abbr.: Canyon) is a German manufacturer of road bikes, mountain bikes, hybrid bikes, triathlon bikes and e-bikes based in Koblenz, Germany. History In 1985 Roman Arnold and his brother Franc Arnold (who is no longer i ...
started to work on the Eco Speed concept bicycle. In 2017, Pragma Industries of France developed a bicycle that was able to travel 100 km on a single hydrogen cylinder. In 2019, Pragma announced that the product, "Alpha Bike", has been improved to offer an electrically assisted pedalling range of 150 km, and the first 200 of the bikes are to be provided to journalists covering the
45th G7 summit The 45th G7 summit was held on 24–26 August 2019, in Biarritz, France. In March 2014, the G7 declared that a meaningful discussion was currently not possible with Russia in the context of the G8. Since then, meetings have continued within the ...
in Biarritz, France. If successful, Lloyd Alter of
TreeHugger ''TreeHugger'' is a sustainability website that reports on news, and other subjects like eco-friendly design, homes, and gardens. It was rated the top sustainability blog of 2007 by Nielsen Netratings, and was included in Time Magazine's 200 ...
responded to the announcement, asking "why … go through the trouble of using electricity to make hydrogen, only to turn it back into electricity to charge a battery to run the e-bike rpick a fuel that needs an expensive filling station that can only handle 35 bikes a day, when you can charge a battery powered bike anywhere. fyou were a captive fleet operator, why otjust swap out batteries to get the range and the fast turnover?"


Military vehicles

General Motors' military division, GM Defense, focuses on hydrogen fuel cell vehicles. Its SURUS (Silent Utility Rover Universal Superstructure) is a flexible fuel cell electric platform with autonomous capabilities. Since April 2017, the U.S. Army has been testing the commercial Chevrolet Colorado ZH2 on its U.S. bases to determine the viability of hydrogen-powered vehicles in military mission tactical environments.


Motorcycles and scooters

ENV env is a shell command for Unix and Unix-like operating systems. It is used to either print a list of environment variables or run another utility in an altered environment without having to modify the currently existing environment. Using env, ...
develops electric motorcycles powered by a hydrogen fuel cell, including the Crosscage and Biplane. Other manufacturers as Vectrix are working on hydrogen scooters. Finally, hydrogen-fuel-cell-electric-hybrid scooters are being made such as the Suzuki Burgman fuel-cell scooter and the FHybrid. The Burgman received "whole vehicle type" approval in the EU. The Taiwanese company APFCT conducted a live street test with 80 fuel-cell scooters for Taiwan's Bureau of Energy.


Auto rickshaws

Hydrogen auto rickshaw concept vehicles have been built by Mahindra HyAlfa and Bajaj Auto.


Quads and tractors

Autostudi S.r.l's H-Due is a hydrogen-powered quad, capable of transporting 1-3 passengers. A concept for a hydrogen-powered tractor has been proposed.


Fork trucks

A
hydrogen internal combustion engine A hydrogen internal combustion engine vehicle (HICEV) is a type of hydrogen vehicle using an internal combustion engine. Hydrogen internal combustion engine vehicles are different from hydrogen fuel cell vehicles (which use electrochemical us ...
(or "HICE") forklift or HICE lift truck is a hydrogen fueled,
internal combustion engine An internal combustion engine (ICE or IC engine) is a heat engine in which the combustion of a fuel occurs with an oxidizer (usually air) in a combustion chamber that is an integral part of the working fluid flow circuit. In an internal co ...
-powered industrial forklift truck used for lifting and transporting materials. The first production HICE forklift truck based on the Linde X39 Diesel was presented at an exposition in
Hannover Hanover (; german: Hannover ; nds, Hannober) is the capital and largest city of the German state of Lower Saxony. Its 535,932 (2021) inhabitants make it the 13th-largest city in Germany as well as the fourth-largest city in Northern Germany ...
on May 27, 2008. It used a 2.0 litre, diesel internal combustion engine converted to use hydrogen as a fuel with the use of a compressor and direct injection.HyICE
/ref> In 2013 there were over 4,000
fuel cell forklift A fuel cell forklift (also called a fuel cell lift truck) is a fuel cell powered industrial forklift used to lift and transport materials. History * 1960Allis-Chalmers builds the first fuel cell forklift. Market In 2013 there were over 4,000 fue ...
s used in
material handling Material handling involves short-distance movement within the confines of a building or between a building and a transportation vehicle. It uses a wide range of manual, semi-automated, and automated equipment and includes consideration of the pro ...
in the US. The global market was estimated at 1 million fuel cell powered forklifts per year for 2014–2016."Global and Chinese Forklift Industry Report, 2014-2016"
, Research and Markets, November 6, 2014
Fleets are being operated by companies around the world. Pike Research stated in 2011 that fuel-cell-powered forklifts will be the largest driver of hydrogen fuel demand by 2020. Most companies in Europe and the US do not use petroleum powered forklifts, as these vehicles work indoors where emissions must be controlled and instead use electric forklifts. Fuel-cell-powered forklifts can provide benefits over battery powered forklifts as they can be refueled in 3 minutes. They can be used in refrigerated warehouses, as their performance is not degraded by lower temperatures. The fuel cell units are often designed as drop-in replacements.


Rockets

Many large rockets use
liquid hydrogen Liquid hydrogen (LH2 or LH2) is the liquid state of the element hydrogen. Hydrogen is found naturally in the molecular H2 form. To exist as a liquid, H2 must be cooled below its critical point of 33  K. However, for it to be in a fully l ...
as fuel, with
liquid oxygen Liquid oxygen—abbreviated LOx, LOX or Lox in the aerospace, submarine and gas industries—is the liquid form of molecular oxygen. It was used as the oxidizer in the first liquid-fueled rocket invented in 1926 by Robert H. Goddard, an app ...
as an oxidizer (LH2/LOX). An advantage of hydrogen rocket fuel is the high effective exhaust velocity compared to
kerosene Kerosene, paraffin, or lamp oil is a combustible hydrocarbon liquid which is derived from petroleum. It is widely used as a fuel in aviation as well as households. Its name derives from el, κηρός (''keros'') meaning " wax", and was re ...
/ LOX or UDMH/ NTO engines. According to the Tsiolkovsky rocket equation, a rocket with higher exhaust velocity uses less propellant to accelerate. Also the energy density of hydrogen is greater than any other fuel.College of the Desert, “Module 1, Hydrogen Properties”, Revision 0, December 200
Hydrogen Properties
. Retrieved 2015-10-05.
LH2/LOX also yields the greatest efficiency in relation to the amount of propellant consumed, of any known rocket propellant. A disadvantage of LH2/LOX engines is the low density and low temperature of liquid hydrogen, which means bigger and insulated and thus heavier fuel tanks are needed. This increases the rocket's structural mass which reduces its delta-v significantly. Another disadvantage is the poor storability of LH2/LOX-powered rockets: Due to the constant hydrogen boil-off, the rocket must be fueled shortly before launch, which makes cryogenic engines unsuitable for ICBMs and other rocket applications with the need for short launch preparations. Overall, the delta-v of a hydrogen stage is typically not much different from that of a dense fuelled stage, but the weight of a hydrogen stage is much less, which makes it particularly effective for upper stages, since they are carried by the lower stages. For first stages, dense fuelled rockets in studies may show a small advantage, due to the smaller vehicle size and lower air drag. LH2/LOX were also used in the
Space Shuttle The Space Shuttle is a retired, partially reusable low Earth orbital spacecraft system operated from 1981 to 2011 by the U.S. National Aeronautics and Space Administration (NASA) as part of the Space Shuttle program. Its official program n ...
to run the fuel cells that power the electrical systems. The byproduct of the fuel cell is water, which is used for drinking and other applications that require water in space.


Heavy trucks

United Parcel Service began testing of a hydrogen powered delivery vehicle in 2017. In 2020,
Hyundai Hyundai is a South Korean industrial conglomerate (" chaebol"), which was restructured into the following groups: * Hyundai Group, parts of the former conglomerate which have not been divested ** Hyundai Mobis, Korean car parts company ** Hyundai A ...
began commercial production of its Xcient fuel cell trucks and shipped ten of them to
Switzerland ). Swiss law does not designate a ''capital'' as such, but the federal parliament and government are installed in Bern, while other federal institutions, such as the federal courts, are in other cities (Bellinzona, Lausanne, Luzern, Neuchâtel ...
. In 2022 in Australia, five hydrogen fuel cell class 8 trucks were placed into use to transport zinc from Sun Metals' Townsville mine to the Port of Townsville, Queensland, to be shipped around the world.


Internal combustion vehicle

Hydrogen internal combustion engine cars are different from hydrogen fuel cell cars. The hydrogen internal combustion car is a slightly modified version of the traditional gasoline
internal combustion engine An internal combustion engine (ICE or IC engine) is a heat engine in which the combustion of a fuel occurs with an oxidizer (usually air) in a combustion chamber that is an integral part of the working fluid flow circuit. In an internal co ...
car. These hydrogen engines burn fuel in the same manner that gasoline engines do; the main difference is the exhaust product. Gasoline combustion results in
emissions Emission may refer to: Chemical products * Emission of air pollutants, notably: **Flue gas, gas exiting to the atmosphere via a flue ** Exhaust gas, flue gas generated by fuel combustion ** Emission of greenhouse gases, which absorb and emit radi ...
of mostly
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is t ...
and water, plus trace amounts of
carbon monoxide Carbon monoxide ( chemical formula CO) is a colorless, poisonous, odorless, tasteless, flammable gas that is slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simpl ...
, , particulates and unburned hydrocarbons, while the main exhaust product of hydrogen combustion is water vapor. In 1807
François Isaac de Rivaz François Isaac de Rivaz (Paris, December 19, 1752 – Sion, July 30, 1828) was a French-born Swiss inventor and a politician. He invented a hydrogen-powered internal combustion engine with electric ignition and described it in a French paten ...
designed the first hydrogen-fueled internal combustion engine. In 1965, Roger E. Billings, then a high school student, converted a Model A to run on hydrogen. In 1970 Paul Dieges patented a modification to internal combustion engines which allowed a gasoline-powered engine to run on hydrogen. Mazda has developed Wankel engines burning hydrogen, which are used in the Mazda RX-8 Hydrogen RE. The advantage of using an internal combustion engine, like Wankel and piston engines, is the lower cost of retooling for production.


Fuel cell


Fuel cell cost

Hydrogen fuel cells are relatively expensive to produce, as their designs require rare substances, such as
platinum Platinum is a chemical element with the symbol Pt and atomic number 78. It is a dense, malleable, ductile, highly unreactive, precious, silverish-white transition metal. Its name originates from Spanish , a diminutive of "silver". Pla ...
, as a
catalyst Catalysis () is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst (). Catalysts are not consumed in the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recyc ...
, In 2014, former European Parliament President
Pat Cox Patrick Cox (born 28 November 1952) is a former Irish Fine Gael politician, journalist and television current affairs presenter who served as President of the European Parliament from 2002 to 2004 and Leader of the European Liberal Democrat a ...
estimated that Toyota would initially lose about $100,000 on each Mirai sold. In 2020, researchers at the University of Copenhagen's Department of Chemistry are developing a new type of catalyst that they hope will decrease the cost of fuel cells. This new catalyst uses far less platinum because the platinum nano-particles are not coated over carbon which, in conventional hydrogen fuel cells, keeps the nano-particles in place but also causes the catalyst to become unstable and denatures it slowly, requiring even more platinum. The new technology uses durable nanowires instead of the nano-particles. "The next step for the researchers is to scale up their results so that the technology can be implemented in hydrogen vehicles."


Freezing conditions

The problems in early fuel-cell designs at low temperatures concerning range and cold start capabilities have been addressed so that they "cannot be seen as show-stoppers anymore". Users in 2014 said that their fuel cell vehicles perform flawlessly in temperatures below zero, even with the heaters blasting, without significantly reducing range. Studies using neutron radiography on unassisted cold-start indicate ice formation in the cathode, three stages in cold start and Nafion ionic conductivity. A parameter, defined as coulomb of charge, was also defined to measure cold start capability.


Service life

The
service life A product's service life is its period of use in service. Several related terms describe more precisely a product's life, from the point of manufacture, storage, and distribution, and eventual use. Service life has been defined as "a product's ...
of fuel cells is comparable to that of other vehicles. Polymer-electrolyte membrane (PEM) fuel cell service life is 7,300 hours under cycling conditions.


Hydrogen

Hydrogen does not exist in convenient reservoirs or deposits like fossil fuels or
helium Helium (from el, ἥλιος, helios, lit=sun) is a chemical element with the symbol He and atomic number 2. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas and the first in the noble gas group in the periodic ta ...
. It is produced from feedstocks such as natural gas and biomass or electrolyzed from water.David Z. Morris.
Why Japan wants to transform into a 'hydrogen society'
" ''
Fortune (magazine) ''Fortune'' is an American multinational business magazine headquartered in New York City. It is published by Fortune Media Group Holdings, owned by Thai businessman Chatchaval Jiaravanon. The publication was founded by Henry Luce in 1929. The ...
'', 21 October 2015. Quote: "Unlike gasoline, solar, or nuclear, hydrogen isn’t an energy source—just a method of energy storage. “Hydrogen is an energy carrier in the same sense that electricity is,” says David Keith"
A suggested benefit of large-scale deployment of hydrogen vehicles is that it could lead to decreased emissions of greenhouse gases and ozone precursors.Schultz, M.G., Thomas Diehl, Guy P. Brasseur, and Werner Zittel
"Air Pollution and Climate-Forcing Impacts of a Global Hydrogen Economy"
, ''Science'', October 24, 2003 302: 624-627
However, as of 2014, 95% of hydrogen is made from
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane ...
. It can be produced by thermochemical or pyrolitic means using renewable feedstocks, but that is an expensive process. Renewable electricity can however be used to power the conversion of water into hydrogen: Integrated wind-to-hydrogen ( power to gas) plants, using electrolysis of water, are exploring technologies to deliver costs low enough, and quantities great enough, to compete with traditional energy sources. The challenges facing the use of hydrogen in vehicles include its storage on board the vehicle.


Production

The molecular hydrogen needed as an onboard fuel for hydrogen vehicles can be obtained through many thermochemical methods utilizing
natural gas Natural gas (also called fossil gas or simply gas) is a naturally occurring mixture of gaseous hydrocarbons consisting primarily of methane in addition to various smaller amounts of other higher alkanes. Low levels of trace gases like carbon d ...
,
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when ...
(by a process known as coal gasification), liquefied petroleum gas, biomass (
biomass gasification Gasification is a process that converts biomass- or fossil fuel-based carbonaceous materials into gases, including as the largest fractions: nitrogen (N2), carbon monoxide (CO), hydrogen (H2), and carbon dioxide (). This is achieved by reacting ...
), by a process called
thermolysis Thermal decomposition, or thermolysis, is a chemical decomposition caused by heat. The decomposition temperature of a substance is the temperature at which the substance chemically decomposes. The reaction is usually endothermic as heat is re ...
, or as a microbial waste product called biohydrogen or Biological hydrogen production. 95% of hydrogen is produced using natural gas.Suplee, Curt
"Don't bet on a hydrogen car anytime soon"
. ''Washington Post'', November 17, 2009
85% of hydrogen produced is used to remove sulfur from gasoline. Hydrogen can be produced from water by electrolysis at working efficiencies of 65–70%. Hydrogen can be made by chemical reduction using chemical hydrides or aluminum. Current technologies for manufacturing hydrogen use energy in various forms, totaling between 25 and 50 percent of the higher heating value of the hydrogen fuel, used to produce, compress or liquefy, and transmit the hydrogen by pipeline or truck. F. Kreith, "Fallacies of a Hydrogen Economy: A Critical Analysis of Hydrogen Production and Utilization" in ''Journal of Energy Resources Technology'' (2004), 126: 249–257. Environmental consequences of the production of hydrogen from fossil energy resources include the emission of greenhouse gasses, a consequence that would also result from the on-board reforming of methanol into hydrogen.Bossel, Ulf
"Does a Hydrogen Economy Make Sense?"
Proceedings of the IEEE, Vol. 94, No. 10, October 2006
Hydrogen production using renewable energy resources would not create such emissions, but the scale of renewable energy production would need to be expanded to be used in producing hydrogen for a significant part of transportation needs. In a few countries, renewable sources are being used more widely to produce energy and hydrogen. For example,
Iceland Iceland ( is, Ísland; ) is a Nordic island country in the North Atlantic Ocean and in the Arctic Ocean. Iceland is the most sparsely populated country in Europe. Iceland's capital and largest city is Reykjavík, which (along with its ...
is using geothermal power to produce hydrogen, and
Denmark ) , song = ( en, "King Christian stood by the lofty mast") , song_type = National and royal anthem , image_map = EU-Denmark.svg , map_caption = , subdivision_type = Sovereign state , subdivision_name = Kingdom of Denmark , establish ...
is using
wind Wind is the natural movement of air or other gases relative to a planet's surface. Winds occur on a range of scales, from thunderstorm flows lasting tens of minutes, to local breezes generated by heating of land surfaces and lasting a few ...
.


Storage

Compressed hydrogen in hydrogen tanks at 350 bar (5,000 psi) and 700 bar (10,000 psi) is used for hydrogen tank systems in vehicles, based on type IV carbon-composite technology. Hydrogen has a very low volumetric energy density at ambient conditions, compared with gasoline and other vehicle fuels. It must be stored in a vehicle either as a super-cooled liquid or as highly compressed gas, which require additional energy to accomplish. In 2018, researchers at
CSIRO The Commonwealth Scientific and Industrial Research Organisation (CSIRO) is an Australian Government agency responsible for scientific research. CSIRO works with leading organisations around the world. From its headquarters in Canberra, CSIRO ...
in Australia powered a Toyota Mirai and Hyundai Nexo with hydrogen separated from ammonia using a membrane technology. Ammonia is easier to transport safely in tankers than pure hydrogen.


Infrastructure

The
hydrogen infrastructure A hydrogen infrastructure is the infrastructure of hydrogen pipeline transport, points of hydrogen production and hydrogen stations (sometimes clustered as a hydrogen highway) for distribution as well as the sale of hydrogen fuel, and thus a cruci ...
consists of hydrogen-equipped filling stations, which are supplied with hydrogen via
compressed hydrogen tube trailer Hydrogen tube trailers are semi-trailers that consist of 4 to 36 cluster high-pressure hydrogen tanks varying in length from for small tubes to on jumbo tube trailers. They are part of the hydrogen highway and usually precede a local hydrogen ...
s,
liquid hydrogen tank truck A tank truck, gas truck, fuel truck, or tanker truck (American English) or tanker (British English) is a motor vehicle designed to carry liquids or gases on roads. The largest such vehicles are similar to railroad tank cars, which are also des ...
s or dedicated onsite production, and some industrial hydrogen pipeline transport. The distribution of hydrogen fuel for vehicles throughout the U.S. would require new hydrogen stations that would cost between 20 billion dollars in the US, (4.6 billion in the EU). and half trillion dollars in the US. , there were 49 publicly accessible hydrogen refueling stations in the US, 48 of which were located in California (compared with 42,830 electric charging stations).Alternative Fueling Station Counts by State
, ''Alternative Fuels Data Center'', accessed March 18, 2016
By 2017, there were 91 hydrogen fueling stations in Japan.Voelcker, John
"Energy use for hydrogen fuel-cell vehicles: higher than electrics, even hybrids (analysis)"
, ''Green Car Reports'', May 4, 2017


Codes and standards

Hydrogen codes and standards, as well as codes and technical standards for
hydrogen safety Hydrogen safety covers the safe production, handling and use of hydrogen, particularly hydrogen gas fuel and liquid hydrogen. Hydrogen possesses the NFPA 704's highest rating of 4 on the flammability scale because it is flammable when mixed eve ...
and the storage of hydrogen, have been an institutional barrier to deploying hydrogen technologies. To enable the commercialization of hydrogen in consumer products, new codes and standards must be developed and adopted by federal, state and local governments.


Official support


U.S. initiatives

Fuel cell buses are supported. The New York State Energy Research and Development Authority (NYSERDA) has created incentives for hydrogen fuel cell electric trucks and buses.


Other efforts

In Japan, hydrogen is mainly to be sourced from outside Japan. Norway plans a series of hydrogen refueling stations along the main roads.


Criticism

Critics claim the time frame for overcoming the technical and economic challenges to implementing wide-scale use of hydrogen in cars is likely to be at least several decades.Meyers, Jeremy P
"Getting Back Into Gear: Fuel Cell Development After the Hype"
. The Electrochemical Society ''Interface'', Winter 2008, pp. 36–39, accessed August 7, 2011
They argue that the focus on the use of the hydrogen car is a dangerous detour from more readily available solutions to reducing the use of fossil fuels in vehicles. In 2008, '' Wired News'' reported that "experts say it will be 40 years or more before hydrogen has any meaningful impact on gasoline consumption or global warming, and we can't afford to wait that long. In the meantime, fuel cells are diverting resources from more immediate solutions." In the 2006 documentary, '' Who Killed the Electric Car?'', former U.S. Department of Energy official
Joseph Romm Joseph J. Romm (born June 27, 1960) is an American author, editor, physicist and climate expert, who advocates reducing greenhouse gas emissions to limit global warming and increasing energy security through energy efficiency, green energy techno ...
said: "A hydrogen car is one of the least efficient, most expensive ways to reduce greenhouse gases." He held the same views in 2014. The ''Los Angeles Times'' wrote, in 2009, "Hydrogen ... is a lousy way to move cars." Robert Zubrin, the author of ''
Energy Victory ''Energy Victory: Winning the War on Terror by Breaking Free of Oil'' is a 2007 book by Robert Zubrin. Zubrin's central argument is that the decisive front in the War on Terror is America's struggle for energy independence. He outlines the manner i ...
'', stated: "Hydrogen is 'just about the worst possible vehicle fuel'".Wrigglesworth, Phil
"The car of the perpetual future"'
September 4, 2008, retrieved on September 15, 2008
''
The Economist ''The Economist'' is a British weekly newspaper printed in demitab format and published digitally. It focuses on current affairs, international business, politics, technology, and culture. Based in London, the newspaper is owned by The Eco ...
'' noted that most hydrogen is produced through steam methane reformation, which creates at least as much emission of carbon per mile as some of today's gasoline cars, but that if the hydrogen could be produced using renewable energy, "it would surely be easier simply to use this energy to charge the batteries of all-electric or plug-in hybrid vehicles." Over their lifetimes, hydrogen vehicles will emit more carbon than gasoline vehicles."Hydrogen Cars' Lifecycle Emits More Carbon Than Gas Cars, Study Says"
'' Digital Trends'', January 1, 2010
''
The Washington Post ''The Washington Post'' (also known as the ''Post'' and, informally, ''WaPo'') is an American daily newspaper published in Washington, D.C. It is the most widely circulated newspaper within the Washington metropolitan area and has a large n ...
'' asked in 2009, " y would you want to store energy in the form of hydrogen and then use that hydrogen to produce electricity for a motor, when electrical energy is already waiting to be sucked out of sockets all over America and stored in auto batteries"? Volkswagen's Rudolf Krebs said in 2013 that "no matter how excellent you make the cars themselves, the laws of physics hinder their overall efficiency. The most efficient way to convert energy to mobility is electricity." He elaborated: "Hydrogen mobility only makes sense if you use green energy", but ... you need to convert it first into hydrogen "with low efficiencies" where "you lose about 40 percent of the initial energy". You then must compress the hydrogen and store it under high pressure in tanks, which uses more energy. "And then you have to convert the hydrogen back to electricity in a fuel cell with another efficiency loss". Krebs continued: "in the end, from your original 100 percent of electric energy, you end up with 30 to 40 percent."Blanco, Sebastian
"VW's Krebs talks hydrogen, says 'most efficient way to convert energy to mobility is electricity'"
, '' AutoblogGreen'', November 20, 2013
In 2015, '' CleanTechnica'' listed some of the disadvantages of hydrogen fuel cell vehicles A 2016 study in ''
Energy In physics, energy (from Ancient Greek: ἐνέργεια, ''enérgeia'', “activity”) is the quantitative property that is transferred to a body or to a physical system, recognizable in the performance of work and in the form of ...
'' by scientists at
Stanford University Stanford University, officially Leland Stanford Junior University, is a private research university in Stanford, California. The campus occupies , among the largest in the United States, and enrolls over 17,000 students. Stanford is conside ...
and the Technical University of Munich concluded that, even assuming local hydrogen production, "investing in all-electric battery vehicles is a more economical choice for reducing carbon dioxide emissions". A 2017 analysis published in ''Green Car Reports'' concluded that the best hydrogen-fuel-cell vehicles consume "more than three times more electricity per mile than an electric vehicle ... generate more
greenhouse gas emissions Greenhouse gas emissions from human activities strengthen the greenhouse effect, contributing to climate change. Most is carbon dioxide from burning fossil fuels: coal, oil, and natural gas. The largest emitters include coal in China and ...
than other powertrain technologies ... nd havevery high fuel costs. ... Considering all the obstacles and requirements for new infrastructure (estimated to cost as much as $400 billion), fuel-cell vehicles seem likely to be a niche technology at best, with little impact on U.S. oil consumption. The US Department of Energy agrees, for fuel produced by grid electricity via electrolysis, but not for most other pathways for generation. A 2019 video by ''Real Engineering'' noted that, notwithstanding the introduction of vehicles that run on hydrogen, using hydrogen as a fuel for cars does not help to reduce carbon emissions from transportation. The 95% of hydrogen still produced from fossil fuels releases carbon dioxide, and producing hydrogen from water is an energy-consuming process. Storing hydrogen requires more energy either to cool it down to the liquid state or to put it into tanks under high pressure, and delivering the hydrogen to fueling stations requires more energy and may release more carbon. The hydrogen needed to move a FCV a kilometer costs approximately 8 times as much as the electricity needed to move a BEV the same distance. Also in 2019, Katsushi Inoue, the president of Honda Europe, stated, "Our focus is on hybrid and electric vehicles now. Maybe hydrogen fuel cell cars will come, but that’s a technology for the next era." Assessments since 2020 have concluded that hydrogen vehicles are still only 38% efficient, while battery EVs are from 80% to 95% efficient. A 2021 assessment by ''CleanTechnica'' concluded that while hydrogen cars are far less efficient than electric cars, the vast majority of hydrogen being produced is polluting grey hydrogen, and delivering hydrogen would require building a vast and expensive new infrastructure, the remaining two "advantages of fuel cell vehicles – longer range and fast fueling times – are rapidly being eroded by improving battery and charging technology." A 2022 study in '' Nature Electronics'' agreed. Another 2022 article, in '' Recharge News'', stated that ships are more likely to be powered by ammonia or methanol than hydrogen.


Safety and supply

Hydrogen fuel is hazardous because of the low ignition energy (see also Autoignition temperature) and high combustion energy of hydrogen, and because it tends to leak easily from tanks. Explosions at hydrogen filling stations have been reported. Hydrogen fuelling stations generally receive deliveries of hydrogen by truck from hydrogen suppliers. An interruption at a hydrogen supply facility can shut down multiple hydrogen fuelling stations.


Comparison with other types of alternative fuel vehicle

Hydrogen vehicles compete with various proposed alternatives to the modern fossil fuel powered vehicle infrastructure.


Plug-in hybrids

Plug-in hybrid electric vehicles, or PHEVs, are hybrid vehicles that can be plugged into the electric grid and contain an electric motor and also an
internal combustion engine An internal combustion engine (ICE or IC engine) is a heat engine in which the combustion of a fuel occurs with an oxidizer (usually air) in a combustion chamber that is an integral part of the working fluid flow circuit. In an internal co ...
. The PHEV concept augments standard hybrid electric vehicles with the ability to recharge their batteries from an external source, enabling increased use of the vehicle's electric motors while reducing their reliance on internal combustion engines.


Natural gas

Internal combustion engine An internal combustion engine (ICE or IC engine) is a heat engine in which the combustion of a fuel occurs with an oxidizer (usually air) in a combustion chamber that is an integral part of the working fluid flow circuit. In an internal co ...
-based
compressed natural gas Compressed natural gas (CNG) is a fuel gas mainly composed of methane (CH4), compressed to less than 1% of the volume it occupies at standard atmospheric pressure. It is stored and distributed in hard containers at a pressure of , usually in ...
(CNG), HCNG, LPG or LNG vehicles (
Natural gas vehicle A natural gas vehicle (NGV) is an alternative fuel vehicle that uses compressed natural gas (CNG) or liquefied natural gas (LNG). Natural gas vehicles should not be confused with autogas vehicles powered by liquefied petroleum gas (LPG), ma ...
s or NGVs) use methane (
Natural gas Natural gas (also called fossil gas or simply gas) is a naturally occurring mixture of gaseous hydrocarbons consisting primarily of methane in addition to various smaller amounts of other higher alkanes. Low levels of trace gases like carbon d ...
or Biogas) directly as a fuel source. Natural gas has a higher energy density than hydrogen gas. NGVs using biogas are nearly
carbon neutral Carbon neutrality is a state of net-zero carbon dioxide emissions. This can be achieved by balancing emissions of carbon dioxide with its removal (often through carbon offsetting) or by eliminating emissions from society (the transition to the " ...
. Unlike hydrogen vehicles, CNG vehicles have been available for many years, and there is sufficient infrastructure to provide both commercial and home refueling stations. Worldwide, there were 14.8 million natural gas vehicles by the end of 2011. The other use for natural gas is in steam reforming which is the common way to produce hydrogen gas for use in electric cars with fuel cells. Methane is also an alternative rocket fuel.


All-electric vehicles

electric ship An electric boat is a motorboat, powered watercraft driven by electric motors, which are powered by either on-board battery packs, solar panels or electric generator, generators. While a significant majority of water vessels are powered by di ...
s cannot carry many containers across oceans and electric aircraft cannot carry many passengers long haul. Long distance electric trucks may require more megawatt charging infrastructure.


See also

*
Airship An airship or dirigible balloon is a type of aerostat or lighter-than-air aircraft that can navigate through the air under its own power. Aerostats gain their lift from a lifting gas that is less dense than the surrounding air. In early ...
* Alternative fuel car * Bivalent engine *
Fuel gas-powered scooter A fuel gas-powered scooter is a scooter powered by fuel gas. Fuel gases include such fuels such as liquefied petroleum gas (LPG), compressed natural gas (CNG), biogas and hydrogen ( HICE). Hydrogen ( hydrogen internal combustion) use in two-wheel ...
*
Carbon-neutral fuel Carbon-neutral fuel is fuel which produces no net-greenhouse gas emissions or carbon footprint. In practice, this usually means fuels that are made using carbon dioxide (CO2) as a feedstock. Proposed carbon-neutral fuels can broadly be grouped in ...
*
Formic acid vehicle An alternative fuel vehicle is a motor vehicle that runs on alternative fuel rather than traditional petroleum fuels (petrol or petrodiesel). The term also refers to any technology (e.g. electric car, hybrid electric vehicles, solar-powered vehic ...
*'' Hell and High Water'' * Hydrogen transport * Proton exchange membrane fuel cell * Hydrogen economy *''
The Hype about Hydrogen ''The Hype About Hydrogen: Fact and Fiction in the Race to Save the Climate'' is a book by Joseph J. Romm, published in 2004 by Island Press and updated in 2005. The book has been translated into German as ''Der Wasserstoff-Boom''. Romm is an ex ...
'' * Tribrid vehicle * World Green Car


References


External links


California Fuel Cell Partnership homepageFuel Cell Today - Market-based intelligence on the fuel cell industryU.S. Dept. of Energy hydrogen pagesSandia Corporation – Hydrogen internal combustion engine descriptionInside world's first hydrogen-powered production car
BBC News, 14 September 2010
Toyota Ecopark Hydrogen Demonstration
ARENAWIRE, 22 March 2019 {{DEFAULTSORT:Hydrogen Vehicle Automotive technologies Hydrogen technologies Hydrogen economy Emerging technologies