''Hepatizon'' (

Greek etymology Greek ( el, label=Modern Greek, Ελληνικά, Elliniká, ; grc, Ἑλληνική, Hellēnikḗ) is an independent branch of the Indo-European family of languages, native to Greece, Cyprus, southern Italy ( Calabria and Salento), southern ...

: , English translation: "

liver The liver is a major organ only found in vertebrates which performs many essential biological functions such as detoxification of the organism, and the synthesis of proteins and biochemicals necessary for digestion and growth. In humans, it i ...

"), also known as black Corinthian bronze, was a highly valuable

metal A metal (from ancient Greek, Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electrical resistivity and conductivity, e ...

alloy An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductili ...

classical antiquity Classical antiquity (also the classical era, classical period or classical age) is the period of cultural history between the 8th century BC and the 5th century AD centred on the Mediterranean Sea, comprising the interlocking civilizations of ...

. It is thought to be an alloy of

copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pink ...

with the addition of a small proportion of

gold Gold is a chemical element with the symbol Au (from la, aurum) and atomic number 79. This makes it one of the higher atomic number elements that occur naturally. It is a bright, slightly orange-yellow, dense, soft, malleable, and ductile ...

and

silver Silver is a chemical element with the symbol Ag (from the Latin ', derived from the Proto-Indo-European ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, white, lustrous transition metal, it exhibits the highest electrical ...

(perhaps as little as 8% of each), mixed and treated to produce a material with a dark purplish

patina Patina ( or ) is a thin layer that variously forms on the surface of copper, brass, bronze and similar metals and metal alloys ( tarnish produced by oxidation or other chemical processes) or certain stones and wooden furniture (sheen produce ...

, similar to the colour of liver. It is referred to in various ancient texts, but few known examples of hepatizon exist today. Of the known types of

bronze Bronze is an alloy consisting primarily of copper, commonly with about 12–12.5% tin and often with the addition of other metals (including aluminium, manganese, nickel, or zinc) and sometimes non-metals, such as phosphorus, or metalloids suc ...

brass Brass is an alloy of copper (Cu) and zinc (Zn), in proportions which can be varied to achieve different mechanical, electrical, and chemical properties. It is a substitutional alloy: atoms of the two constituents may replace each other wi ...

in classical antiquity (known in

Latin Latin (, or , ) is a classical language belonging to the Italic languages, Italic branch of the Indo-European languages. Latin was originally a dialect spoken in the lower Tiber area (then known as Latium) around present-day Rome, but through ...

as ''aes'' and in Greek as χαλκός), hepatizon was the second most valuable.

Pliny the Elder Gaius Plinius Secundus (AD 23/2479), called Pliny the Elder (), was a Roman author, naturalist and natural philosopher, and naval and army commander of the early Roman Empire, and a friend of the emperor Vespasian. He wrote the encyclopedic ' ...

mentions it in his '' Natural History'', stating that it is less valuable than Corinthian bronze, which contained a greater proportion of gold or silver and as a result resembled the

precious metal Precious metals are rare, naturally occurring metallic chemical elements of high economic value. Chemically, the precious metals tend to be less reactive than most elements (see noble metal). They are usually ductile and have a high lu ...

s, but was esteemed before bronze from

Delos The island of Delos (; el, Δήλος ; Attic: , Doric: ), near Mykonos, near the centre of the Cyclades archipelago, is one of the most important mythological, historical, and archaeological sites in Greece. The excavations in the island ar ...

and

Aegina Aegina (; el, Αίγινα, ''Aígina'' ; grc, Αἴγῑνα) is one of the Saronic Islands of Greece in the Saronic Gulf, from Athens. Tradition derives the name from Aegina, the mother of the hero Aeacus, who was born on the island an ...

.Aes
from ''A Dictionary of Greek and Roman Antiquities'', John Murray, London, 1875.Pliny's chapter on Corinthian Brass and hepatizon
Chapter 3 of Book 34 from '' Natural History''. As a result of its dark colour, it was particularly valued for

statue A statue is a free-standing sculpture in which the realistic, full-length figures of persons or animals are carved or cast in a durable material such as wood, metal or stone. Typical statues are life-sized or close to life-size; a sculpture t ...

s. According to Pliny, the method of making it, like that for Corinthian bronze, had been lost for a long time. Similar alloys are found outside Europe. For example, shakudō is a Japanese billon of gold and copper with a characteristic dark blue-purple patina.

References

Sources

New Scientist, 22 January 1994, "Secret of Achilles' Shield"

See also

''Metallurgy''

References

Sources

Further reading