Hartshorn is the

antler Antlers are extensions of an animal's skull found in members of the Cervidae (deer) family. Antlers are a single structure composed of bone, cartilage, fibrous tissue, skin, nerves, and blood vessels. They are generally found only on ...

of male

red deer The red deer (''Cervus elaphus'') is one of the largest deer species. A male red deer is called a stag or hart, and a female is called a hind. The red deer inhabits most of Europe, the Caucasus Mountains region, Anatolia, Iran, and parts of ...

Derivatives

Various

nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...

compounds were made from hartshorn shavings: * Oil of hartshorn is a crude chemical product obtained from the destructive distillation of deer antlers. * Salt of hartshorn refers to

ammonium carbonate Ammonium carbonate is a salt with the chemical formula (NH4)2CO3. Since it readily degrades to gaseous ammonia and carbon dioxide upon heating, it is used as a leavening agent and also as smelling salt. It is also known as baker's ammonia and is ...

, an early form of

smelling salts Smelling salts, also known as ammonia inhalants, spirit of hartshorn or sal volatile, are chemical compounds used as stimulants to restore consciousness after fainting. Usage The usual active compound is ammonium carbonate—a colorless-to-w ...

obtained by

dry distillation Dry distillation is the heating of solid materials to produce gaseous products (which may condense into liquids or solids). The method may involve pyrolysis or thermolysis, or it may not (for instance, a simple mixture of ice and glass could be s ...

of oil of hartshorn. * Spirit of hartshorn (or spirits of hartshorn) is an archaic name for aqueous ammonia. Originally, this term was applied to a solution manufactured from the hooves and antlers of the red deer, as well as those of some other animals. The aqueous solution was colorless and pungent, consisting of about 28.5 percent ammonia. It was used chiefly as a

detergent A detergent is a surfactant or a mixture of surfactants with cleansing properties when in dilute solutions. There are a large variety of detergents, a common family being the alkylbenzene sulfonates, which are soap-like compounds that are m ...

, for removing stains and extracting certain vegetable coloring agents, and in the manufacture of ammonium salts. Later, the term was applied to the partially purified similar products of the action of heat on nitrogenous animal matter generally. Finally, the term was applied to any aqueous solution of ammonia.

Uses

Medicine

Hartshorn jelly or a decoction of burnt hartshorn in water was used to treat

diarrhea Diarrhea, also spelled diarrhoea, is the condition of having at least three loose, liquid, or watery bowel movements each day. It often lasts for a few days and can result in dehydration due to fluid loss. Signs of dehydration often begin w ...

. The coal of hartshorn, called calcinated hartshorn, was used as an absorbent, as well as in the treatment of

dysentery Dysentery (UK pronunciation: , US: ), historically known as the bloody flux, is a type of gastroenteritis that results in bloody diarrhea. Other symptoms may include fever, abdominal pain, and a feeling of incomplete defecation. Complications ...

. ''Salt of hartshorn'' (

) was used as a sudorific for treatment of fevers, and as a

smelling salt Smelling salts, also known as ammonia inhalants, spirit of hartshorn or sal volatile, are chemical compounds used as stimulants to restore consciousness after fainting. Usage The usual active compound is ammonium carbonate—a colorless-to-w ...

. Hartshorn was used to treat insect bites, sunstroke,

stye A stye, also known as a hordeolum, is a bacterial infection of an oil gland in the eyelid. This results in a red tender bump at the edge of the eyelid. The outside or the inside of the eyelid can be affected. The cause of a stye is usually a b ...

, and snakebites.

Baking

''Hartshorn salt'' (ammonium carbonate), also known simply as ''hartshorn'', and ''baker's ammonia'', was used as a

leavening agent In cooking, a leavening agent () or raising agent, also called a leaven () or leavener, is any one of a number of substances used in doughs and batters that cause a foaming action (gas bubbles) that lightens and softens the mixture. An altern ...

, in the baking of cookies and other edible treats. It was used mainly in the seventeenth and eighteenth centuries as a forerunner of

baking powder Baking powder is a dry chemical leavening agent, a mixture of a carbonate or bicarbonate and a weak acid. The base and acid are prevented from reacting prematurely by the inclusion of a buffer such as cornstarch. Baking powder is used to increas ...

. A half-teaspoon of hartshorn can substitute for one teaspoon of baking powder. It is called for in old German and Scandinavian recipes and, although rarely used in modern times, may still be purchased as a baking ingredient. Hartshorn helps molded cookies such as Springerle to retain their intricate designs during baking. Cookies made with hartshorn can be kept for a long time without hardening. Use of hartshorn may turn some ingredients, such as sunflower seeds, green. Ammonium carbonate is especially suited to thin, dry cookies and crackers. When heated, it releases ammonia and carbon dioxide gases, but no water. The absence of water allows cookies to cook and dry out more quickly, and thinner cookies allow the pungent ammonia to escape, rather than to remain trapped, as it would in a deeper mass.

Safety concerns

Ammonia released during the baking process reacts with glucose and fructose to form intermediate molecules that in turn, react with

asparagine Asparagine (symbol Asn or N) is an α-amino acid that is used in the biosynthesis of proteins. It contains an α-amino group (which is in the protonated −NH form under biological conditions), an α-carboxylic acid group (which is in the depro ...

(an amino acid found in nuts, seeds, and whole grains) to form

acrylamide Acrylamide (or acrylic amide) is an organic compound with the chemical formula CH2=CHC(O)NH2. It is a white odorless solid, soluble in water and several organic solvents. From the chemistry perspective, acrylamide is a vinyl-substituted primar ...

, a

carcinogen A carcinogen is any substance, radionuclide, or radiation that promotes carcinogenesis (the formation of cancer). This may be due to the ability to damage the genome or to the disruption of cellular metabolic processes. Several radioactive sub ...

References

{{reflist Traditional medicine