Gangue
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In mining, gangue () is the commercially worthless material that surrounds, or is closely mixed with, a wanted
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2 ...
in an ore deposit. It is thus distinct from
overburden In mining, overburden (also called waste or spoil) is the material that lies above an area that lends itself to economical exploitation, such as the rock, soil, and ecosystem that lies above a coal seam or ore body. Overburden is distinct from tai ...
, which is the waste rock or materials overlying an ore or mineral body that are displaced during mining without being processed, and from
tailings In mining, tailings are the materials left over after the process of separating the valuable fraction from the uneconomic fraction ( gangue) of an ore. Tailings are different to overburden, which is the waste rock or other material that ove ...
, which is rock already stripped of valuable minerals. The separation of valuable mineral from gangue minerals is known as mineral processing, mineral dressing, or ore dressing. It is a necessary, and often significant, aspect of
mining Mining is the extraction of valuable minerals or other geological materials from the Earth, usually from an ore body, lode, vein, seam, reef, or placer deposit. The exploitation of these deposits for raw material is based on the econom ...
. It can be a complicated process, depending on the nature of the minerals involved. For example,
galena Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver. Galena is one of the most abundant and widely distributed sulfide minerals. It cr ...
, an ore of lead, is usually found in large pieces within its gangue, so it does not normally need extensive processing to remove it; but
cassiterite Cassiterite is a tin oxide mineral, SnO2. It is generally opaque, but it is translucent in thin crystals. Its luster and multiple crystal faces produce a desirable gem. Cassiterite was the chief tin ore throughout ancient history and remains ...
, the chief ore mineral of tin, is usually disseminated as very small crystals throughout its gangue, so when it is mined from hard rock, the ore-bearing rock first needs to be crushed very finely, and then has to be subjected to sophisticated processes to separate the ore. For any particular ore deposit, and at any particular point in time, the concentration of the wanted mineral(s) in the gangue material will determine whether it is commercially viable to mine that deposit. The ease with which the wanted mineral(s) can be separated from gangue minerals also plays an important part. Early mining ventures, having relatively unsophisticated methods, often could not achieve a high degree of separation, so large quantities of minerals found their way into the waste mineral dumps of mines. As the value of a mineral increases, or when new and cheaper means of processing the ore to extract the wanted mineral(s) are introduced, it may become worthwhile to rework such old dumps to retrieve the wanted minerals they still contain.


Environmental impact of gangue minerals in mine tailings

Gangue minerals, once separated by mineral dressing processes of (most of) the valuable ore minerals and dumped in mine tailings may be a significant environmental impact. In particular, oxidation of pyrite, a common gangue mineral, is one of the main sources of acid mine drainage.


Re-use

Minerals that were once thought of as gangue, and were dumped, may later find a commercial use. When this happens, the old dumps are often reworked to extract the wanted mineral. For example, in
copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pink ...
mines in the 19th century the mineral
arsenopyrite Arsenopyrite ( IMA symbol: Apy) is an iron arsenic sulfide (FeAsS). It is a hard ( Mohs 5.5-6) metallic, opaque, steel grey to silver white mineral with a relatively high specific gravity of 6.1. When dissolved in nitric acid, it releases elem ...
was dumped until
arsenic Arsenic is a chemical element with the symbol As and atomic number 33. Arsenic occurs in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Arsenic is a metalloid. It has various allotropes, b ...
compounds became popular as
insecticide Insecticides are substances used to kill insects. They include ovicides and larvicides used against insect eggs and larvae, respectively. Insecticides are used in agriculture, medicine, industry and by consumers. Insecticides are claimed t ...
s later in the century. In the 21st century, the use of gangue has been considered from an environmental point of view. For example, in 2002, about 130 million tons of gangue were produced per year from coal mining in China. This, mixed with the 60 million tons of coal mud also produced, could be used for power generation; and the coal mining gangue could be combined with
coal fly ash Fly ash, flue ash, coal ash, or pulverised fuel ash (in the UK) plurale tantum: coal combustion residuals (CCRs)is a coal combustion product that is composed of the particulates (fine particles of burned fuel) that are driven out of coal-fired b ...
to produce building materials. The estimated cost of such projects would be up to 4 billion yuan, but would be expected to save just over 4 million tons of standard coal per year.


See also

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References

* ''An Elementary Outline Of Mechanical Processes'', by G. W. Danforth. 1912; 49. Elimination Of Gangue {{Authority control History of mining Ore deposits