Fuel system icing inhibitor
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Fuel system icing inhibitor (FSII) is an additive to
aviation fuel Aviation fuels are petroleum-based fuels, or petroleum and synthetic fuel blends, used to power aircraft. They have more stringent requirements than fuels used for ground use, such as heating and road transport, and contain additives to enhan ...
s that prevents the formation of ice in fuel lines. FSII is sometimes referred to by the registered, genericized trademark Prist. Jet fuel can contain a small amount of dissolved
water Water (chemical formula ) is an inorganic, transparent, tasteless, odorless, and nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living organisms (in which it acts as ...
that does not appear in droplet form. As an aircraft gains altitude, the temperature drops and the fuel's capacity to hold water is diminished. Dissolved water can separate out and could become a serious problem if it freezes in fuel lines or filters, blocking the flow of fuel and shutting down an
engine An engine or motor is a machine designed to convert one or more forms of energy into mechanical energy. Available energy sources include potential energy (e.g. energy of the Earth's gravitational field as exploited in hydroelectric power ...
.


Chemical composition

Chemically, FSII is an almost pure (99.9%) ethylene glycol monomethyl ether (EGMME, 2-methoxy ethanol, APISOLVE 76, CAS number ); or since 1994,
diethylene glycol monomethyl ether 2-(2-Methoxyethoxy)ethanol, also known under trade names Methyl carbitol, is an industrial solvent and is also commonly used as a fuel system icing inhibitor (FSII) in jet fuels. It is a clear, colorless, hygroscopic liquid. Structurally it is an ...
(DEGMME, 2-(2-methoxy ethoxy) ethanol, APITOL 120, methyl carbitol, CAS number ). Prior to 1994, Prist was regulated under the MIL-I-27686E standard, which specified use of EGMME, but subsequently came under the MIL-DTL-85470B, with use of less hazardous DEGMME with higher
flash point The flash point of a material is the "lowest liquid temperature at which, under certain standardized conditions, a liquid gives off vapours in a quantity such as to be capable of forming an ignitable vapour/air mixture". (EN 60079-10-1) The fl ...
. FSII was thought to retard the growth of microorganisms eventually present in the fuel, mostly ''
Cladosporium resinae ''Amorphotheca resinae'' is an ascomycete fungus of the family Amorphothecaceae which is known to thrive in environments containing alkanes (and water), like aviation fuel Aviation fuels are petroleum-based fuels, or petroleum and syntheti ...
'' fungi and ''
Pseudomonas aeruginosa ''Pseudomonas aeruginosa'' is a common encapsulated, gram-negative, aerobic– facultatively anaerobic, rod-shaped bacterium that can cause disease in plants and animals, including humans. A species of considerable medical importance, ''P. a ...
'' bacteria, known as "hydrocarbon utilizing microorganisms" or "HUM bugs", which live in the water-fuel interface of the water droplets, form dark, gel-like mats, and cause microbial corrosion to plastic and rubber parts. But has since been removed from labeling. EGMME had been certified as a
pesticide Pesticides are substances that are meant to control pests. This includes herbicide, insecticide, nematicide, molluscicide, piscicide, avicide, rodenticide, bactericide, insect repellent, animal repellent, microbicide, fungicide, and ...
by the EPA, but as the requirement changes raised the certification costs, DEGMME has no official pesticide certification. DEGMME is a potent
solvent A solvent (s) (from the Latin '' solvō'', "loosen, untie, solve") is a substance that dissolves a solute, resulting in a solution. A solvent is usually a liquid but can also be a solid, a gas, or a supercritical fluid. Water is a solvent for ...
, and at high concentrations can damage fuel bladders and filters. Long-term storage of FSII-fuel mixtures is therefore not recommended. Anhydrous
isopropyl alcohol Isopropyl alcohol (IUPAC name propan-2-ol and also called isopropanol or 2-propanol) is a colorless, flammable organic compound with a pungent alcoholic odor. As an isopropyl group linked to a hydroxyl group ( chemical formula ) it is the s ...
is sometimes used as an alternative.


Purpose

FSII is an agent that is mixed with
jet fuel Jet fuel or aviation turbine fuel (ATF, also abbreviated avtur) is a type of aviation fuel designed for use in aircraft powered by gas-turbine engines. It is colorless to straw-colored in appearance. The most commonly used fuels for commercial a ...
as it is pumped into the aircraft. The mixture of FSII must be between 0.10% and 0.15% by volume for the additive to work correctly, and the FSII must be distributed evenly throughout the fuel. Simply adding FSII after the fuel has been pumped is therefore not sufficient. As aircraft climbs after takeoff, the temperature drops, and any dissolved water will separate out from the fuel. FSII dissolves itself in water preferentially over the jet fuel, where it then serves to depress the freezing point of water to -43 °C. Since the freezing point of jet fuel itself is usually in this region, the formation of ice is now a minimal concern. Large aircraft do not require FSII as they are usually equipped with electric fuel line heaters or fuel/ oil intercoolers that keep the fuel at an appropriate temperature to prevent icing. However, if the fuel heaters are inoperable, the aircraft may be still be declared fit to fly, if FSII is added to the fuel.


Storage and dispensing

It is extremely important to store FSII properly. Drums containing FSII must be kept clean and dry, since the additive is
hygroscopic Hygroscopy is the phenomenon of attracting and holding water molecules via either absorption or adsorption from the surrounding environment, which is usually at normal or room temperature. If water molecules become suspended among the substance' ...
and can absorb water directly from moisture in the air. Since some brands of FSII are highly toxic, a crew member must wear gloves when handling it undiluted. Many FBOs allow FSII injection to be turned on or off so that one fuel truck can service planes that do require FSII as well as planes that don't. Line crew, however, must be able to deliver FSII when it is needed.


References

{{Reflist Aviation fuels