Forming gas is a mixture of

hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic ...

(mole fraction varies) and

nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...

. It is sometimes called a "dissociated

ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous wa ...

atmosphere" due to the reaction which generates it: :2 NH₃ → 3 H₂ + N₂ It can also be manufactured by thermal cracking of ammonia, in an ammonia cracker or forming gas generator. Forming gas is used as an atmosphere for processes that need the properties of hydrogen gas. Typical forming gas formulations (5% H2 in N2) are not explosive. It is used in chambers for gas hypersensitization, a process in which photographic film is heated in forming gas to drive out moisture and

oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as ...

and to increase the base fog of the film. Hypersensitization is used particularly in deep-sky

astrophotography Astrophotography, also known as astronomical imaging, is the photography or imaging of astronomical objects, celestial events, or areas of the night sky. The first photograph of an astronomical object (the Moon) was taken in 1840, but it was no ...

, which deals with low-intensity incoming light, requires long

exposure time In photography, shutter speed or exposure time is the length of time that the film or digital sensor inside the camera is exposed to light (that is, when the camera's shutter is open) when taking a photograph. The amount of light that re ...

s, and is thus particularly sensitive to contaminants in the film. Forming gas is also used to regenerate

catalyst Catalysis () is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst (). Catalysts are not consumed in the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recyc ...

s in

glove box A glovebox (or glove box) is a sealed container that is designed to allow one to manipulate objects where a separate atmosphere is desired. Built into the sides of the glovebox are gloves arranged in such a way that the user can place their hand ...

es and as an atmosphere for annealing processes. It can be purchased at

welding Welding is a fabrication process that joins materials, usually metals or thermoplastics, by using high heat to melt the parts together and allowing them to cool, causing fusion. Welding is distinct from lower temperature techniques such as bra ...

supply stores. It is sometimes used as a

reducing agent In chemistry, a reducing agent (also known as a reductant, reducer, or electron donor) is a chemical species that "donates" an electron to an (called the , , , or ). Examples of substances that are commonly reducing agents include the Earth me ...

for high-temperature

soldering Soldering (; ) is a process in which two or more items are joined by melting and putting a filler metal (solder) into the joint, the filler metal having a lower melting point than the adjoining metal. Unlike welding, soldering does not involv ...

and

brazing Brazing is a metal-joining process in which two or more metal items are joined together by melting and flowing a filler metal into the joint, with the filler metal having a lower melting point than the adjoining metal. Brazing differs from we ...

, to remove

oxidation Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a ...

of the joint without the use of flux. It also finds application in microchip production, where a high-temperature anneal in forming gas assists in silicon-silicon dioxide interface passivation. Quite often forming gas is used in furnaces during annealing or

sintering Clinker nodules produced by sintering Sintering or frittage is the process of compacting and forming a solid mass of material by pressure or heat without melting it to the point of liquefaction. Sintering happens as part of a manufacturing ...

for the thermal treatment of metals, because it reduces oxides on the metal surface.

References

{{DEFAULTSORT:Forming Gas Gases Welding Brazing and soldering Metal heat treatments Industrial gases

See also

References