Quartzite Mine in Kakwa Park.JPG
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Quartzite is a hard, non- foliated
metamorphic rock Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock ( protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, caus ...
which was originally pure
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical ...
sandstone Sandstone is a clastic sedimentary rock composed mainly of sand-sized (0.0625 to 2 mm) silicate grains. Sandstones comprise about 20–25% of all sedimentary rocks. Most sandstone is composed of quartz or feldspar (both silicates ...
.Essentials of Geology, 3rd Edition, Stephen Marshak, p 182 Sandstone is converted into quartzite through heating and pressure usually related to
tectonic Tectonics (; ) are the processes that control the structure and properties of the Earth's crust and its evolution through time. These include the processes of mountain building, the growth and behavior of the strong, old cores of continents ...
compression within
orogenic belts Orogeny is a mountain building process. An orogeny is an event that takes place at a convergent plate margin when plate motion compresses the margin. An ''orogenic belt'' or ''orogen'' develops as the compressed plate crumples and is uplifted t ...
. Pure quartzite is usually white to grey, though quartzites often occur in various shades of pink and red due to varying amounts of hematite. Other colors, such as yellow, green, blue and orange, are due to other minerals. The term ''quartzite'' is also sometimes used for very hard but unmetamorphosed
sandstones Sandstone is a clastic sedimentary rock composed mainly of sand-sized (0.0625 to 2 mm) silicate grains. Sandstones comprise about 20–25% of all sedimentary rocks. Most sandstone is composed of quartz or feldspar (both silicates) b ...
that are composed of quartz grains thoroughly cemented with additional quartz. Such sedimentary rock has come to be described as orthoquartzite to distinguish it from metamorphic quartzite, which is sometimes called metaquartzite to emphasize its metamorphic origins. Quartzite is very resistant to chemical
weathering Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs ''in situ'' (on site, with little or no movement) ...
and often forms ridges and resistant hilltops. The nearly pure silica content of the rock provides little material for
soil Soil, also commonly referred to as earth or dirt Dirt is an unclean matter, especially when in contact with a person's clothes, skin, or possessions. In such cases, they are said to become dirty. Common types of dirt include: * Debri ...
; therefore, the quartzite ridges are often bare or covered only with a very thin layer of soil and little (if any) vegetation. Some quartzites contain just enough weather-susceptible nutrient-bearing minerals such as
carbonates A carbonate is a salt of carbonic acid (H2CO3), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word ''carbonate'' may also refer to a carbonate ester, an organic compound containing the carbonate g ...
and chlorite to form a loamy, fairly fertile though shallow and stony soil. Quartzite has been used since prehistoric times for stone tools. It is presently used for decorative dimension stone, as crushed stone in highway construction, and as a source of
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is ...
for production of
silicon Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic ta ...
and silicon compounds.


Characteristics and origin

Quartzite is a very hard rock composed predominantly of an interlocking mosaic of quartz crystals. The grainy, sandpaper-like surface is glassy in appearance. Minor amounts of former cementing materials, iron oxide, silica, carbonate and clay, often migrate during recrystallization, causing streaks and lenses to form within the quartzite. To be classified as a quartzite by the British Geological Survey, a metamorphic rock must contain at least 80% quartz by volume. Quartzite is commonly regarded as metamorphic in origin. When sandstone is subjected to the great heat and pressure associated with regional metamorphism, the individual quartz grains recrystallize along with the former cementing material. Most or all of the original texture and sedimentary structures of the sandstone are erased by the metamorphism. The recrystallized quartz grains are roughly equal in size, forming what is called a granoblastic texture, and they also show signs of metamorphic annealing, in which the grains become coarser and acquire a more polygonal texture. The grains are so tightly interlocked that when the rock is broken, it fractures through the grains to form an irregular or conchoidal fracture. Geologists had recognized by 1941 that some rocks show the macroscopic characteristics of quartzite, even though they have not undergone metamorphism at high pressure and temperature. These rocks have been subject only to the much lower temperatures and pressures associated with
diagenesis Diagenesis () is the process that describes physical and chemical changes in sediments first caused by water-rock interactions, microbial activity, and compaction after their deposition. Increased pressure and temperature only start to play a ...
of sedimentary rock, but diagenesis has cemented the rock so thoroughly that microscopic examination is necessary to distinguish it from metamorphic quartize. The term ''orthoquartzite'' is used to distinguish such sedimentary rock from ''metaquartzite'' produced by metamorphism. By extension, the term ''orthoquartzite'' has occasionally been more generally applied to any quartz-cemented
quartz arenite A quartz arenite or quartzarenite is a sandstone composed of greater than 90% detrital quartz. Quartz arenites are the most mature sedimentary rocks possible, and are often referred to as ultra- or super-mature, and are usually cemented by sili ...
. Orthoquartzite (in the narrow sense) is often 99% SiO2 with only very minor amounts of iron oxide and trace resistant minerals such as
zircon Zircon () is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is Zr SiO4. An empirical formula showing some of t ...
,
rutile Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer polymorphs of TiO2 are known, including anatase, akaogiite, and brookite. Rutile has one of the highest refractive indices at visib ...
and
magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With th ...
. Although few
fossil A fossil (from Classical Latin , ) is any preserved remains, impression, or trace of any once-living thing from a past geological age. Examples include bones, shells, exoskeletons, stone imprints of animals or microbes, objects preserved ...
s are normally present, the original texture and
sedimentary Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles ...
structures are preserved. The typical distinction between a true orthoquartzite and an ordinary quartz sandstone is that an orthoquartzite is so highly cemented that it will fracture across grains, not around them. This is a distinction that can be recognized in the
field Field may refer to: Expanses of open ground * Field (agriculture), an area of land used for agricultural purposes * Airfield, an aerodrome that lacks the infrastructure of an airport * Battlefield * Lawn, an area of mowed grass * Meadow, a grass ...
. In turn, the distinction between an orthoquartzite and a metaquartzite is the onset of recrystallization of existing grains. The dividing line may be placed at the point where strained quartz grains begin to be replaced by new, unstrained, small quartz grains, producing a ''mortar texture'' that can be identified in thin sections under a polarizing microscope. With increasing grade of metamorphism, further recrystallization produces ''foam texture'', characterized by polygonal grains meeting at triple junctions, and then ''porphyroblastic texture'', characterized by coarse, irregular grains, including some larger grains (
porphyroblasts A porphyroblast is a large mineral crystal in a metamorphic rock which has grown within the finer grained matrix. Porphyroblasts are commonly euhedral crystals, but can also be partly to completely irregular in shape. The most common porphyrobl ...
.)


Occurrence

In the United States, formations of quartzite can be found in some parts of Pennsylvania, the Washington DC area, eastern
South Dakota South Dakota (; Sioux: , ) is a U.S. state in the North Central region of the United States. It is also part of the Great Plains. South Dakota is named after the Lakota and Dakota Sioux Native American tribes, who comprise a large porti ...
, Central Texas, southwest
Minnesota Minnesota () is a state in the upper midwestern region of the United States. It is the 12th largest U.S. state in area and the 22nd most populous, with over 5.75 million residents. Minnesota is home to western prairies, now given over to ...
, Devil's Lake State Park in the Baraboo Range in
Wisconsin Wisconsin () is a state in the upper Midwestern United States. Wisconsin is the 25th-largest state by total area and the 20th-most populous. It is bordered by Minnesota to the west, Iowa to the southwest, Illinois to the south, Lake M ...
, the
Wasatch Range The Wasatch Range ( ) or Wasatch Mountains is a mountain range in the western United States that runs about from the Utah-Idaho border south to central Utah. It is the western edge of the greater Rocky Mountains, and the eastern edge of the G ...
in
Utah Utah ( , ) is a state in the Mountain West subregion of the Western United States. Utah is a landlocked U.S. state bordered to its east by Colorado, to its northeast by Wyoming, to its north by Idaho, to its south by Arizona, and to it ...
, near Salt Lake City, Utah and as resistant ridges in the
Appalachians The Appalachian Mountains, often called the Appalachians, (french: Appalaches), are a system of mountains in eastern to northeastern North America. The Appalachians first formed roughly 480 million years ago during the Ordovician Period. They ...
and other mountain regions. Quartzite is also found in the Morenci Copper Mine in
Arizona Arizona ( ; nv, Hoozdo Hahoodzo ; ood, AlÄ­ á¹£onak ) is a state in the Southwestern United States. It is the 6th largest and the 14th most populous of the 50 states. Its capital and largest city is Phoenix. Arizona is part of the Fou ...
. The town of
Quartzsite Quartzsite is a town in La Paz County, Arizona, United States. According to the 2020 census, the population was 2,413. Interstate 10 runs directly through Quartzsite which is at the intersection of U.S. Route 95 and Arizona State Route 95 wi ...
in western Arizona derives its name from the quartzites in the nearby mountains in both Arizona and Southeastern California. A glassy ''vitreous quartzite'' has been described from the Belt Supergroup in the Coeur d’Alene district of northern
Idaho Idaho ( ) is a state in the Pacific Northwest region of the Western United States. To the north, it shares a small portion of the Canada–United States border with the province of British Columbia. It borders the states of Montana and Wyomi ...
. In Canada, the
La Cloche Mountains The La Cloche Mountains, also called the La Cloche Range, are a range of mountains in Northern Ontario, Canada, along the northern shore of Lake Huron near Manitoulin Island. The mountains are located in the Canadian Shield, and are composed pr ...
in
Ontario Ontario ( ; ) is one of the thirteen provinces and territories of Canada.Ontario is located in the geographic eastern half of Canada, but it has historically and politically been considered to be part of Central Canada. Located in Central C ...
are composed primarily of white quartzite. Vast areas of
Nova Scotia Nova Scotia ( ; ; ) is one of the thirteen provinces and territories of Canada. It is one of the three Maritime provinces and one of the four Atlantic provinces. Nova Scotia is Latin for "New Scotland". Most of the population are native Eng ...
are underlain by quartzite.
Paleoproterozoic The Paleoproterozoic Era (;, also spelled Palaeoproterozoic), spanning the time period from (2.5–1.6  Ga), is the first of the three sub-divisions ( eras) of the Proterozoic Eon. The Paleoproterozoic is also the longest era of the Earth's ...
quartzite- rhyolite successions are common in the Precambrian basement rock of western North America. The quartzites in these successions are interpreted as sedimentary beds deposited atop older greenstone belts. The quartzite-rhyolite successions may record the formation of back-arc basins along the margin of
Laurentia Laurentia or the North American Craton is a large continental craton that forms the ancient geological core of North America. Many times in its past, Laurentia has been a separate continent, as it is now in the form of North America, althoug ...
, the ancient core of North America, between episodes of mountain building during the assembly of the continent. The quartzites are often nearly pure quartz, which is puzzling for sediments which must have eroded from igneous rock. Their purity may reflect unusual conditions of chemical weathering, at a time when the Earth's atmosphere was beginning to be oxygenated. In
Ireland Ireland ( ; ga, Éire ; Ulster Scots dialect, Ulster-Scots: ) is an island in the Atlantic Ocean, North Atlantic Ocean, in Northwestern Europe, north-western Europe. It is separated from Great Britain to its east by the North Channel (Grea ...
areas of quartzite are found across the west and northwest, with
Errigal Errigal () is a mountain near Gweedore in County Donegal, Ireland. It is the tallest peak of the Derryveagh Mountains and the tallest peak in County Donegal. Errigal is also the most southern and the highest of the mountain chain called the ...
in Donegal as the most prominent outcrop. A good example of a quartzite area is on An Corràn peninsula, in Co. Mayo, which has a very thin layer of Irish Atlantic Bog covering it. In the United Kingdom, a craggy ridge of quartzite called the Stiperstones (early
Ordovician The Ordovician ( ) is a geologic period and system, the second of six periods of the Paleozoic Era. The Ordovician spans 41.6 million years from the end of the Cambrian Period million years ago (Mya) to the start of the Silurian Period Mya. T ...
– Arenig Epoch, 500 Ma) runs parallel with the Pontesford-Linley fault, 6 km north-west of the
Long Mynd , photo = , photo_alt = , photo_caption = View down Townbrook Valley toward Burway Hill , country_type = , country = England , subdivision1_type = County , subdivision1 = Shropshire , border ...
in south
Shropshire Shropshire (; alternatively Salop; abbreviated in print only as Shrops; demonym Salopian ) is a landlocked historic county in the West Midlands region of England. It is bordered by Wales to the west and the English counties of Cheshire to ...
. Also to be found in
England England is a country that is part of the United Kingdom. It shares land borders with Wales to its west and Scotland to its north. The Irish Sea lies northwest and the Celtic Sea to the southwest. It is separated from continental Europe b ...
are the Cambrian "
Wrekin The Wrekin is a hill in east Shropshire, England. It is located some five miles (8 km) west of Telford, on the border between the unitary authorities of Shropshire and Telford and Wrekin. Rising above the Shropshire Plain to a height of 4 ...
quartzite" (in Shropshire), and the Cambrian "
Hartshill Hartshill is a large village and civil parish in North Warwickshire, England, 2.5 miles (4 km) north-west of the town of Nuneaton. The parish borders the district of Nuneaton and Bedworth at the south, the North Warwickshire district parishes ...
quartzite" ( Nuneaton area). In
Wales Wales ( cy, Cymru ) is a country that is part of the United Kingdom. It is bordered by England to the east, the Irish Sea to the north and west, the Celtic Sea to the south west and the Bristol Channel to the south. It had a population in ...
,
Holyhead Mountain Holyhead Mountain (''Mynydd Twr'' in Welsh: from ''(pen)twr'', meaning "tower") is the highest mountain on Holy Island, Anglesey, and the highest in the county of Anglesey, north Wales. It lies about two miles west of the town of Holyhead, and s ...
and most of Holy island off
Anglesey Anglesey (; cy, (Ynys) Môn ) is an island off the north-west coast of Wales. It forms a principal area known as the Isle of Anglesey, that includes Holy Island across the narrow Cymyran Strait and some islets and skerries. Anglesey island ...
sport excellent Precambrian quartzite crags and cliffs. In the
Scottish Highlands The Highlands ( sco, the Hielands; gd, a’ Ghàidhealtachd , 'the place of the Gaels') is a historical region of Scotland. Culturally, the Highlands and the Lowlands diverged from the Late Middle Ages into the modern period, when Lowland S ...
, several mountains (e.g.
Foinaven – , photo = Foinaven_from_Achriesgill.jpg , photo_caption = Foinaven seen from Achriesgill on Loch Inchard , elevation_m = 911 , elevation_ref = , prominence_m = 690 , prominence_ref = , parent_peak = Ben Klibreck , listing = Mari ...
, Arkle) composed of Cambrian quartzite can be found in the far north-west
Moine Thrust Belt The Moine Thrust Belt or Moine Thrust Zone is a linear tectonics, tectonic feature in the Scottish Highlands which runs from Loch Eriboll on the north coast south-west to the Sleat peninsula on the Isle of Skye. The thrust belt consists of a s ...
running in a narrow band from
Loch Eriboll __NOTOC__ Loch Eriboll (Scottish Gaelic: "Loch Euraboil") is a long sea loch on the north coast of Scotland, which has been used for centuries as a deep water anchorage as it is safe from the often stormy seas of Cape Wrath and the Pentland Firt ...
in a south-westerly direction to Skye. In continental Europe, various regionally isolated quartzite deposits exist at surface level in a belt from the Rhenish Massif and the German Central Highlands into the Western
Czech Republic The Czech Republic, or simply Czechia, is a landlocked country in Central Europe. Historically known as Bohemia, it is bordered by Austria to the south, Germany to the west, Poland to the northeast, and Slovakia to the southeast. The ...
, for example in the
Taunus The Taunus is a mountain range in Hesse, Germany, located north of Frankfurt. The tallest peak in the range is '' Großer Feldberg'' at 878 m; other notable peaks are ''Kleiner Feldberg'' (825 m) and '' Altkönig'' (798 m). The Taunus range span ...
and
Harz The Harz () is a highland area in northern Germany. It has the highest elevations for that region, and its rugged terrain extends across parts of Lower Saxony, Saxony-Anhalt, and Thuringia. The name ''Harz'' derives from the Middle High German ...
mountains. In Poland quartzite deposits at surface level exists in
Świętokrzyskie Mountains The Świętokrzyskie Mountains ( pl, Góry Świętokrzyskie, ), often anglicized to Holy Cross Mountains, are a mountain range in central Poland, near the city of Kielce. The Świętokrzyskie Mountains are some of the oldest mountains in Europ ...
. In Norway, deposits are quarried near Austertana, which is one of the largest quarries in the world at 850,000
metric tonnes The tonne ( or ; symbol: t) is a unit of mass equal to 1000 kilograms. It is a non-SI unit accepted for use with SI. It is also referred to as a metric ton to distinguish it from the non-metric units of the short ton (United States c ...
) annually, and Mårnes near Sandhornøy with an output of 150,000 metric tonnes annually. Deposits are also quarried at
Kragerø Kragerø () is a town and municipality in Vestfold og Telemark county, Norway. It is part of the traditional regions of Grenland and the smaller Vestmar. The administrative centre of the municipality is the town of Kragerø. The city of Kragerà ...
, and several other deposits are known but not actively quarried. The highest mountain in
Mozambique Mozambique (), officially the Republic of Mozambique ( pt, Moçambique or , ; ny, Mozambiki; sw, Msumbiji; ts, Muzambhiki), is a country located in southeastern Africa bordered by the Indian Ocean to the east, Tanzania to the north, Malawi ...
,
Monte Binga Monte Binga is the highest mountain in Mozambique and the second highest mountain in Zimbabwe. It is located in the Chimanimani Mountains, on the border between Zimbabwe and Mozambique in the Chimanimani Transfrontier Park in Manica Province. I ...
(2436 m), as well as the rest of the surrounding Chimanimani Plateau are composed of very hard, pale grey, Precambrian quartzite. Quartzite is also mined in Brazil for use in kitchen countertops.


Uses

Quartzite is a decorative stone and may be used to cover walls, as roofing tiles, as flooring, and stairsteps. Its use for countertops in kitchens is expanding rapidly. It is harder and more resistant to stains than granite. Crushed quartzite is sometimes used in road construction. High purity quartzite is used to produce
ferrosilicon Ferrosilicon is an alloy of iron and silicon with a typical silicon content by weight of 15–90%. It contains a high proportion of iron silicides. Production and reactions Ferrosilicon is produced by reduction of silica or sand with coke in t ...
, industrial
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is ...
sand,
silicon Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic ta ...
and
silicon carbide Silicon carbide (SiC), also known as carborundum (), is a hard chemical compound containing silicon and carbon. A semiconductor, it occurs in nature as the extremely rare mineral moissanite, but has been mass-produced as a powder and crystal s ...
. During the Paleolithic, quartzite was used, along with
flint Flint, occasionally flintstone, is a sedimentary cryptocrystalline form of the mineral quartz, categorized as the variety of chert that occurs in chalk or marly limestone. Flint was widely used historically to make stone tools and sta ...
,
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical ...
, and other lithic raw materials, for making
stone tools A stone tool is, in the most general sense, any tool made either partially or entirely out of stone. Although stone tool-dependent societies and cultures still exist today, most stone tools are associated with prehistoric (particularly Stone Ag ...
.


Safety

As quartzite is a form of silica, it is a possible cause for concern in various workplaces. Cutting, grinding, chipping, sanding, drilling, and polishing natural and manufactured stone products can release hazardous levels of very small, crystalline silica dust particles into the air that workers breathe. Crystalline silica of respirable size is a recognized human
carcinogen A carcinogen is any substance, radionuclide, or radiation that promotes carcinogenesis (the formation of cancer). This may be due to the ability to damage the genome or to the disruption of cellular metabolic processes. Several radioactive subs ...
and may lead to other diseases of the lungs such as silicosis and
pulmonary fibrosis Pulmonary fibrosis is a condition in which the lungs become scarred over time. Symptoms include shortness of breath, a dry cough, feeling tired, weight loss, and nail clubbing. Complications may include pulmonary hypertension, respiratory failu ...
.


Etymology

The term ''quartzite'' is derived from german: Quarzit. File:SwanPeakQuartziteOutcrop.jpg, Swan Peak Quartzite (
Ordovician The Ordovician ( ) is a geologic period and system, the second of six periods of the Paleozoic Era. The Ordovician spans 41.6 million years from the end of the Cambrian Period million years ago (Mya) to the start of the Silurian Period Mya. T ...
) exposed just north of
Tony Grove Lake Tony Grove Lake is a lake in Cache County, Utah. The Tony Grove Lake Campground is located on the southeast shore of the lake. The lake and campground are situated on the Logan Canyon Scenic Byway. A paved road climbs to a height of to reac ...
, Cache County, Utah File:View_of_Doso_Doyabi_from_Wheeler_Peak.jpg, The quartzite of the Prospect Mountain Formation at the top of
Doso Doyabi Wheeler Peak is the tallest mountain in the Snake Range and in White Pine County, in Nevada, United States. The summit elevation of makes it the second-highest peak in Nevada, just behind Boundary Peak. With a topographic prominence of , Whee ...
in
White Pine County, Nevada White Pine County is a largely rural, mountain county along the central eastern boundary of the U.S. state of Nevada. As of the 2010 census, the population was 10,030. Its county seat is Ely. The name "(Rocky Mountain) white pine" is an old ...
Image:Normal view of Bo Quartzite.JPG, Quartzite from Salangen, South Troms, Norway, showing elongate crystals associated with high
strain Strain may refer to: Science and technology * Strain (biology), variants of plants, viruses or bacteria; or an inbred animal used for experimental purposes * Strain (chemistry), a chemical stress of a molecule * Strain (injury), an injury to a mu ...
regimes Image:Thin section image of quartzie.jpg,
Thin section In optical mineralogy and petrography, a thin section (or petrographic thin section) is a thin slice of a rock or mineral sample, prepared in a laboratory, for use with a polarizing petrographic microscope, electron microscope and electron ...
of quartzite from Salangen, South Troms, Norway, showing elongate crystals associated with high strain regimes


See also

*
Neomorphism Neomorphism refers to the wet metamorphic process in which diagenetic alterations systematically transform minerals into either polymorphs or crystalline structures that are structurally identical to the rock(s) from which they developed. Coined ...


References


External links


R. V. Dietrich's GemRocks: Quartzite




* ttps://web.archive.org/web/20100309140357/http://www.dnr.state.mn.us/snas/naturalhistory.html Minnesota Department of Natural Resources : Natural History: Minnesota's geology
Wisconsin's Baraboo Syncline (map and aerial photos of Baraboo quartzite quarries)

South Dakota 2002 Mineral Summary: Production, Exploration and Environmental Issues (including 2002 quartzite production)


{{Authority control Quartz varieties Metasedimentary rocks