Hydroxide is a diatomic anion with

chemical formula In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbol ...

OH⁻. It consists of an

oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as ...

and

hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic ...

atom Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas, ...

held together by a single covalent bond, and carries a negative

electric charge Electric charge is the physical property of matter that causes charged matter to experience a force when placed in an electromagnetic field. Electric charge can be ''positive'' or ''negative'' (commonly carried by protons and electrons respe ...

. It is an important but usually minor constituent of water. It functions as a base, a

ligand In coordination chemistry, a ligand is an ion or molecule ( functional group) that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one or more of the ligand's elec ...

, a nucleophile, and a

catalyst Catalysis () is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst (). Catalysts are not consumed in the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recyc ...

. The hydroxide ion forms

salts In chemistry, a salt is a chemical compound consisting of an ionic assembly of positively charged cations and negatively charged anions, which results in a compound with no net electric charge. A common example is table salt, with positively c ...

, some of which

dissociate Dissociation in chemistry is a general process in which molecules (or ionic compounds such as salts, or complexes) separate or split into other things such as atoms, ions, or radicals, usually in a reversible manner. For instance, when an acid ...

in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum

commodity chemical Commodity chemicals (or bulk commodities or bulk chemicals) are a group of chemicals that are made on a very large scale to satisfy global markets. The average prices of commodity chemicals are regularly published in the chemical trade magazines an ...

. The corresponding

electrically neutral Electric charge is the physical property of matter that causes charged matter to experience a force when placed in an electromagnetic field. Electric charge can be ''positive'' or ''negative'' (commonly carried by protons and electrons respe ...

compound HO^• is the

hydroxyl radical The hydroxyl radical is the diatomic molecule . The hydroxyl radical is very stable as a dilute gas, but it decays very rapidly in the condensed phase. It is pervasive in some situations. Most notably the hydroxyl radicals are produced from the ...

. The corresponding

covalently A covalent bond is a chemical bond that involves the sharing of electrons to form electron pairs between atoms. These electron pairs are known as shared pairs or bonding pairs. The stable balance of attractive and repulsive forces between atom ...

bound

group A group is a number of persons or things that are located, gathered, or classed together. Groups of people * Cultural group, a group whose members share the same cultural identity * Ethnic group, a group whose members share the same ethnic ide ...

–OH of atoms is the hydroxy group. Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in

organic chemistry Organic chemistry is a subdiscipline within chemistry involving the scientific study of the structure, properties, and reactions of organic compounds and organic materials, i.e., matter in its various forms that contain carbon atoms.Clayden, ...

. Many

inorganic In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemist ...

substances which bear the word ''hydroxide'' in their names are not ionic compounds of the hydroxide ion, but covalent compounds which contain hydroxy groups.

Hydroxide ion

The hydroxide ion is a natural part of

water Water (chemical formula ) is an Inorganic compound, inorganic, transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living ...

because of the self-ionization reaction in which its complement,

hydronium In chemistry, hydronium (hydroxonium in traditional British English) is the common name for the aqueous cation , the type of oxonium ion produced by protonation of water. It is often viewed as the positive ion present when an Arrhenius acid i ...

, is passed hydrogen: : H₃O⁺ + OH⁻ 2H₂O The

equilibrium constant The equilibrium constant of a chemical reaction is the value of its reaction quotient at chemical equilibrium, a state approached by a dynamic chemical system after sufficient time has elapsed at which its composition has no measurable tendency ...

for this reaction, defined as :''K''_w = ⁺OH⁻] ⁺denotes the concentration of hydrogen cations and H⁻the concentration of hydroxide ions has a value close to 10⁻¹⁴ at 25 °C, so the

concentration In chemistry, concentration is the abundance of a constituent divided by the total volume of a mixture. Several types of mathematical description can be distinguished: '' mass concentration'', ''molar concentration'', '' number concentration'', ...

of hydroxide ions in pure water is close to 10⁻⁷ mol∙dm⁻³, in order to satisfy the equal charge constraint. The pH of a solution is equal to the decimal

cologarithm In mathematics, the logarithm is the inverse function to exponentiation. That means the logarithm of a number to the base is the exponent to which must be raised, to produce . For example, since , the ''logarithm base'' 10 o ...

of the

hydrogen cation In chemistry, the hydron, informally called proton, is the cationic form of atomic hydrogen, represented with the symbol . The general term "hydron", endorsed by the IUPAC, encompasses cations of hydrogen regardless of their isotopic composition: ...

concentration;Strictly speaking pH is the cologarithm of the hydrogen cation activity the pH of pure water is close to 7 at ambient temperatures. The concentration of hydroxide ions can be expressed in terms of pOH, which is close to (14 − pH),pOH signifies the minus the logarithm to base 10 of H⁻ alternatively the logarithm of so the pOH of pure water is also close to 7. Addition of a base to water will reduce the hydrogen cation concentration and therefore increase the hydroxide ion concentration (increase pH, decrease pOH) even if the base does not itself contain hydroxide. For example,

ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous wa ...

solutions have a pH greater than 7 due to the reaction NH₃ + H⁺ , which decreases the hydrogen cation concentration, which increases the hydroxide ion concentration. pOH can be kept at a nearly constant value with various

buffer solution A buffer solution (more precisely, pH buffer or hydrogen ion buffer) is an aqueous solution consisting of a mixture of a weak acid and its conjugate base, or vice versa. Its pH changes very little when a small amount of strong acid or base is ...

In aqueous solution the hydroxide ion is a base in the Brønsted–Lowry sense as it can accept a protonIn this context proton is the term used for a solvated hydrogen cation from a Brønsted–Lowry acid to form a water molecule. It can also act as a Lewis base by donating a pair of electrons to a Lewis acid. In aqueous solution both hydrogen and hydroxide ions are strongly solvated, with hydrogen bonds between oxygen and hydrogen atoms. Indeed, the bihydroxide ion has been characterized in the solid state. This compound is centrosymmetric and has a very short hydrogen bond (114.5 pm) that is similar to the length in the

bifluoride The bifluoride ion is an inorganic anion with the chemical formula . The anion is colorless. Salts of bifluoride are commonly encountered in the reactions of fluoride salts with hydrofluoric acid. The commercial production of fluorine involves e ...

ion (114 pm). In aqueous solution the hydroxide ion forms strong hydrogen bonds with water molecules. A consequence of this is that concentrated solutions of sodium hydroxide have high

viscosity The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the inte ...

due to the formation of an extended network of hydrogen bonds as in hydrogen fluoride solutions. In solution, exposed to air, the hydroxide ion reacts rapidly with atmospheric

carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is trans ...

, acting as an acid, to form, initially, the

bicarbonate In inorganic chemistry, bicarbonate (IUPAC-recommended nomenclature: hydrogencarbonate) is an intermediate form in the deprotonation of carbonic acid. It is a polyatomic anion with the chemical formula . Bicarbonate serves a crucial biochem ...

ion. :OH⁻ + CO₂ The

for this reaction can be specified either as a reaction with dissolved carbon dioxide or as a reaction with carbon dioxide gas (see Carbonic acid for values and details). At neutral or acid pH, the reaction is slow, but is catalyzed by the

enzyme Enzymes () are proteins that act as biological catalysts by accelerating chemical reactions. The molecules upon which enzymes may act are called substrates, and the enzyme converts the substrates into different molecules known as products ...

carbonic anhydrase, which effectively creates hydroxide ions at the active site. Solutions containing the hydroxide ion attack

glass Glass is a non-crystalline, often transparent, amorphous solid that has widespread practical, technological, and decorative use in, for example, window panes, tableware, and optics. Glass is most often formed by rapid cooling ( quenching ...

. In this case, the silicates in glass are acting as acids. Basic hydroxides, whether solids or in solution, are stored in

airtight A hermetic seal is any type of sealing that makes a given object airtight (preventing the passage of air, oxygen, or other gases). The term originally applied to airtight glass containers, but as technology advanced it applied to a larger categor ...

plastic containers. The hydroxide ion can function as a typical electron-pair donor

, forming such complexes as tetrahydroxoaluminate/tetrahydroxido

aluminate In chemistry, an aluminate is a compound containing an oxyanion of aluminium, such as sodium aluminate. In the naming of inorganic compounds, it is a suffix that indicates a polyatomic anion with a central aluminum atom. Aluminate oxyanions Alum ...

l(OH)₄sup>−. It is also often found in mixed-ligand complexes of the type L_''x''(OH)_''y''sup>''z''+, where L is a ligand. The hydroxide ion often serves as a

bridging ligand In coordination chemistry, a bridging ligand is a ligand that connects two or more atoms, usually metal ions. The ligand may be atomic or polyatomic. Virtually all complex organic compounds can serve as bridging ligands, so the term is usually ...

, donating one pair of electrons to each of the atoms being bridged. As illustrated by b₂(OH)sup>3+, metal hydroxides are often written in a simplified format. It can even act as a 3-electron-pair donor, as in the tetramer tMe₃(OH)sub>4. When bound to a strongly electron-withdrawing metal centre, hydroxide ligands tend to ionise into oxide ligands. For example, the bichromate ion CrO₄sup>− dissociates according to : ₃CrO–Hsup>− rO₄sup>2− + H⁺ with a p''K''_a of about 5.9.IUPAC SC-Database
A comprehensive database of published data on equilibrium constants of metal complexes and ligands

Vibrational spectra

The infrared spectra of compounds containing the OH

functional group In organic chemistry, a functional group is a substituent or moiety in a molecule that causes the molecule's characteristic chemical reactions. The same functional group will undergo the same or similar chemical reactions regardless of the re ...

have strong

absorption bands A spectral line is a dark or bright line in an otherwise uniform and continuous spectrum, resulting from emission or absorption of light in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to identi ...

in the region centered around 3500 cm⁻¹. The high frequency of molecular vibration is a consequence of the small mass of the hydrogen atom as compared to the mass of the oxygen atom, and this makes detection of hydroxyl groups by infrared spectroscopy relatively easy. A band due to an OH group tends to be sharp. However, the band width increases when the OH group is involved in hydrogen bonding. A water molecule has an HOH bending mode at about 1600 cm⁻¹, so the absence of this band can be used to distinguish an OH group from a water molecule. When the OH group is bound to a metal ion in a

coordination complex A coordination complex consists of a central atom or ion, which is usually metallic and is called the ''coordination centre'', and a surrounding array of bound molecules or ions, that are in turn known as '' ligands'' or complexing agents. ...

, an M−OH bending mode can be observed. For example, in n(OH)₆sup>2− it occurs at 1065 cm⁻¹. The bending mode for a bridging hydroxide tends to be at a lower frequency as in bipyridine)Cu(OH)₂Cu(bipyridine.html" ;"title="bipyridine.html" ;"title="bipyridine">bipyridine)Cu(OH)₂Cu(bipyridine">bipyridine.html" ;"title="bipyridine">bipyridine)Cu(OH)₂Cu(bipyridine)]²⁺ (955 cm⁻¹). M−OH stretching vibrations occur below about 600 cm⁻¹. For example, the tetrahedron, tetrahedral ion [Zn(OH)₄]²⁻ has bands at 470 cm⁻¹ ( Raman-active, polarized) and 420 cm⁻¹ (infrared). The same ion has a (HO)–Zn–(OH) bending vibration at 300 cm⁻¹.

Applications

Sodium hydroxide solutions, also known as

lye A lye is a metal hydroxide traditionally obtained by leaching wood ashes, or a strong alkali which is highly soluble in water producing caustic basic solutions. "Lye" most commonly refers to sodium hydroxide (NaOH), but historically has been u ...

and caustic soda, are used in the manufacture of

pulp Pulp may refer to: * Pulp (fruit), the inner flesh of fruit Engineering * Dissolving pulp, highly purified cellulose used in fibre and film manufacture * Pulp (paper), the fibrous material used to make paper * Molded pulp, a packaging material ...

and

paper Paper is a thin sheet material produced by mechanically or chemically processing cellulose fibres derived from wood, rags, grasses or other vegetable sources in water, draining the water through fine mesh leaving the fibre evenly distrib ...

textile Textile is an umbrella term that includes various fiber-based materials, including fibers, yarns, filaments, threads, different fabric types, etc. At first, the word "textiles" only referred to woven fabrics. However, weaving is not the ...

drinking water Drinking water is water that is used in drink or food preparation; potable water is water that is safe to be used as drinking water. The amount of drinking water required to maintain good health varies, and depends on physical activity level, a ...

soap Soap is a salt of a fatty acid used in a variety of cleansing and lubricating products. In a domestic setting, soaps are surfactants usually used for washing, bathing, and other types of housekeeping. In industrial settings, soaps are use ...

s and detergents, and as a

drain cleaner A drain cleaner is method for unblocking sewer pipes or clogged wastewater drains. The term may also refer to a mechanical device such as a plumber's snake, drain auger, toilet plunger, or similar device. Occasionally, the term is applied to a pl ...

. Worldwide production in 2004 was approximately 60 million

tonne The tonne ( or ; symbol: t) is a unit of mass equal to 1000 kilograms. It is a non-SI unit accepted for use with SI. It is also referred to as a metric ton to distinguish it from the non-metric units of the short ton ( United State ...

s. The principal method of manufacture is the

chloralkali process The chloralkali process (also chlor-alkali and chlor alkali) is an industrial process for the electrolysis of sodium chloride (NaCl) solutions. It is the technology used to produce chlorine and sodium hydroxide (caustic soda), which are commodit ...

. Solutions containing the hydroxide ion are generated when a salt of a

weak acid Acid strength is the tendency of an acid, symbolised by the chemical formula HA, to dissociate into a proton, H+, and an anion, A-. The dissociation of a strong acid in solution is effectively complete, except in its most concentrated solutions ...

is dissolved in water. Sodium carbonate is used as an alkali, for example, by virtue of the

hydrolysis Hydrolysis (; ) is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution, elimination, and solvation reactions in which water is the nucleophile. Biological hydrolys ...

reaction : + H₂O + OH⁻ ( p''K''_a2= 10.33 at 25 °C and zero ionic strength) Although the base strength of sodium carbonate solutions is lower than a concentrated sodium hydroxide solution, it has the advantage of being a solid. It is also manufactured on a vast scale (42 million tonnes in 2005) by the

Solvay process The Solvay process or ammonia-soda process is the major industrial process for the production of sodium carbonate (soda ash, Na2CO3). The ammonia-soda process was developed into its modern form by the Belgian chemist Ernest Solvay during the 1860s ...

.Kostick, Dennis (2006)
"Soda Ash"
chapter in ''2005 Minerals Yearbook,'' United States Geological Survey. An example of the use of sodium carbonate as an alkali is when

washing soda Sodium carbonate, , (also known as washing soda, soda ash and soda crystals) is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield moderately alkaline solutions ...

(another name for sodium carbonate) acts on insoluble esters, such as

triglyceride A triglyceride (TG, triacylglycerol, TAG, or triacylglyceride) is an ester derived from glycerol and three fatty acids (from ''wikt:tri-#Prefix, tri-'' and ''glyceride''). Triglycerides are the main constituents of body fat in humans and other ...

s, commonly known as fats, to hydrolyze them and make them soluble.

Bauxite Bauxite is a sedimentary rock with a relatively high aluminium content. It is the world's main source of aluminium and gallium. Bauxite consists mostly of the aluminium minerals gibbsite (Al(OH)3), boehmite (γ-AlO(OH)) and diaspore (α-AlO ...

, a basic hydroxide of

aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...

, is the principal ore from which the metal is manufactured. Similarly,

goethite Goethite (, ) is a mineral of the diaspore group, consisting of iron(III) oxide-hydroxide, specifically the "α" polymorph. It is found in soil and other low-temperature environments such as sediment. Goethite has been well known since ancient t ...

(α-FeO(OH)) and

lepidocrocite Lepidocrocite (γ-FeO(OH)), also called esmeraldite or hydrohematite, is an iron oxide-hydroxide mineral. Lepidocrocite has an orthorhombic crystal structure, a hardness of 5, specific gravity of 4, a submetallic luster and a yellow-brown stre ...

(γ-FeO(OH)), basic hydroxides of

iron Iron () is a chemical element with Symbol (chemistry), symbol Fe (from la, Wikt:ferrum, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 element, group 8 of the periodic table. It is, Abundanc ...

, are among the principal ores used for the manufacture of metallic iron.

Inorganic hydroxides

Alkali metals

Aside from NaOH and KOH, which enjoy very large scale applications, the hydroxides of the other alkali metals also are useful.

Lithium hydroxide Lithium hydroxide is an inorganic compound with the formula LiOH. It can exist as anhydrous or hydrated, and both forms are white hygroscopic solids. They are soluble in water and slightly soluble in ethanol. Both are available commercially. While ...

is a strong base, with a p''K''_b of −0.36. Lithium hydroxide is used in

breathing gas A breathing gas is a mixture of gaseous chemical elements and compounds used for respiration. Air is the most common and only natural breathing gas, but other mixtures of gases, or pure oxygen, are also used in breathing equipment and enclosed ...

purification systems for

spacecraft A spacecraft is a vehicle or machine designed to fly in outer space. A type of artificial satellite, spacecraft are used for a variety of purposes, including communications, Earth observation, meteorology, navigation, space colonization, p ...

, submarines, and

rebreather A rebreather is a breathing apparatus that absorbs the carbon dioxide of a user's breathing, exhaled breath to permit the rebreathing (recycling) of the substantially unused oxygen content, and unused inert content when present, of each breath. ...

s to remove

from exhaled gas. :2 LiOH + CO₂ → Li₂CO₃ + H₂O The hydroxide of lithium is preferred to that of sodium because of its lower mass. Sodium hydroxide,

potassium hydroxide Potassium hydroxide is an inorganic compound with the formula K OH, and is commonly called caustic potash. Along with sodium hydroxide (NaOH), KOH is a prototypical strong base. It has many industrial and niche applications, most of which exp ...

, and the hydroxides of the other alkali metals are also strong bases.

Alkaline earth metals

Beryllium hydroxide Beryllium hydroxide, Be(OH)2, is an amphoteric hydroxide, dissolving in both acids and alkalis. Industrially, it is produced as a by-product in the extraction of beryllium metal from the ores beryl and bertrandite. The natural pure beryllium hydro ...

Be(OH)₂ is

amphoteric In chemistry, an amphoteric compound () is a molecule or ion that can react both as an acid and as a base. What exactly this can mean depends on which definitions of acids and bases are being used. One type of amphoteric species are amphipro ...

.Thomas R. Dulsk
A manual for the chemical analysis of metals
ASTM International, 1996, p. 100 The hydroxide itself is

insoluble In chemistry, solubility is the ability of a substance, the solute, to form a solution with another substance, the solvent. Insolubility is the opposite property, the inability of the solute to form such a solution. The extent of the solubil ...

in water, with a

solubility product Solubility equilibrium is a type of dynamic equilibrium that exists when a chemical compound in the solid state is in chemical equilibrium with a solution of that compound. The solid may dissolve unchanged, with dissociation, or with chemical reacti ...

log ''K''*_sp of −11.7. Addition of acid gives soluble

products, including the trimeric ion e₃(OH)₃(H₂O)₆sup>3+, which has OH groups bridging between pairs of beryllium ions making a 6-membered ring. At very low pH the

aqua ion A metal ion in aqueous solution or aqua ion is a cation, dissolved in water, of chemical formula (H2O)nsup>z+. The solvation number, ''n'', determined by a variety of experimental methods is 4 for Li+ and Be2+ and 6 for most elements in periods ...

e(H₂O)₄sup>2+ is formed. Addition of hydroxide to Be(OH)₂ gives the soluble tetrahydroxoberyllate/tetrahydroxido

beryllate Beryllium compounds {{Short pages monitor