Emission inventory
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An emission inventory (or emissions inventory) is an accounting of the amount of
pollutants A pollutant or novel entity is a substance or energy introduced into the environment that has undesired effects, or adversely affects the usefulness of a resource. These can be both naturally forming (i.e. minerals or extracted compounds like o ...
discharged into the atmosphere. An emission inventory usually contains the total emissions for one or more specific
greenhouse gases A greenhouse gas (GHG or GhG) is a gas that absorbs and emits radiant energy within the thermal infrared range, causing the greenhouse effect. The primary greenhouse gases in Earth's atmosphere are water vapor (), carbon dioxide (), methane ...
or air pollutants, originating from all source categories in a certain geographical area and within a specified time span, usually a specific year. An emission inventory is generally characterized by the following aspects: *Why: The types of activities that cause emissions *What: The chemical or physical identity of the
pollutants A pollutant or novel entity is a substance or energy introduced into the environment that has undesired effects, or adversely affects the usefulness of a resource. These can be both naturally forming (i.e. minerals or extracted compounds like o ...
included, and the quantity thereof *Where: The geographic area covered *When: The time period over which emissions are estimated *How: The methodology to use Emission inventories are compiled for both scientific applications and for use in policy processes.


Use

Emissions and releases to the environment are the starting point of every environmental pollution problem. Information on emissions therefore is an absolute requirement in understanding environmental problems and in monitoring progress towards solving these. Emission inventories provide this type of information. Emission inventories are developed for a variety of purposes: *Policy use: by policy makers to **track progress towards emission reduction targets **develop strategies and policies or *Scientific use: Inventories of natural and anthropogenic emissions are used by scientists as inputs to air quality models


Policy use

Two more or less independent types of emission reporting schemes have been developed: *Annual reporting of national total emissions of greenhouse gases and air pollutants in response to obligations under international conventions and protocols; this type of emissions reporting aims at monitoring the progress towards agreed national emission reduction targets; *Regular emission reporting by individual industrial facilities in response to legal obligations; this type of emission reporting is developed to support public participation in decision-making. Examples of the first are the annual emission inventories as reported to the
United Nations Framework Convention on Climate Change The United Nations Framework Convention on Climate Change (UNFCCC) established an international environmental treaty to combat "dangerous human interference with the climate system", in part by stabilizing greenhouse gas concentrations in ...
(UNFCCC) for greenhouse gases and to the UNECE
Convention on Long-Range Transboundary Air Pollution The Convention on Long-Range Transboundary Air Pollution, often abbreviated as Air Convention or CLRTAP, is intended to protect the human environment against air pollution and to gradually reduce and prevent air pollution, including long-range ...
(LRTAP) for air pollutants. In the United States, a national emissions inventory is published annually by the
United States Environmental Protection Agency The Environmental Protection Agency (EPA) is an independent executive agency of the United States federal government tasked with environmental protection matters. President Richard Nixon proposed the establishment of EPA on July 9, 1970; it ...
. This inventory is called the "National Emissions Inventory", and can be found here

Examples of the second are the so-called Pollutant Release and Transfer Registers. Policy users typically are interested in annual total emission only.


Scientific use

Air quality models need input to describe all air pollution sources in the study area. Air emission inventories provide this type of information. Depending on the spatial and temporal resolution of the models, the spatial and temporal resolution of the inventories frequently has to be increased beyond what is available from national emission inventories as reported to the international conventions and protocols.


Compilation

For each of the pollutants in the inventory emissions are typically estimated by multiplying the intensity of each relevant activity ('activity rate') in the geographical area and time span with a pollutant dependent proportionality constant (' emission factor').


Why: the source categories

To compile an emission inventory, all sources of the pollutants must be identified and quantified. Frequently used source categorisations are *those defined by the Intergovernmental Panel on Climate Change (IPCC) in th
Revised 1996 IPCC Guidelines for National Greenhouse Gas Inventories
ttp://www.ipcc-nggip.iges.or.jp/public/gpglulucf/gpglulucf.html IPCC Good practice guidance for land use, land use change and forestryand more recently th
2006 IPCC Guidelines for National Greenhouse Gas Inventories
*those defined in the UNECE
Convention on Long-Range Transboundary Air Pollution The Convention on Long-Range Transboundary Air Pollution, often abbreviated as Air Convention or CLRTAP, is intended to protect the human environment against air pollution and to gradually reduce and prevent air pollution, including long-range ...
(LRTAP); recently the LRTAP Convention adopted a source categorisation that is largely consistent with those of IPCC, to replace the more technology oriented Standardized Nomenclature for Air Pollutants (SNAP) used until 2005. Both source categorisations make a clear distinction between sources related to the combustion of (fossil) fuels and those that are not caused by combustion. In most cases the specific fuel combusted in the former is added to the source definition. Source categories include: # Energy ## Fuel combustion ### Stationary combustion #### Industrial combustion #### Residential heating ### Mobile combustion (transport) ## Fugitive emissions from (fossil) fuel use # Industrial Processes # Solvent and other product use # Agriculture # LULUCF (Land Use, Land Use Change and Forestry) # Waste Many researchers and research projects use their own source classifications, sometimes based on either the IPCC or the SNAP source categories, but in most cases the source categories listed above will be included.


What: the pollutants

Emission inventories have been developed and still are being developed for two major groups of pollutants: *
Greenhouse gases A greenhouse gas (GHG or GhG) is a gas that absorbs and emits radiant energy within the thermal infrared range, causing the greenhouse effect. The primary greenhouse gases in Earth's atmosphere are water vapor (), carbon dioxide (), methane ...
: **
Carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is trans ...
(CO2), **
Methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Ea ...
(CH4), **
Nitrous oxide Nitrous oxide (dinitrogen oxide or dinitrogen monoxide), commonly known as laughing gas, nitrous, or nos, is a chemical compound, an oxide of nitrogen with the formula . At room temperature, it is a colourless non-flammable gas, and has ...
(N2O) and **A number of fluorinated gaseous compounds (HFCs, PFCs, SF6) **Other greenhouse gases, not included in the United Nations Framework Convention on Climate Change (
UNFCCC The United Nations Framework Convention on Climate Change (UNFCCC) established an international environmental treaty to combat "dangerous human interference with the climate system", in part by stabilizing greenhouse gas concentrations in th ...
) * Air pollutants: ** Acidifying pollutants: sulphur dioxide (SO2),
nitrogen oxides Nitrogen oxide may refer to a binary compound of oxygen and nitrogen, or a mixture of such compounds: Charge-neutral *Nitric oxide (NO), nitrogen(II) oxide, or nitrogen monoxide *Nitrogen dioxide (), nitrogen(IV) oxide * Nitrogen trioxide (), or ...
(NOx, a combination of
nitrogen monoxide Nitric oxide (nitrogen oxide or nitrogen monoxide) is a colorless gas with the formula . It is one of the principal oxides of nitrogen. Nitric oxide is a free radical: it has an unpaired electron, which is sometimes denoted by a dot in its c ...
, NO and
nitrogen dioxide Nitrogen dioxide is a chemical compound with the formula . It is one of several nitrogen oxides. is an intermediate in the industrial synthesis of nitric acid, millions of tons of which are produced each year for use primarily in the productio ...
, NO2) and
ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous wa ...
(NH3), ** Photochemical smog precursors: again
nitrogen oxides Nitrogen oxide may refer to a binary compound of oxygen and nitrogen, or a mixture of such compounds: Charge-neutral *Nitric oxide (NO), nitrogen(II) oxide, or nitrogen monoxide *Nitrogen dioxide (), nitrogen(IV) oxide * Nitrogen trioxide (), or ...
and
non-methane volatile organic compound Non-methane volatile organic compounds (NMVOCs) are a set of organic compounds that are typically photochemically reactive in the atmosphere—marked by the exclusion of methane. NMVOCs include a large variety of chemically different compounds, suc ...
s (NMVOCs) ** Particulates and particulate precursors **Toxic pollutants like heavy metals and
persistent organic pollutants Persistent organic pollutants (POPs), sometimes known as "forever chemicals", are organic compounds that are resistant to environmental degradation through chemical, biological, and photolytic processes. They are toxic chemicals that adversel ...
**
Carbon monoxide Carbon monoxide (chemical formula CO) is a colorless, poisonous, odorless, tasteless, flammable gas that is slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simple ...
(CO)


Where: geographical resolution

Typically national inventories provide data summed at the national territory only. In some cases additional information on major industrial stacks ('point sources') is available. Stacks are also called release points, because not all emissions come from stacks. Other industrial sources include fugitive emissions, which cannot be attributed to any single release point. Some inventories are compiled from sub-national entities such as states and counties (in the U.S.), which can provide additional spatial resolution. In scientific applications, where higher resolutions are needed, geographical information such as population densities, land use or other data can provide tools to disaggregate the national level emissions to the required resolution, matching the geographical resolution of the model.


When: temporal resolution

Similarly, national emission inventories provide total emissions in a specific year, based on national statistics. In some model applications higher temporal resolutions are needed, for instance when modelling air quality problems related to road transport. In such cases data on time dependent traffic intensities (rush hours, weekends and working days, summer and winter driving patterns, etc.) can be used to establish the required higher temporal resolution. Inventories compiled from Continuous Emissions Monitors (CEMs) can provide hourly emissions data.


How: methodology to compile an emission inventory

The European Environment Agency updated in 2007 the third edition of the inventory guidebook. The guidebook is prepared by the UNECE/EME
Task Force on Emission Inventories and Projections
and provides a detailed guide to the atmospheric emissions inventory methodology. Especially for Road Transport the European Environment Agency finances COPERT 4, a software program to calculate emissions which will be included in official annual national inventories.


Quality

The quality of an emission inventory depends on its use. In policy applications, the inventory should comply with all what has been decided under the relevant convention. Both the UNFCCC and LRTAP conventions require an inventory to follow the quality criteria below (seeGuidelines for the preparation of national communications by Parties included in Annex I to the Convention, Part I: UNFCCC reporting guidelines on annual inventories (following incorporation of the provisions of decision 13/CP.9)
/ref>): A well constructed inventory should include enough documentation and other data to allow readers and users to understand the underlying assumptions and to assess its usability in an intended application.


See also

* Emission factor *
Emissions & Generation Resource Integrated Database The Emissions & Generation Resource Integrated Database (eGRID) is a comprehensive source of data on the environmental characteristics of almost all electric power generated in the United States. eGRID is issued by the U.S. Environmental Protecti ...
*
Greenhouse gas inventory Greenhouse gas inventories are emission inventories of greenhouse gas emissions that are developed for a variety of reasons. Scientists use inventories of natural and anthropogenic (human-caused) emissions as tools when developing atmospheric m ...


Notes


External Links


National inventories of GhG emitted in 2019 (received by the UNFCCC in 2021)


Sources and further reading


United Nations Framework Convention on Climate ChangeIntergovernmental Panel on Climate Change
* ttps://web.archive.org/web/20120915230825/http://www.epa.gov/climatechange/ghgemissions/usinventoryreport.html U.S. Environmental Protection Agency: National Greenhouse Gas Emissions Databr>U.S. Environmental Protection Agency: Toxics Release InventoryEuropean Environment Agency EMEP/CORINAIR Emission Inventory Guidebook 2009U.S. Toxic Air Emissions MapCOPERT 4 - Computer Programme to Calculate Emissions from Road TransportMethodology for the calculation of exhaust emissions - Road Transport
{{Authority control Air pollution emissions Greenhouse gas inventories