Electric discharge in gases
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Electric discharge in gases occurs when electric current flows through a
gas Gas is one of the four fundamental states of matter (the others being solid, liquid, and plasma). A pure gas may be made up of individual atoms (e.g. a noble gas like neon), elemental molecules made from one type of atom (e.g. oxygen), or ...
eous medium due to
ionization Ionization, or Ionisation is the process by which an atom or a molecule acquires a negative or positive charge by gaining or losing electrons, often in conjunction with other chemical changes. The resulting electrically charged atom or molecul ...
of the gas. Depending on several factors, the discharge may radiate visible light. The properties of electric discharges in gases are studied in connection with design of lighting sources and in the design of high voltage electrical equipment.


Discharge types

In
cold cathode A cold cathode is a cathode that is not electrically heated by a filament.A negatively charged electrode emits electrons or is the positively charged terminal. For more, see field emission. A cathode may be considered "cold" if it emits more el ...
tubes, the electric discharge in gas has three regions, with distinct
current–voltage characteristic A current–voltage characteristic or I–V curve (current–voltage curve) is a relationship, typically represented as a chart or graph, between the electric current through a circuit, device, or material, and the corresponding voltage, or ...
s:Reference Data for Engineers: Radio, Electronics, Computers and Communications
By Wendy Middleton, Mac E. Van Valkenburg, p. 16-42, Newnes, 2002
*I:
Townsend discharge The Townsend discharge or Townsend avalanche is a gas ionisation process where free electrons are accelerated by an electric field, collide with gas molecules, and consequently free additional electrons. Those electrons are in turn accelerated an ...
, below the
breakdown voltage The breakdown voltage of an insulator is the minimum voltage that causes a portion of an insulator to experience electrical breakdown and become electrically conductive. For diodes, the breakdown voltage is the minimum reverse voltage that mak ...
. At low voltages, the only current is that due to the generation of charge carriers in the gas by cosmic rays or other sources of ionizing radiation. As the applied voltage is increased, the free electrons carrying the current gain enough energy to cause further ionization, causing an electron avalanche. In this regime, the current increases from femtoamperes to microamperes, i.e. by nine orders of magnitude, for very little further increase in voltage. The voltage-current characteristics begins tapering off near the breakdown voltage and the glow becomes visible. *II:
glow discharge A glow discharge is a plasma formed by the passage of electric current through a gas. It is often created by applying a voltage between two electrodes in a glass tube containing a low-pressure gas. When the voltage exceeds a value called the st ...
, which occurs once the breakdown voltage is reached. The voltage across the electrodes suddenly drops and the current increases to milliampere range. At lower currents, the voltage across the tube is almost current-independent; this is used in glow discharge
voltage-regulator tube A voltage-regulator tube (VR tube) is an electronic component used as a shunt regulator to hold a voltage constant at a pre-determined level. Physically, these devices resemble vacuum tubes, but there are two main differences: * Their glass env ...
s. At lower currents, the area of the electrodes covered by the glow discharge is proportional to the current. At higher currents the normal glow turns into abnormal glow, the voltage across the tube gradually increases, and the glow discharge covers more and more of the surface of the electrodes. Low-power switching (glow-discharge thyratrons), voltage stabilization, and lighting applications (e.g.
Nixie tube A Nixie tube ( ), or cold cathode display, is an electronic device used for displaying numerals or other information using glow discharge. The glass tube contains a wire-mesh anode and multiple cathodes, shaped like numerals or other symbo ...
s, decatrons,
neon lamp A neon lamp (also neon glow lamp) is a miniature gas discharge lamp. The lamp typically consists of a small glass capsule that contains a mixture of neon and other gases at a low pressure and two electrodes (an anode and a cathode). When suff ...
s) operate in this region. *III:
arc discharge An electric arc, or arc discharge, is an electrical breakdown of a gas that produces a prolonged electrical discharge. The current through a normally nonconductive medium such as air produces a plasma; the plasma may produce visible light. An ...
, which occurs in the ampere range of the current; the voltage across the tube drops with increasing current. High-current switching tubes, e.g.
triggered spark gap A spark gap consists of an arrangement of two conducting electrodes separated by a gap usually filled with a gas such as air, designed to allow an electric spark to pass between the conductors. When the potential difference between the conduct ...
,
ignitron An ignitron is a type of gas-filled tube used as a controlled rectifier and dating from the 1930s. Invented by Joseph Slepian while employed by Westinghouse, Westinghouse was the original manufacturer and owned trademark rights to the name "Ignit ...
,
thyratron A thyratron is a type of gas-filled tube used as a high-power electrical switch and controlled rectifier. Thyratrons can handle much greater currents than similar hard-vacuum tubes. Electron multiplication occurs when the gas becomes ionized, p ...
and
krytron The krytron is a cold-cathode gas-filled tube intended for use as a very high-speed switch, somewhat similar to the thyratron. It consists of a sealed glass tube with four electrodes. A small triggering pulse on the grid electrode switches the ...
(and its
vacuum tube A vacuum tube, electron tube, valve (British usage), or tube (North America), is a device that controls electric current flow in a high vacuum between electrodes to which an electric potential difference has been applied. The type known as ...
derivate,
sprytron The krytron is a cold-cathode gas-filled tube intended for use as a very high-speed switch, somewhat similar to the thyratron. It consists of a sealed glass tube with four electrodes. A small triggering pulse on the control grid, grid electrode s ...
, using vacuum arc), high-power
mercury-arc valve A mercury-arc valve or mercury-vapor rectifier or (UK) mercury-arc rectifier is a type of electrical rectifier used for converting high-voltage or high-current alternating current (AC) into direct current (DC). It is a type of cold cathode gas-fil ...
s and high-power light sources, e.g.
mercury-vapor lamp A mercury-vapor lamp is a gas-discharge lamp that uses an electric arc through vaporized mercury to produce light. The arc discharge is generally confined to a small fused quartz arc tube mounted within a larger soda lime or borosilicate gl ...
s and
metal halide lamp A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typicall ...
s, operate in this range. Glow discharge is facilitated by electrons striking the gas atoms and ionizing them. For formation of glow discharge, the
mean free path In physics, mean free path is the average distance over which a moving particle (such as an atom, a molecule, or a photon) travels before substantially changing its direction or energy (or, in a specific context, other properties), typically as a ...
of the electrons has to be reasonably long but shorter than the distance between the electrodes; glow discharges therefore do not readily occur at both too low and too high gas pressures. The
breakdown Breakdown may refer to: Breaking down *Breakdown (vehicle), failure of a motor vehicle in such a way that it cannot be operated *Chemical decomposition, also called chemical breakdown, the breakdown of a substance into simpler components *Decompo ...
voltage for the glow discharge depends nonlinearly on the product of gas pressure and electrode distance according to
Paschen's law Paschen's law is an equation that gives the breakdown voltage, that is, the voltage necessary to start a discharge or electric arc, between two electrodes in a gas as a function of pressure and gap length. It is named after Friedrich Paschen who ...
. For a certain pressure × distance value, there is a lowest breakdown voltage. The increase of strike voltage for shorter electrode distances is related to too long mean free path of the electrons in comparison with the electrode distance. A small amount of a radioactive element may be added into the tube, either as a separate piece of material (e.g.
nickel-63 Naturally occurring nickel (28Ni) is composed of five stable isotopes; , , , and , with being the most abundant (68.077% natural abundance). 26 radioisotopes have been characterised with the most stable being with a half-life of 76,000 years, ...
in
krytron The krytron is a cold-cathode gas-filled tube intended for use as a very high-speed switch, somewhat similar to the thyratron. It consists of a sealed glass tube with four electrodes. A small triggering pulse on the grid electrode switches the ...
s) or as addition to the alloy of the electrodes (e.g.
thorium Thorium is a weakly radioactive metallic chemical element with the symbol Th and atomic number 90. Thorium is silvery and tarnishes black when it is exposed to air, forming thorium dioxide; it is moderately soft and malleable and has a high ...
), to preionize the gas and increase the reliability of electrical breakdown and glow or arc discharge ignition. A gaseous radioactive isotope, e.g.
krypton-85 Krypton-85 (85Kr) is a radioisotope of krypton. Krypton-85 has a half-life of 10.756 years and a maximum decay energy of 687 keV. It decays into stable rubidium-85. Its most common decay (99.57%) is by beta particle emission with maximum energ ...
, can also be used. Ignition electrodes and keepalive discharge electrodes can also be employed.Handbook of optoelectronics, Volume 1
by John Dakin, Robert G. W. Brown, p. 52, CRC Press, 2006
The E/N ratio between the electric field E and the concentration of neutral particles N is often used, because the mean energy of electrons (and therefore many other properties of discharge) is a function of E/N. Increasing the electric intensity E by some factor q has the same consequences as lowering gas density N by factor q. Its
SI unit The International System of Units, known by the international abbreviation SI in all languages and sometimes pleonastically as the SI system, is the modern form of the metric system and the world's most widely used system of measurement. ...
is V·cm2, but the Townsend unit (Td) is frequently used.


Application in analog computation

The use of a glow discharge for solution of certain mapping problems was described in 2002. According to a Nature news article describing the work, researchers at Imperial College London demonstrated how they built a mini-map that gives tourists luminous route indicators. To make the one-inch London chip, the team etched a plan of the city centre on a glass slide. Fitting a flat lid over the top turned the streets into hollow, connected tubes. They filled these with helium gas, and inserted electrodes at key tourist hubs. When a voltage is applied between two points, electricity naturally runs through the streets along the shortest route from A to B – and the gas glows like a tiny glowing strip light. The approach itself provides a novel visible analog computing approach for solving a wide class of maze searching problems based on the properties of lighting up of a glow discharge in a microfluidic chip.


References

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