Diffuse sky radiation
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Diffuse sky radiation is
solar radiation Solar irradiance is the power per unit area (surface power density) received from the Sun in the form of electromagnetic radiation in the wavelength range of the measuring instrument. Solar irradiance is measured in watts per square metre ( ...
reaching the
Earth Earth is the third planet from the Sun and the only astronomical object known to harbor life. While large volumes of water can be found throughout the Solar System, only Earth sustains liquid surface water. About 71% of Earth's surfa ...
's surface after having been scattered from the direct solar beam by
molecule A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and bioche ...
s or
particulates Particulates – also known as atmospheric aerosol particles, atmospheric particulate matter, particulate matter (PM) or suspended particulate matter (SPM) – are microscopic particles of solid or liquid matter suspended in the air. The t ...
in the atmosphere. It is also called sky radiation, the determinative process for changing the colors of the sky. Approximately 23% of direct incident radiation of total sunlight is removed from the direct solar beam by scattering into the atmosphere; of this amount (of incident radiation) about two-thirds ultimately reaches the earth as photon diffused skylight radiation. The dominant radiative scattering processes in the atmosphere are
Rayleigh scattering Rayleigh scattering ( ), named after the 19th-century British physicist Lord Rayleigh (John William Strutt), is the predominantly elastic scattering of light or other electromagnetic radiation by particles much smaller than the wavelength of th ...
and
Mie scattering The Mie solution to Maxwell's equations (also known as the Lorenz–Mie solution, the Lorenz–Mie–Debye solution or Mie scattering) describes the scattering of an electromagnetic plane wave by a homogeneous sphere. The solution takes the ...
; they are elastic, meaning that a photon of light can be deviated from its path without being absorbed and without changing wavelength. Under an overcast sky, there is no direct sunlight, and all light results from diffused skylight radiation. Proceeding from analyses of the aftermath of the eruption of the Philippines volcano Mount Pinatubo (in June 1991) and other studies: Diffused skylight, owing to its intrinsic structure and behavior, can illuminate under-canopy leaves, permitting more efficient total whole-plant photosynthesis than would otherwise be the case; this in stark contrast to the effect of totally clear skies with direct sunlight that casts shadows onto understory leaves and thereby limits plant photosynthesis to the top canopy layer, (see below).


Color

Earth's atmosphere The atmosphere of Earth is the layer of gases, known collectively as air, retained by Earth's gravity that surrounds the planet and forms its planetary atmosphere. The atmosphere of Earth protects life on Earth by creating pressure allowing fo ...
scatters short-
wavelength In physics, the wavelength is the spatial period of a periodic wave—the distance over which the wave's shape repeats. It is the distance between consecutive corresponding points of the same phase on the wave, such as two adjacent crests, t ...
light more efficiently than that of longer wavelengths. Because its wavelengths are shorter, blue light is more strongly scattered than the longer-wavelength lights, red or green. Hence, the result that when looking at the sky away from the direct incident sunlight, the human eye perceives the sky to be blue. The color perceived is similar to that presented by a monochromatic blue (at wavelength ) mixed with white light, that is, an unsaturated blue light. The explanation of blue color by Rayleigh in 1871 is a famous example of applying
dimensional analysis In engineering and science, dimensional analysis is the analysis of the relationships between different physical quantities by identifying their base quantities (such as length, mass, time, and electric current) and units of measure (such as mi ...
to solving problems in physics; (see top figure). Scattering and absorption are major causes of the
attenuation In physics, attenuation (in some contexts, extinction) is the gradual loss of flux intensity through a medium. For instance, dark glasses attenuate sunlight, lead attenuates X-rays, and water and air attenuate both light and sound at variabl ...
of sunlight radiation by the atmosphere. Scattering varies as a function of the ratio of particle diameters (of
particulates Particulates – also known as atmospheric aerosol particles, atmospheric particulate matter, particulate matter (PM) or suspended particulate matter (SPM) – are microscopic particles of solid or liquid matter suspended in the air. The t ...
in the atmosphere) to the wavelength of the incident radiation. When this ratio is less than about one-tenth,
Rayleigh scattering Rayleigh scattering ( ), named after the 19th-century British physicist Lord Rayleigh (John William Strutt), is the predominantly elastic scattering of light or other electromagnetic radiation by particles much smaller than the wavelength of th ...
occurs. (In this case, the scattering coefficient varies inversely with the fourth power of the wavelength. At larger ratios scattering varies in a more complex fashion, as described for spherical particles by the Mie theory.) The laws of
geometric optics Geometry (; ) is, with arithmetic, one of the oldest branches of mathematics. It is concerned with properties of space such as the distance, shape, size, and relative position of figures. A mathematician who works in the field of geometry is ca ...
begin to apply at higher ratios. Daily at any global venue experiencing
sunrise Sunrise (or sunup) is the moment when the upper rim of the Sun appears on the horizon in the morning. The term can also refer to the entire process of the solar disk crossing the horizon and its accompanying atmospheric effects. Terminology A ...
or sunset, most of the solar beam of visible sunlight arrives nearly tangentially to Earth's surface. Here, the
path A path is a route for physical travel – see Trail. Path or PATH may also refer to: Physical paths of different types * Bicycle path * Bridle path, used by people on horseback * Course (navigation), the intended path of a vehicle * Desire p ...
of sunlight through the atmosphere is elongated such that much of the blue or green light is scattered away from the line of perceivable visible light. This phenomenon leaves the Sun's rays, and the clouds they illuminate, abundantly orange-to-red in colors, which one sees when looking at a sunset or sunrise. For the example of the Sun at
zenith The zenith (, ) is an imaginary point directly "above" a particular location, on the celestial sphere. "Above" means in the vertical direction ( plumb line) opposite to the gravity direction at that location ( nadir). The zenith is the "high ...
, in broad daylight, the sky is blue due to Rayleigh scattering, which also involves the diatomic gases and . Near sunset and especially during
twilight Twilight is light produced by sunlight scattering in the upper atmosphere, when the Sun is below the horizon, which illuminates the lower atmosphere and the Earth's surface. The word twilight can also refer to the periods of time when this i ...
, absorption by
ozone Ozone (), or trioxygen, is an inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , breaking down in the lo ...
() significantly contributes to maintaining blue color in the evening sky.


Under an overcast sky

There is essentially no direct sunlight under an
overcast Overcast or overcast weather, as defined by the World Meteorological Organization, is the meteorological condition of clouds obscuring at least 95% of the sky. However, the total cloud cover must not be entirely due to obscuring phenomena near t ...
sky, so all light is then diffuse sky radiation. The flux of light is not very wavelength-dependent because the cloud droplets are larger than the light's wavelength and scatter all colors approximately equally. The light passes through the
translucent In the field of optics, transparency (also called pellucidity or diaphaneity) is the physical property of allowing light to pass through the material without appreciable scattering of light. On a macroscopic scale (one in which the dimensions ...
clouds in a manner similar to
frosted glass Frosted glass is produced by the sandblasting or acid etching of clear sheet glass. This creates a pitted surface on one side of the glass pane and has the effect of rendering the glass translucent by scattering the light which passes through, ...
. The intensity ranges (roughly) from of direct sunlight for relatively thin clouds down to of direct sunlight under the extreme of thickest storm clouds.


As a part of total radiation

One of the equations for total solar radiation is: : H_t= H_b R_b + H_d R_d + (H_b+H_d) R_r where ''Hb'' is the beam radiation irradiance, ''Rb'' is the tilt factor for beam radiation, ''Hd'' is the diffuse radiation irradiance, ''Rd'' is the tilt factor for diffuse radiation and ''Rr'' is the tilt factor for reflected radiation. ''Rb'' is given by: : R_b=\frac where ''δ'' is the solar declination, ''Φ'' is the latitude, ''β'' is an angle from the horizontal and ''h'' is the solar
hour angle In astronomy and celestial navigation, the hour angle is the angle between two planes: one containing Earth's axis and the zenith (the '' meridian plane''), and the other containing Earth's axis and a given point of interest (the ''hour circle ...
. ''Rd'' is given by: : R_d=\frac and ''Rr'' by: : R_r=\frac where ''ρ'' is the
reflectivity The reflectance of the surface of a material is its effectiveness in Reflection (physics), reflecting radiant energy. It is the fraction of incident electromagnetic power that is reflected at the boundary. Reflectance is a component of the respon ...
of the surface.


Agriculture and the eruption of Mt. Pinatubo

The eruption of the
Philippines The Philippines (; fil, Pilipinas, links=no), officially the Republic of the Philippines ( fil, Republika ng Pilipinas, links=no), * bik, Republika kan Filipinas * ceb, Republika sa Pilipinas * cbk, República de Filipinas * hil, Republ ...
volcano A volcano is a rupture in the Crust (geology), crust of a Planet#Planetary-mass objects, planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and volcanic gas, gases to escape from a magma chamber below the surface. On Ear ...
-
Mount Pinatubo Mount Pinatubo is an active stratovolcano in the Zambales Mountains, located on the tripoint boundary of the Philippine provinces of Zambales, Tarlac and Pampanga, all in Central Luzon on the northern island of Luzon. Its eruptive histor ...
in June 1991 ejected roughly of magma and "17,000,000
metric ton The tonne ( or ; symbol: t) is a unit of mass equal to 1000  kilograms. It is a non-SI unit accepted for use with SI. It is also referred to as a metric ton to distinguish it from the non-metric units of the short ton ( United State ...
s"(17 teragrams) of sulfur dioxide SO2 into the air, introducing ten times as much total SO2 as the 1991 Kuwaiti fires, mostly during the explosive Plinian/Ultra-Plinian event of June 15, 1991, creating a global stratospheric SO2 haze layer which persisted for years. This resulted in the global average temperature dropping by about . Since
volcanic ash Volcanic ash consists of fragments of rock, mineral crystals, and volcanic glass, created during volcanic eruptions and measuring less than 2 mm (0.079 inches) in diameter. The term volcanic ash is also often loosely used to refer ...
falls out of the atmosphere rapidly, the negative agricultural, effects of the eruption were largely immediate and localized to a relatively small area in close proximity to the eruption, caused by the resulting thick ash cover. Globally however, despite a several-month 5% drop in overall solar irradiation, and a reduction in direct sunlight by 30%, there was no negative impact on global agriculture.LARGE VOLCANIC ERUPTIONS HELP PLANTS ABSORB MORE CARBON DIOXIDE FROM THE ATMOSPHERE
/ref> Surprisingly, a 3-4 year increase in global
Agricultural productivity Agricultural productivity is measured as the ratio of agricultural outputs to inputs. While individual products are usually measured by weight, which is known as crop yield, varying products make measuring overall agricultural output difficu ...
and forestry growth was observed, excepting
boreal forest Taiga (; rus, тайга́, p=tɐjˈɡa; relates to Mongolic and Turkic languages), generally referred to in North America as a boreal forest or snow forest, is a biome characterized by coniferous forests consisting mostly of pines, spruc ...
regions.Evaluating aerosol direct radiative effects on global terrestrial ecosystem carbon dynamics from 2003 to 2010. Chen et al., ''Tellus B'' 2014; 66, 21808, Published by the international meteorological institute in Stockholm.
/ref> The means of discovery was that initially, a mysterious drop in the rate at which
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is trans ...
(CO2) was filling the atmosphere was observed, which is charted in what is known as the " Keeling Curve". This led numerous scientists to assume that the reduction was due to the lowering of Earth's temperature, and with that, a, slowdown in plant and soil
respiration Respiration may refer to: Biology * Cellular respiration, the process in which nutrients are converted into useful energy in a cell ** Anaerobic respiration, cellular respiration without oxygen ** Maintenance respiration, the amount of cellul ...
, indicating a deleterious impact on global agriculture from the volcanic haze layer. However upon investigation, the reduction in the rate at which carbon dioxide filled the atmosphere did not match up with the hypothesis that plant respiration rates had declined. Instead the advantageous anomaly was relatively firmly linked to an unprecedented increase in the growth/ net primary production, of global plant life, resulting in the increase of the
carbon sink A carbon sink is anything, natural or otherwise, that accumulates and stores some carbon-containing chemical compound for an indefinite period and thereby removes carbon dioxide () from the atmosphere. Globally, the two most important carbon si ...
effect of global photosynthesis. The mechanism by which the increase in plant growth was possible, was that the 30% reduction of direct sunlight can also be expressed as an increase or "enhancement" in the amount of
diffuse Diffusion is the net movement of anything (for example, atoms, ions, molecules, energy) generally from a region of higher concentration to a region of lower concentration. Diffusion is driven by a gradient in Gibbs free energy or chemical p ...
sunlight.


The diffused skylight effect

This diffused skylight, owing to its intrinsic nature, can illuminate under-
canopy Canopy may refer to: Plants * Canopy (biology), aboveground portion of plant community or crop (including forests) * Canopy (grape), aboveground portion of grapes Religion and ceremonies * Baldachin or canopy of state, typically placed over an ...
leaves permitting more efficient total whole-plant
photosynthesis Photosynthesis is a process used by plants and other organisms to convert light energy into chemical energy that, through cellular respiration, can later be released to fuel the organism's activities. Some of this chemical energy is stored i ...
than would otherwise be the case, and also increasing evaporative cooling, from vegetated surfaces. In stark contrast, for totally clear skies and the direct sunlight that results from it, shadows are cast onto
understorey In forestry and ecology, understory (American English), or understorey (Commonwealth English), also known as underbrush or undergrowth, includes plant life growing beneath the forest canopy without penetrating it to any great extent, but abo ...
leaves, limiting plant photosynthesis to the top canopy layer. This increase in global agriculture from the volcanic haze layer also naturally results as a product of other aerosols that are not emitted by volcanoes, such, "moderately thick smoke loading" pollution, as the same mechanism, the "aerosol direct radiative effect" is behind both.Direct observations of the effects of aerosol loading on net ecosystem CO2 exchanges over different landscapes. Niyogi et al. ''Geophysical Research Letters'' Volume 31, Issue 20, October 2004


See also

* Atmospheric diffraction * Aerial perspective *
Cyanometer A cyanometer (from ''cyan'' and '' -meter'') is an instrument for measuring " blueness", specifically the colour intensity of blue sky. It is attributed to Horace-Bénédict de Saussure and Alexander von Humboldt. It consists of squares of pa ...
* Daylight *Nighttime
airglow Airglow (also called nightglow) is a faint emission of light by a planetary atmosphere. In the case of Earth's atmosphere, this optical phenomenon causes the night sky never to be completely dark, even after the effects of starlight and diffu ...
*
Rayleigh scattering Rayleigh scattering ( ), named after the 19th-century British physicist Lord Rayleigh (John William Strutt), is the predominantly elastic scattering of light or other electromagnetic radiation by particles much smaller than the wavelength of th ...
* Rayleigh sky model * Sunshine duration * Sunset#Colors * Sunrise#Colors * Tyndall effect


References


Further reading

*


External links


Dr. C. V. Raman lecture: Why is the sky blue?Atmospheric Optics (.pdf), Dr. Craig Bohren
{{Authority control Sun Light Visibility Atmospheric optical phenomena