Cupola furnace
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A cupola or cupola furnace is a melting device used in
foundries A foundry is a factory that produces metal castings. Metals are cast into shapes by melting them into a liquid, pouring the metal into a mold, and removing the mold material after the metal has solidified as it cools. The most common metals pr ...
that can be used to melt
cast iron Cast iron is a class of iron– carbon alloys with a carbon content more than 2%. Its usefulness derives from its relatively low melting temperature. The alloy constituents affect its color when fractured: white cast iron has carbide impur ...
, Ni-resist iron and some bronzes. The cupola can be made almost any practical size. The size of a cupola is expressed in diameters and can range from . The overall shape is cylindrical and the equipment is arranged vertically, usually supported by four legs. The overall look is similar to a large
smokestack A chimney is an architectural ventilation structure made of masonry, clay or metal that isolates hot toxic exhaust gases or smoke produced by a boiler, stove, furnace, incinerator, or fireplace from human living areas. Chimneys are typ ...
. The bottom of the cylinder is fitted with doors which swing down and out to 'drop bottom'. The top where gases escape can be open or fitted with a cap to prevent rain from entering the cupola. To control emissions a cupola may be fitted with a cap that is designed to pull the gases into a device to cool the gases and remove particulate matter. The shell of the cupola, being usually made of steel, has
refractory brick In materials science, a refractory material or refractory is a material that is resistant to decomposition by heat, pressure, or chemical attack, and retains strength and form at high temperatures. Refractories are polycrystalline, polyphase, ...
and plastic
refractory In materials science, a refractory material or refractory is a material that is resistant to decomposition by heat, pressure, or chemical attack, and retains strength and form at high temperatures. Refractories are polycrystalline, polyphase, ...
patching material lining it. The bottom is lined in a similar manner but often a clay and sand mixture ("bod") may be used, as this lining is temporary. Finely divided coal ("sea coal") can be mixed with the clay lining so when heated the coal decomposes and the bod becomes slightly friable, easing the opening up of the tap holes. The bottom lining is compressed or 'rammed' against the bottom doors. Some cupolas are fitted with cooling jackets to keep the sides cool and with oxygen injection to make the coke fire burn hotter.


History

Cupola furnaces were built in China as early as the
Warring States period The Warring States period () was an era in ancient Chinese history characterized by warfare, as well as bureaucratic and military reforms and consolidation. It followed the Spring and Autumn period and concluded with the Qin wars of conquest ...
(403–221 BC), although Donald Wagner writes that some iron ore melted in the blast furnace may have been cast directly into molds. During the Han Dynasty (202 BC – 220 AD), most, if not all, iron smelted in the blast furnace was remelted in a cupola furnace; it was designed so that a
cold blast Cold blast, in ironmaking, refers to a metallurgical furnace where air is not preheated before being blown into the furnace. This represents the earliest stage in the development of ironmaking. Until the 1820s, the use of cold air was thought to b ...
injected at the bottom traveled through
tuyere A tuyere or tuyère (; ) is a tube, nozzle or pipe through which air is blown into a furnace or hearth.W. K. V. Gale, The iron and Steel industry: a dictionary of terms (David and Charles, Newton Abbot 1972), 216–217. Air or oxygen is in ...
pipes across the top where the charge (i.e. of charcoal and scrap or pig iron) was dumped, the air becoming a
hot blast Hot blast refers to the preheating of air blown into a blast furnace or other metallurgical process. As this considerably reduced the fuel consumed, hot blast was one of the most important technologies developed during the Industrial Revolution. ...
before reaching the bottom of the furnace where the iron was melted and then drained into appropriate molds for casting. A modern cupola furnace was made by French scientist and entomologist René-Antoine Ferchault de Réaumur around 1720.


Operation

To begin a production run, called a 'cupola campaign', the furnace is filled with layers of coke and ignited with torches. Some smaller cupolas may be ignited with wood to start the coke burning. When the coke is ignited, air is introduced to the coke bed through ports in the sides called
tuyeres A tuyere or tuyère (; ) is a tube, nozzle or pipe through which air is blown into a furnace or hearth.W. K. V. Gale, The iron and Steel industry: a dictionary of terms (David and Charles, Newton Abbot 1972), 216–217. Air or oxygen is inj ...
. Wood, charcoal, or biomass may also be used as fuel for the cupola's fire. Flammable gases also can be added to air and blown through the tuyere section of the furnace to add fuel to the fire. When the coke is very hot, solid pieces of metal are charged into the furnace through an opening in the top. The metal is alternated with additional layers of fresh coke.
Limestone Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms whe ...
is added to act as a flux. As the heat rises within the stack the metal is melted. It drips down through the coke bed to collect in a pool at the bottom, just above the bottom doors. During the melting process a
thermodynamic Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of the ...
reaction takes place between the fuel and the blast air. The
carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon mak ...
in the coke combines with the oxygen in the air to form
carbon monoxide Carbon monoxide (chemical formula CO) is a colorless, poisonous, odorless, tasteless, flammable gas that is slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simple ...
. The carbon monoxide further burns to form
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is trans ...
. Some of the carbon is picked up by the falling droplets of molten metal which raises the carbon content of the iron.
Silicon carbide Silicon carbide (SiC), also known as carborundum (), is a hard chemical compound containing silicon and carbon. A semiconductor, it occurs in nature as the extremely rare mineral moissanite, but has been mass-produced as a powder and crystal s ...
and
ferromanganese Ferromanganese is a ferroalloy with high manganese content (high-carbon ferromanganese can contain as much as 80% Mn by weight). It is made by heating a mixture of the oxides MnO2 and Fe2O3, with carbon (usually as coal and coke) in either a bla ...
briquettes may also be added to the charge materials. The silicon carbide dissociates and carbon and silicon enters into the molten metal. Likewise, the ferromanganese melts and is combined into the pool of liquid iron in the 'well' at the bottom of the cupola. Additions to the molten iron such as
ferromanganese Ferromanganese is a ferroalloy with high manganese content (high-carbon ferromanganese can contain as much as 80% Mn by weight). It is made by heating a mixture of the oxides MnO2 and Fe2O3, with carbon (usually as coal and coke) in either a bla ...
,
ferrosilicon Ferrosilicon is an alloy of iron and silicon with a typical silicon content by weight of 15–90%. It contains a high proportion of iron silicides. Production and reactions Ferrosilicon is produced by reduction of silica or sand with coke in t ...
,
silicon carbide Silicon carbide (SiC), also known as carborundum (), is a hard chemical compound containing silicon and carbon. A semiconductor, it occurs in nature as the extremely rare mineral moissanite, but has been mass-produced as a powder and crystal s ...
and other alloying agents are used to alter the molten iron to conform to the needs of the castings at hand. Pea-sized raw ore of metals such as iron, copper, lead, and even those containing precious metals can be melted in the cupola or blast furnace. Vannoccio Biringuccio describes how to separate metals and slag by pouring the melted ore contents from the furnace into a small pool then peeling off layers of slag or metal from the top as they cool into a solid. The operator of the cupola is known as the "cupola tender" or "furnace master". During the operation of a tapped cupola (cupolas may vary in this regard) the tender observes the amount of iron rising in the well of the cupola. When the metal level is sufficiently high, the cupola tender opens the "tap hole" to let the metal flow into a ladle or other container to hold the molten metal. When enough metal is drawn off the "tap hole" is plugged with a refractory plug made of clay. The cupola tender observes the furnace through the sight glass or peep sight in the tuyeres. Slag will rise to the top of the pool of iron being formed. A slag hole, located higher up on the cylinder of the furnace, and usually to the rear or side of the tap hole, is opened to let the slag flow out. The
viscosity The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the inte ...
is low (with proper fluxing) and the red hot molten slag will flow easily. Sometimes the slag which runs out the slag hole is collected in a small cup shaped tool, allowed to cool and harden. It is fractured and visually examined. With acid refractory lined cupolas a greenish colored slag means the fluxing is proper and adequate. In basic refractory lined cupolas the slag is brown. After the cupola has produced enough metal to supply the foundry with its needs, the bottom is opened, or 'dropped' and the remaining materials fall to the floor between the legs. This material is allowed to cool and subsequently removed. The cupola can be used over and over. A 'campaign' may last a few hours, a day, weeks or even months. When the operation is over, the blast is shut off and the prop under the bottom door is knocked down so that the bottom plates swing open. This enables the cupola remains to drop to the floor or into a bucket. They are then quenched and removed from underneath the cupola.


Quality control

During the production, samples may be taken from the metal and poured into small molds. A chill wedge is often poured to monitor the iron quality. These small, approx 18 mm (") wide × 38 mm (") tall triangular shaped pieces are allowed to cool until the metal has solidified. They are then extracted from the sand mold and quenched in water, wide end first. After cooling in this manner the wedges are fractured and the metal coloration is assessed. A typical fracture will have a whitish color towards the thin area of the wedge and grayish color towards the wide end. The width of the wedge at the point of demarcation between the white and gray areas is measured and compared to normal results for particular iron
tensile strength Ultimate tensile strength (UTS), often shortened to tensile strength (TS), ultimate strength, or F_\text within equations, is the maximum stress that a material can withstand while being stretched or pulled before breaking. In brittle materials t ...
s. This visual method serves as a control measurement.


Notes


References

{{Authority control Industrial furnaces Cast iron Chinese inventions French inventions Metalworking