Cornubian batholith
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The Cornubian batholith is a large mass of
granite Granite () is a coarse-grained ( phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies un ...
rock, formed about 280 million years ago, which lies beneath much of
Devon Devon ( , historically known as Devonshire , ) is a ceremonial and non-metropolitan county in South West England. The most populous settlement in Devon is the city of Plymouth, followed by Devon's county town, the city of Exeter. Devo ...
and
Cornwall Cornwall (; kw, Kernow ) is a Historic counties of England, historic county and Ceremonial counties of England, ceremonial county in South West England. It is recognised as one of the Celtic nations, and is the homeland of the Cornish people ...
, the south-western peninsula of
Great Britain Great Britain is an island in the North Atlantic Ocean off the northwest coast of continental Europe. With an area of , it is the largest of the British Isles, the largest European island and the ninth-largest island in the world. It ...
. The main exposed masses of granite are seen at
Dartmoor Dartmoor is an upland area in southern Devon, England. The moorland and surrounding land has been protected by National Park status since 1951. Dartmoor National Park covers . The granite which forms the uplands dates from the Carboniferous P ...
,
Bodmin Moor Bodmin Moor ( kw, Goon Brenn) is a granite moorland in north-eastern Cornwall, England. It is in size, and dates from the Carboniferous period of geological history. It includes Brown Willy, the highest point in Cornwall, and Rough Tor, a sl ...
,
St Austell St Austell (; kw, Sans Austel) is a town in Cornwall, England, south of Bodmin and west of the border with Devon. St Austell is one of the largest towns in Cornwall; at the 2011 census it had a population of 19,958. History St Austell ...
,
Carnmenellis Carnmenellis Hill (or just Carnmenellis) gives its name to the area of west Cornwall in England, between Redruth, Helston and Penryn. The hill itself is situated approximately three miles (5 km) south of Redruth.Ordnance Survey: Landran ...
,
Land's End Land's End ( kw, Penn an Wlas or ''Pedn an Wlas'') is a headland and tourist and holiday complex in western Cornwall, England, on the Penwith peninsula about west-south-west of Penzance at the western end of the A30 road. To the east of it is ...
and the
Isles of Scilly The Isles of Scilly (; kw, Syllan, ', or ) is an archipelago off the southwestern tip of Cornwall, England. One of the islands, St Agnes, is the most southerly point in Britain, being over further south than the most southerly point of th ...
. The intrusion is associated with significant quantities of
minerals In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed ...
particularly
cassiterite Cassiterite is a tin oxide mineral, SnO2. It is generally opaque, but it is translucent in thin crystals. Its luster and multiple crystal faces produce a desirable gem. Cassiterite was the chief tin ore throughout ancient history and remains ...
, an ore of tin which has been mined since about 2000 BC. Other minerals include
china clay Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedra ...
and ores of
copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pink ...
,
lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, ...
,
zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
and
tungsten Tungsten, or wolfram, is a chemical element with the symbol W and atomic number 74. Tungsten is a rare metal found naturally on Earth almost exclusively as compounds with other elements. It was identified as a new element in 1781 and first isol ...
. It takes its name from ''Cornubia'', the
Medieval Latin Medieval Latin was the form of Literary Latin used in Roman Catholic Western Europe during the Middle Ages. In this region it served as the primary written language, though local languages were also written to varying degrees. Latin functioned ...
name for Cornwall.


Extent and geometry

A
batholith A batholith () is a large mass of intrusive igneous rock (also called plutonic rock), larger than in area, that forms from cooled magma deep in Earth's crust. Batholiths are almost always made mostly of felsic or intermediate rock types, s ...
is a large mass of
intrusive rock Intrusive rock is formed when magma penetrates existing rock, crystallizes, and solidifies underground to form '' intrusions'', such as batholiths, dikes, sills, laccoliths, and volcanic necks.Intrusive RocksIntrusive rocks accessdate: March ...
formed from the crystallization of molten rock beneath the Earth's surface (
magma Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natura ...
). From
gravity In physics, gravity () is a fundamental interaction which causes mutual attraction between all things with mass or energy. Gravity is, by far, the weakest of the four fundamental interactions, approximately 1038 times weaker than the stro ...
and
magnetic Magnetism is the class of physical attributes that are mediated by a magnetic field, which refers to the capacity to induce attractive and repulsive phenomena in other entities. Electric currents and the magnetic moments of elementary particl ...
geophysical data, the batholith is interpreted to extend from about 8°W, more than 100 km southwest of the Isles of Scilly, to the eastern edge of Dartmoor. The negative gravity anomaly, caused by the relatively low density of the granites compared to average
continental crust Continental crust is the layer of igneous, sedimentary, and metamorphic rocks that forms the geological continents and the areas of shallow seabed close to their shores, known as continental shelves. This layer is sometimes called '' sial'' be ...
, is linear and trends WSW-ENE, parallel with that associated with the
Haig Fras Haig Fras is a 45 km long submarine granitic rocky outcrop in the southern part of the Celtic Sea, lying about 95 km northwest of the Isles of Scilly. It covers an area of . At one point it reaches within 38 m of the sea surface. It is ...
granite. The shape of the
batholith A batholith () is a large mass of intrusive igneous rock (also called plutonic rock), larger than in area, that forms from cooled magma deep in Earth's crust. Batholiths are almost always made mostly of felsic or intermediate rock types, s ...
and the relationship between the individual
pluton In geology, an igneous intrusion (or intrusive body or simply intrusion) is a body of intrusive igneous rock that forms by crystallization of magma slowly cooling below the surface of the Earth. Intrusions have a wide variety of forms and com ...
s and the main mass of the granite remained entirely speculative until gravity data began to be used to constrain the thickness and shape of the batholith by modelling. The initial work by Martin Bott suggested that the batholith had an overall trapezoidal shape with a base to the batholith at about 10–12 km. However, current understanding of granite pluton shape suggest that most are either
laccolith A laccolith is a body of intrusive rock with a dome-shaped upper surface and a level base, fed by a conduit from below. A laccolith forms when magma (molten rock) rising through the Earth's crust begins to spread out horizontally, prying apar ...
ic or
lopolith A lopolith is a large igneous intrusion which is lenticular in shape with a depressed central region. Lopoliths are generally concordant with the intruded strata with dike or funnel-shaped feeder bodies below the body. The term was first defin ...
ic. Comparisons with other examples would suggest that the thicknesses of the individual plutons would be in the range 3–5 km, based on their outcrop widths. The volume of the batholith was estimated in 1989 to be around 68,000 cubic kilometres.


Formation

The Cornubian batholith formed during the
Early Permian 01 or '01 may refer to: * The year 2001, or any year ending with 01 * The month of January * 1 (number) Music * 01'' (Richard Müller album), 2001 * ''01'' (Son of Dave album), 2000 * ''01'' (Urban Zakapa album), 2011 * ''O1'' (Hiroyuki Sawan ...
period, from about 300 to 275 Ma (million years ago) at a late stage in the mountain-building event known as the
Variscan orogeny The Variscan or Hercynian orogeny was a geologic mountain-building event caused by Late Paleozoic continental collision between Euramerica (Laurussia) and Gondwana to form the supercontinent of Pangaea. Nomenclature The name ''Variscan'', comes f ...
as a suite of late
orogenic Orogeny is a mountain building process. An orogeny is an event that takes place at a convergent plate margin when plate motion compresses the margin. An ''orogenic belt'' or ''orogen'' develops as the compressed plate crumples and is uplifted t ...
granites. It has been suggested that stretching of the Earth's crust (
crustal extension Extensional tectonics is concerned with the structures formed by, and the tectonic processes associated with, the stretching of a planetary body's crust or lithosphere. Deformation styles The types of structure and the geometries formed depend on ...
) allowed the granitic magmas to move to higher levels in the crust. Evidence from
neodymium Neodymium is a chemical element with the symbol Nd and atomic number 60. It is the fourth member of the lanthanide series and is considered to be one of the rare-earth metals. It is a hard, slightly malleable, silvery metal that quickly tarn ...
and
strontium Strontium is the chemical element with the symbol Sr and atomic number 38. An alkaline earth metal, strontium is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is e ...
isotopes suggests that the magmas that formed the batholith were mainly the result of
partial melting Partial melting occurs when only a portion of a solid is melted. For mixed substances, such as a rock containing several different minerals or a mineral that displays solid solution, this melt can be different from the bulk composition of the soli ...
of the lower crust with a minor component of basaltic magma from a
mantle A mantle is a piece of clothing, a type of cloak. Several other meanings are derived from that. Mantle may refer to: *Mantle (clothing), a cloak-like garment worn mainly by women as fashionable outerwear **Mantle (vesture), an Eastern Orthodox ve ...
source. This lower crustal source is likely to have consisted of both
metasedimentary In geology, metasedimentary rock is a type of metamorphic rock. Such a rock was first formed through the deposition and solidification of sediment Sediment is a naturally occurring material that is broken down by processes of weathering and e ...
and metavolcanic rocks, of
Proterozoic The Proterozoic () is a geological eon spanning the time interval from 2500 to 538.8million years ago. It is the most recent part of the Precambrian "supereon". It is also the longest eon of the Earth's geologic time scale, and it is subdivided i ...
age (2500 million to 539 million years old). As the molten rock cooled to around 1000
Celsius The degree Celsius is the unit of temperature on the Celsius scale (originally known as the centigrade scale outside Sweden), one of two temperature scales used in the International System of Units (SI), the other being the Kelvin scale. The d ...
it solidified and crystallised and fractures along vertical joints formed. Over time the slate and sandstone rocks covering the granite were eroded exposing the granite in areas such as Dartmoor and Bodmin Moor. The granite also expanded and horizontal joints were formed. These joints are most clearly seen on exposed pieces of rock such as the
Tors Tors may refer to: * Tor (rock formation), rock outcrops * Ivan Tors (1916–1983), playwright, screenwriter and film and television producer * TransOral Robotic Surgery, a surgical technique See also * Tor (disambiguation) * Ten Tors Ten To ...
of Dartmoor and Bodmin Moor. As the granite erodes further, blocks of eroded granite known as clitter are left.


Timing

An approximate age of emplacement for the Cornubian batholith was known before
radiometric dating Radiometric dating, radioactive dating or radioisotope dating is a technique which is used to date materials such as rocks or carbon, in which trace radioactive impurities were selectively incorporated when they were formed. The method compares ...
methods became commonplace, from the observed relationships with the
sedimentary Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles ...
rocks – both those which formed before the intrusion and those which were laid down after it. The youngest rocks into which the granites intrude are the
Carboniferous The Carboniferous ( ) is a geologic period and system of the Paleozoic that spans 60 million years from the end of the Devonian Period million years ago ( Mya), to the beginning of the Permian Period, million years ago. The name ''Carboniferou ...
Crackington and Bealsmill formations of
Namurian The Namurian is a stage in the regional stratigraphy of northwest Europe with an age between roughly 326 and 313 Ma (million years ago). It is a subdivision of the Carboniferous system or period and the regional Silesian series. The Namurian ...
to lower Westphalian age. This provides a lower bound for the timing of granite emplacement of about 310 Ma. The earliest instance of granitic
clasts Clastic rocks are composed of fragments, or clasts, of pre-existing minerals and rock. A clast is a fragment of geological detritus,Essentials of Geology, 3rd Ed, Stephen Marshak, p. G-3 chunks, and smaller grains of rock broken off other rocks ...
(fragments of the granite which have weathered away and become part of a new sedimentary rock) in younger sedimentary sequences is from the Late Permian St. Cyres beds. This gives an upper bound of about 250 Ma. The inferred age of emplacement from this evidence of Late Carboniferous to Early Permian has been confirmed by radiometric dating, although it has shown that the individual intrusions were emplaced over a significant time interval. The earliest dated major intrusion is the Carnmenellis pluton at 293.1±3 Ma. The youngest dated granite is the southern lobe of the Land's End pluton, intruded at 274.5±1.4 Ma. The earliest recorded magmatic activity is the intrusion of the small Hemerdon pluton on the southwestern flank of the Dartmoor pluton at 298.3±2.3 Ma. There is no apparent systematic variation in age of plutons compared to their position within the batholith. This suggests that the batholith grew by the coalescence of a series of separate intrusions over a period of about 25 Ma.


Mechanism of emplacement

As with all large intrusive bodies, the method by which the batholith's plutons were emplaced is a matter of debate, due to the space problem of adding such large masses to the upper crust. Four main mechanisms have been proposed; stoping,
diapirism A diapir (; , ) is a type of igneous intrusion in which a more mobile and ductily deformable material is forced into brittle overlying rocks. Depending on the tectonic environment, diapirs can range from idealized mushroom-shaped Rayleigh–T ...
, extensional faulting and uplift of the overlying
country rock Country rock is a genre of music which fuses rock and country. It was developed by rock musicians who began to record country-flavored records in the late 1960s and early 1970s. These musicians recorded rock records using country themes, vocal ...
over a laccolithic
sill Sill may refer to: * Sill (dock), a weir at the low water mark retaining water within a dock * Sill (geology), a subhorizontal sheet intrusion of molten or solidified magma * Sill (geostatistics) * Sill (river), a river in Austria * Sill plate, ...
with a relatively small vertical dyke feeder. Evidence for a stoping mechanism has been described locally from the margin of the Tregonning intrusion, where a series of intrusive sheets extend out from the roof zone of the intrusion into the country-rock. Although the Land's End pluton was once thought to have a diapiric origin, its emplacement is now interpreted to have been accommodated by fault movements during regional extension.


Plutons

The individual
pluton In geology, an igneous intrusion (or intrusive body or simply intrusion) is a body of intrusive igneous rock that forms by crystallization of magma slowly cooling below the surface of the Earth. Intrusions have a wide variety of forms and com ...
s that comprise the Cornubian Batholith can be broadly subdivided into five main lithologies: Two mica, Muscovite, Biotite, Tourmaline and Topaz granites, each named for their distinguishing mineral(s). The two-mica and muscovite granites are older, and can be found in the Carnmenellis, Bodmin and Isles of Scilly, whereas the younger biotite and tourmaline granites are found within the Land's End, St. Austell and Dartmoor plutons. Topaz granites outcrop within the Tregonning, Land's End and St Austell plutons.


Dartmoor

This is the largest exposed area of granite which also forms the easternmost development of the batholith. The granite consists of two main types, coarse-grained granite with abundant large
alkali feldspar Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) feldspa ...
megacrysts and coarse-grained granite with few megacrysts. To the southwest there is an area of coarse-grained granite with small megacrysts and several small exposures of fine-grained granite, particularly in the southeastern part of the outcrop. Interpretation of the gravity field over this pluton suggests that it is sheet-like with a thickness of nearly 10 km, and a root at its southern end extending down to about 17 km depth, which may represent the conduit that carried the magma to shallow crustal levels. It appears to have been intruded along the interface between Devonian and Carboniferous rocks. Uranium-lead dating of
Monazite Monazite is a primarily reddish-brown phosphate mineral that contains rare-earth elements. Due to variability in composition, monazite is considered a group of minerals. The most common species of the group is monazite-(Ce), that is, the ceriu ...
from this intrusion gives emplacement ages of 278.2±0.8 Ma and 280.4±1.2 Ma.


Bodmin Moor

The Bodmin Moor pluton consists mainly of coarse-grained granite with abundant small megacrysts. Towards the centre and the western margin of the outcrop there are smaller bodies of fine-grained granite. Gravity data suggest that this pluton is in the form of a south-southeastward thickening wedge, reaching a maximum of about 7 km. Monazite from this pluton gives an emplacement age of 291.4±0.8 Ma.


St Austell

The St Austell pluton consists of coarse-grained megacrystic granite with large megacrysts at the western and eastern ends of the outcrop. The central part of the pluton is also coarse-grained but lacks the megacrysts. Between the central megacryst poor and the large megacryst rich coarse-grained granites at the western end, a medium-grained granite is developed with lithium-mica. Smaller bodies of fine-grained granite are found in the central part of the outcrop and at the western end. Gravity data indicate that this pluton is wedge-shaped similar to that at Bodmin. Monazite gives an emplacement age of 281.8±0.4 Ma for this pluton.


Carnmenellis

The Carnmenellis pluton and the smaller intrusion of Carn Brea appear to be part of a single intrusive body. The central part of the Carnmenellis outcrop is a medium-grained granite with few megacrysts. The bulk of the main outcrop and the Carn Brea and Carn Marth masses consist of coarse-grained megacrystic granite with small megacrysts. Small bodies of fine-grained granite are found towards the west of the Carnemellis outcrop. The shape of this pluton is interpreted to be a sheet about 3 km thick with a near central root extending down to about 7 km depth. Boreholes at
Rosemanowes Rosemanowes Quarry, near Penryn, Cornwall, England, was a granite quarry and the site of an early experiment in extracting geothermal energy from the earth using hot dry rock (HDR) technology. Quarry In the nineteenth century the quarry provid ...
that extend to over 2.5 km deep have shown very little variation in the petrographic composition of the granite with depth in this pluton. Monazite gives an emplacement age of 293.7±0.6 Ma for this pluton.


Tregonning-Godolphin

The Tregonning Granite and Godolphin Granite are two distinct granite bodies on the southern coast of Cornwall. The Tregonning Granite is mainly a medium-grained lithium-mica granite with a body of fine-grained granite developed towards the northwest of the outcrop. It has a unique chemistry and differs from the granite found within the Carnmenellis and Land's End granites, likely forming in a different manner. The Godolphin Granite is mineralogically and chemically similar to the nearby Carnmenellis Granite, although is finer grained.


Land's End

The Land's End pluton is mainly a coarse-grained granite with abundant large megacrysts. There is an area in the centre which is poor in megacrysts and there are several small and medium-sized masses of fine-grained granite throughout the outcrop. Dating has been carried out on
xenotime Xenotime is a rare-earth phosphate mineral, the major component of which is yttrium orthophosphate ( Y P O4). It forms a solid solution series with chernovite-(Y) ( Y As O4) and therefore may contain trace impurities of arsenic, as well as sili ...
and monazite samples, from a fine-grained granite and the main coarse-grained granite respectively. These give emplacement ages of 279.3±0.4 Ma for the fine-grained granite and 274.8±0.5 Ma for the main phase granite. This difference is consistent with fine-grained granite being a roof-pendant to the coarse-grained main phase granite intrusion.


Isles of Scilly

The Isles of Scilly all have granite bedrock. The dominant rock type is a megacrystic biotite granite, although the megacrysts are relatively small. In the centre of the pluton a medium-grained granite is developed with few megacrysts, more tourmaline and less biotite than the main variety. Monazite from this pluton suggest an emplacement age of 290.3±0.6 Ma.


Haig Fras

This submarine outcrop, 45 km in length, lies 95 km northwest of the Scilly Isles, rising at one point to 38 m below sea level. In contrast to most granites of the Cornubian batholith the granites here are fine to medium-grained and generally lack megacrysts. It was intruded at 277 Ma and is considered most likely to be a separate but related intrusive body that runs parallel to the Cornubian batholith.


Other intrusions

Minor granitic intrusions are present throughout the peninsula. In some cases granitic bodies have been recognised from the mineralization above them, even if the intrusion itself has not been encountered. A series of minor intrusions are found within the country rock and the granites themselves. Common types are
pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silici ...
s, aplites and elvans.


Mineralogy and chemistry of the granite and other rocks


Granite

The main rock forming the batholith is
granite Granite () is a coarse-grained ( phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies un ...
, which formed when
magma Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natura ...
cooled slowly, covered by 2–3,000 metres of slate and sandstone. The slow cooling gave time for crystals to form in the granite which are large enough to see with the naked eye, giving it a granular appearance. These grains are mainly of
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical f ...
,
feldspar Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) felds ...
and
biotite Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron- endmember annite, and the magnesium-endmember phlogopite; more ...
. The granite is generally coarse grained and in some places very coarse-grained, or pegmatitic (grains larger than 3 cm). Large phenocrysts, several centimetres long, of K-feldspar, are a distinctive feature. The chemistry and mineralogy of the granites vary from one location to another, but they are all classified on the Chappell & White classification as being ''S-type'', which means that they are ultimately derived from
sedimentary rock Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles ...
protolith A protolith () is the original, unmetamorphosed rock from which a given metamorphic rock is formed. For example, the protolith of a slate is a shale or mudstone. Metamorphic rocks can be derived from any other kind of non-metamorphic rock an ...
.


Mineralogy

The Cornubian intrusions are mostly made up of two-
mica Micas ( ) are a group of silicate minerals whose outstanding physical characteristic is that individual mica crystals can easily be split into extremely thin elastic plates. This characteristic is described as perfect basal cleavage. Mica is ...
granite (containing both
muscovite Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula K Al2(Al Si3 O10)( F,O H)2, or ( KF)2( Al2O3)3( SiO2)6( H2O). It has a highly perfect basal cleavag ...
and
biotite Biotite is a common group of phyllosilicate minerals within the mica group, with the approximate chemical formula . It is primarily a solid-solution series between the iron- endmember annite, and the magnesium-endmember phlogopite; more ...
). Li-mica granite forms a less common type found only in the St. Austell pluton and some smaller intrusions. Many of the granites contain large alkali feldspar phenocrysts. In some locations the original granite has been modified to form a
tourmaline Tourmaline ( ) is a crystalline Silicate mineral, silicate mineral group in which boron is compounded with elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. Tourmaline is a gemstone and can be found in a wide variety o ...
-bearing granite called luxullianite. This tourmalinisation occurred during the late stages of cooling of the granite, as feldspar and mica were partly replaced by tourmaline.


Chemistry

The two-mica granites are strongly peraluminous – they have a high ratio of aluminium oxide to sodium and potassium oxides. They also have a low ratio of sodium to potassium and overall high level of alkalis. The granites are highly enriched in
lithium Lithium (from el, λίθος, lithos, lit=stone) is a chemical element with the symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the least dense metal and the least dense soli ...
,
boron Boron is a chemical element with the symbol B and atomic number 5. In its crystalline form it is a brittle, dark, lustrous metalloid; in its amorphous form it is a brown powder. As the lightest element of the '' boron group'' it has t ...
,
caesium Caesium (IUPAC spelling) (or cesium in American English) is a chemical element with the symbol Cs and atomic number 55. It is a soft, silvery-golden alkali metal with a melting point of , which makes it one of only five elemental metals that a ...
and
uranium Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weak ...
and moderately so in
fluorine Fluorine is a chemical element with the symbol F and atomic number 9. It is the lightest halogen and exists at standard conditions as a highly toxic, pale yellow diatomic gas. As the most electronegative reactive element, it is extremely reactiv ...
,
gallium Gallium is a chemical element with the Symbol (chemistry), symbol Ga and atomic number 31. Discovered by France, French chemist Paul-Émile Lecoq de Boisbaudran in 1875, Gallium is in boron group, group 13 of the periodic table and is similar to ...
,
germanium Germanium is a chemical element with the symbol Ge and atomic number 32. It is lustrous, hard-brittle, grayish-white and similar in appearance to silicon. It is a metalloid in the carbon group that is chemically similar to its group neighbors ...
,
rubidium Rubidium is the chemical element with the symbol Rb and atomic number 37. It is a very soft, whitish-grey solid in the alkali metal group, similar to potassium and caesium. Rubidium is the first alkali metal in the group to have a density higher ...
, tin,
tantalum Tantalum is a chemical element with the symbol Ta and atomic number 73. Previously known as ''tantalium'', it is named after Tantalus, a villain in Greek mythology. Tantalum is a very hard, ductile, lustrous, blue-gray transition metal that ...
,
tungsten Tungsten, or wolfram, is a chemical element with the symbol W and atomic number 74. Tungsten is a rare metal found naturally on Earth almost exclusively as compounds with other elements. It was identified as a new element in 1781 and first isol ...
and
thallium Thallium is a chemical element with the symbol Tl and atomic number 81. It is a gray post-transition metal that is not found free in nature. When isolated, thallium resembles tin, but discolors when exposed to air. Chemists William Crookes an ...
. Given the overall chemistry, the levels of
phosphorus Phosphorus is a chemical element with the symbol P and atomic number 15. Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Ea ...
are also high. Strontium,
barium Barium is a chemical element with the symbol Ba and atomic number 56. It is the fifth element in group 2 and is a soft, silvery alkaline earth metal. Because of its high chemical reactivity, barium is never found in nature as a free element. Th ...
and the elements from
scandium Scandium is a chemical element with the symbol Sc and atomic number 21. It is a silvery-white metallic d-block element. Historically, it has been classified as a rare-earth element, together with yttrium and the Lanthanides. It was discovered in ...
to
zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
are relatively depleted. This chemistry is consistent with partial melting of a source consisting of
greywacke Greywacke or graywacke (German ''grauwacke'', signifying a grey, earthy rock) is a variety of sandstone generally characterized by its hardness, dark color, and poorly sorted angular grains of quartz, feldspar, and small rock fragments or lit ...
s (a variety of sandstone). The conditions under which the melts formed is modelled to be temperature of 770 °C and a
confining pressure Pressure is force magnitude applied over an area. Overburden pressure is a geology term that denotes the pressure caused by the weight of the overlying layers of material at a specific depth under the earth's surface. Overburden pressure is also ca ...
of 50 MPa. Differences in chemistry have been identified between an earlier group of plutons (Isles of Scilly, Carnmenellis & Bodmin Moor) and a later group (Land's End, St Austell & Dartmoor). The early group of granites contain more aluminium than the later set and have steeper slopes on plots of
cerium Cerium is a chemical element with the symbol Ce and atomic number 58. Cerium is a soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it often shows the +3 ...
against
yttrium Yttrium is a chemical element with the symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a " rare-earth element". Yttrium is almost always found in co ...
. The later group contain more common basic microgranite
xenolith A xenolith ("foreign rock") is a rock fragment ( country rock) that becomes enveloped in a larger rock during the latter's development and solidification. In geology, the term ''xenolith'' is almost exclusively used to describe inclusions in ig ...
s. The granites are generally rich in ammonium compared to average granites worldwide. There is also considerable variation between the individual plutons, with an average of 11 ppm for Dartmoor compared to 94 ppm for Bodmin Moor. The concentration of ammonium in these granites correlates well with both their initial / ratios and their peraluminosity. The relatively high ammonium content is interpreted to indicate that the granites were derived from a sedimentary protolith, or have been contaminated from such a source after emplacement to high crustal levels.


Associated metamorphic and metasomatic rocks

Around the edges of many of the plutons the country rocks have been transformed by heat in a process known as
contact metamorphism Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of che ...
. The effects of this can be seen up to a distance of 4 miles from the granite in an area called the metamorphic aureole. The effect of this process depends on the type of rocks which were heated and their distance from the intrusion. Fine grained sedimentary rocks were transformed into
hornfels Hornfels is the group name for a set of contact metamorphic rocks that have been baked and hardened by the heat of intrusive igneous masses and have been rendered massive, hard, splintery, and in some cases exceedingly tough and durable. These pro ...
and minerals such as
amphibole Amphibole () is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is ...
,
pyroxene The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe I ...
. At greater distances from the plutons, the only evidence of metamorphism is spotting in these rocks.
Garnet Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. All species of garnets possess similar physical properties and crystal forms, but differ in chemical composition. The different ...
developed in
calcareous Calcareous () is an adjective meaning "mostly or partly composed of calcium carbonate", in other words, containing lime or being chalky. The term is used in a wide variety of scientific disciplines. In zoology ''Calcareous'' is used as an ad ...
rocks as well as
amphibole Amphibole () is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is ...
and
pyroxene The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe I ...
. The metamorphism of greenstones has generally led to the formation of
hornblende Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rock ...
-
plagioclase Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more p ...
rocks. A feature of the granites of the batholith is the high concentrations of volatile components. Fluids rich in these have strongly affected the country rock and locally the granites themselves in a process called metasomatism. The first phase recognised is alkali metasomatism (where alkaline components are enhanced), which occurred within and at the margins of the granite.
Potassium Potassium is the chemical element with the symbol K (from Neo-Latin '' kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmos ...
metasomatism Metasomatism (from the Greek μετά ''metá'' "change" and σῶμα ''sôma'' "body") is the chemical alteration of a rock by hydrothermal and other fluids. It is the replacement of one rock by another of different mineralogical and chemical co ...
was followed by
sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable ...
–metasomatism. Finally acid metasomatism (enrichment of acid components and depletion of alkalis) took place leading to the formation of greisen and tourmalines.


Mineral formation

Large
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2 ...
deposits are found in the vicinity of the batholith and these have been mined for thousands of years. The area has been famous for its tin since about 2000 BC. The minerals formed when fluids escaped along fractures in the hot granite as it cooled and are typically found in
veins Veins are blood vessels in humans and most other animals that carry blood towards the heart. Most veins carry deoxygenated blood from the tissues back to the heart; exceptions are the pulmonary and umbilical veins, both of which carry oxygenated ...
or washed into streams to form
alluvium Alluvium (from Latin ''alluvius'', from ''alluere'' 'to wash against') is loose clay, silt, sand, or gravel that has been deposited by running water in a stream bed, on a floodplain, in an alluvial fan or beach, or in similar settings. ...
. The mineral deposits are associated with multiple
lode In geology, a lode is a deposit of metalliferous ore that fills or is embedded in a fissure (or crack) in a rock formation or a vein of ore that is deposited or embedded between layers of rock. The current meaning (ore vein) dates from the 1 ...
s and fractures that dip steeply and cut across both the granites and the country rocks. The ore-bearing lodes are up to several kilometres long and are 0.5 to 3m wide on average.


Stages of mineralization

There are four recognised stages of
mineralization Mineralization may refer to: * Mineralization (biology), when an inorganic substance precipitates in an organic matrix ** Biomineralization, a form of mineralization ** Mineralization of bone, an example of mineralization ** Mineralized tissues ar ...
associated with different conditions as the granite slowly cooled. Each stage is associated with different temperatures, economic deposits of different metals and different
gangue In mining, gangue () is the commercially worthless material that surrounds, or is closely mixed with, a wanted mineral in an ore deposit. It is thus distinct from overburden, which is the waste rock or materials overlying an ore or mineral body ...
minerals. The first three stages have been connected to the intrusion and cooling of the batholith, while the fourth stage may have been driven by the heat production associated with
radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consi ...
materials in the granite. ;Stage 1 – exoskarns : The earliest phase of mineralization occurred during the intrusion of the granite. Hot water from the magma which was rich in silica, iron, aluminium, and magnesium mixed and dissolved
shale Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4) and tiny fragments (silt-sized particles) of other minerals, especiall ...
s and
metabasalt Amphibolite () is a metamorphic rock that contains amphibole, especially hornblende and actinolite, as well as plagioclase feldspar, but with little or no quartz. It is typically dark-colored and dense, with a weakly foliated or schistose (flaky ...
s, and converted them into exoskarns in a process called
metasomatism Metasomatism (from the Greek μετά ''metá'' "change" and σῶμα ''sôma'' "body") is the chemical alteration of a rock by hydrothermal and other fluids. It is the replacement of one rock by another of different mineralogical and chemical co ...
, where the chemical composition of rocks is changed by hot water or other fluids. Typical minerals formed at this time include
garnet Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. All species of garnets possess similar physical properties and crystal forms, but differ in chemical composition. The different ...
,
pyroxene The pyroxenes (commonly abbreviated to ''Px'') are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula , where X represents calcium (Ca), sodium (Na), iron (Fe I ...
,
epidote Epidote is a calcium aluminium iron sorosilicate mineral. Description Well developed crystals of epidote, Ca2Al2(Fe3+;Al)(SiO4)(Si2O7)O(OH), crystallizing in the monoclinic system, are of frequent occurrence: they are commonly prismatic in ...
, chlorine-rich amphiboles,
malayaite Malayaite is a calcium tin silicate mineral with formula CaSnOSiO4. It is a member of the titanite group. Discovery Malayaite was originally found in Perak (a state in Malaysia) and was first described in literature in 1961, though it was not yet ...
,
vesuvianite Vesuvianite, also known as idocrase, is a green, brown, yellow, or blue silicate mineral. Vesuvianite occurs as tetragonal crystals in skarn deposits and limestones that have been subjected to contact metamorphism. It was first discovered within ...
,
siderite Siderite is a mineral composed of iron(II) carbonate (FeCO3). It takes its name from the Greek word σίδηρος ''sideros,'' "iron". It is a valuable iron mineral, since it is 48% iron and contains no sulfur or phosphorus. Zinc, magnesium and ...
and axinite. The skarns may contain economic amounts of tin,
copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pink ...
,
iron Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in ...
and
arsenic Arsenic is a chemical element with the symbol As and atomic number 33. Arsenic occurs in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Arsenic is a metalloid. It has various allotropes, b ...
. These minerals were formed at about the same time as the crystallisation of the pluton they are associated with. Temperatures associated with this stage were 375 – 450 °C. ;Stage 2 – greisen bordered veins and tourmaline veins and breccias : The second recognised phase of mineralization involved the granite being transformed by high-temperature late magmatic fluids rich in volatiles to form greisen and
tourmaline Tourmaline ( ) is a crystalline Silicate mineral, silicate mineral group in which boron is compounded with elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. Tourmaline is a gemstone and can be found in a wide variety o ...
. Veins of
cassiterite Cassiterite is a tin oxide mineral, SnO2. It is generally opaque, but it is translucent in thin crystals. Its luster and multiple crystal faces produce a desirable gem. Cassiterite was the chief tin ore throughout ancient history and remains ...
(tin oxide) and
wolframite Wolframite is an iron, manganese, and tungstate mineral with a chemical formula of that is the intermediate between ferberite ( rich) and hübnerite ( rich). Along with scheelite, the wolframite series are the most important tungsten ore mineral ...
(a mineral containing iron, manganese and tungsten) are found associated with the greisens, the former deposited by high salinity, low , fluids and the latter by low salinity, high fluids.
Muscovite Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula K Al2(Al Si3 O10)( F,O H)2, or ( KF)2( Al2O3)3( SiO2)6( H2O). It has a highly perfect basal cleavag ...
s within the greisens give cooling ages similar to magmatic muscovites in the relevant granite. ;Stage 3 – the main phase of mineralization : The third and main phase of mineralization occurred at a later stage, and at lower temperatures (200 – 400 °C) as the granite intrusion cooled. Fluids circulating within the country rock leached out tin, copper and arsenic and deposited them in veins which generally lie on an east–west axis. The typical fill of these veins is
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical f ...
-tourmaline-
chlorite The chlorite ion, or chlorine dioxide anion, is the halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as salts of chlorou ...
-sulfide-
fluorite Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon. The Mohs sca ...
, with tin, copper, lead, zinc, iron and arsenic sulfides. This mineralization is 25–40 Ma later than the intrusion age for the Carnmenellis pluton. These veins are the main economically useful source of minerals. ;Stage 4 – crosscourses :The fourth and final stage of mineralization was the lowest temperature phase (100 – 170 °C) and is associated with veins containing multiple metallic elements (lead, zinc,
silver Silver is a chemical element with the symbol Ag (from the Latin ', derived from the Proto-Indo-European ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, white, lustrous transition metal, it exhibits the highest electrical ...
and
uranium Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weak ...
). The veins lie on a north–south or northwest–southeast axis and are known as 'crosscourses' because they cross-cut the earlier E-W trending veins. Gangue minerals include quartz,
barite Baryte, barite or barytes ( or ) is a mineral consisting of barium sulfate ( Ba S O4). Baryte is generally white or colorless, and is the main source of the element barium. The ''baryte group'' consists of baryte, celestine (strontium sulfate), ...
and fluorite. Studies on quartz
fluid inclusions image:Inclumed.gif, 250px, Trapped in a time capsule the same size as the diameter of a human hair, the ore-forming liquid in this inclusion was so hot and contained so much dissolved solids that when it cooled, crystals of halite, sylvite, gypsum, ...
have shown that the fluids causing this stage are similar in composition to deep sedimentary
brine Brine is a high-concentration solution of salt (NaCl) in water (H2O). In diverse contexts, ''brine'' may refer to the salt solutions ranging from about 3.5% (a typical concentration of seawater, on the lower end of that of solutions used for ...
s which are rich in sodium, calcium and chlorine. This brine came from Permo-Triassic sedimentary rocks that once covered the entire area. These rocks are still preserved in the
Southwest Approaches The Southwest Approaches is the name given to the offshore waters to the southwest of Great Britain and Ireland. The area includes the Celtic Sea, the Bristol Channel and sea areas off southwest Ireland. The area is bordered on the north by the S ...
to the
English Channel The English Channel, "The Sleeve"; nrf, la Maunche, "The Sleeve" ( Cotentinais) or ( Jèrriais), ( Guernésiais), "The Channel"; br, Mor Breizh, "Sea of Brittany"; cy, Môr Udd, "Lord's Sea"; kw, Mor Bretannek, "British Sea"; nl, Het Ka ...
. Evidence of seawater influence suggests that the mineralization did not start until the Late
Triassic The Triassic ( ) is a geologic period and system which spans 50.6 million years from the end of the Permian Period 251.902 million years ago ( Mya), to the beginning of the Jurassic Period 201.36 Mya. The Triassic is the first and shortest per ...
marine incursion at the earliest. The high heatflow from the granites helped drive fluid circulation.


China clay

Large economic deposits of
china clay Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedra ...
are found in places across the south-west peninsula, in particular Lee Moor on the western edge of Dartmoor and the St Austell district. The china clay was formed by the alteration of feldspars in a process known as kaolinization. There is still debate about the origin and age of these deposits but they are commonly thought to arise from the circulation of
meteoric water Meteoric water is the water derived from precipitation (snow and rain). This includes water from lakes, rivers, and icemelts, which all originate from precipitation indirectly. While the bulk of rainwater or meltwater from snow and ice reaches the ...
(water from rain or snow) at a late stage during cooling of the batholith. One theory is that the kaolinization resulted from intense
supergene A supergene is a chromosomal region encompassing multiple neighboring genes that are inherited together because of close genetic linkage, i.e. much less recombination than would normally be expected. This mode of inheritance can be due to genom ...
weathering Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs '' in situ'' (on site, with little or no movement ...
in a tropical to warm climate during the
Cretaceous The Cretaceous ( ) is a geological period that lasted from about 145 to 66 million years ago (Mya). It is the third and final period of the Mesozoic Era, as well as the longest. At around 79 million years, it is the longest geological period of ...
to
Cenozoic The Cenozoic ( ; ) is Earth's current geological era, representing the last 66million years of Earth's history. It is characterised by the dominance of mammals, birds and flowering plants, a cooling and drying climate, and the current configu ...
, based on studies of D/ H and / ratios.


References


Sources

*


External links


Nick LeBoutillier's website on Cornish Geology
* Nick LeBoutillier's D.Phil. thesis: ''The Tectonics of Variscan Magmatism and Mineralisation in South West England'' (2002)
Vol 1
an
Vol 2
{{coord, 50.2, -5.2, display=title Geology of Cornwall Geology of Devon Batholiths of Europe Permian England Granite Permian magmatism