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Weathering steel, often referred to by the genericised trademark COR-TEN steel and sometimes written without the hyphen as corten steel, is a group of
steel alloy Alloy steel is steel that is alloyed with a variety of elements in total amounts between 1.0% and 50% by weight to improve its mechanical properties. Alloy steels are broken down into two groups: low alloy steels and high alloy steels. The differe ...
s which were developed to eliminate the need for painting, and form a stable
rust Rust is an iron oxide, a usually reddish-brown oxide formed by the reaction of iron and oxygen in the catalytic presence of water or air moisture. Rust consists of hydrous iron(III) oxides (Fe2O3·nH2O) and iron(III) oxide-hydroxide (FeO( ...
-like appearance after several years' exposure to weather. U.S. Steel (USS) holds the
registered trademark The registered trademark symbol, , is a typographic symbol that provides notice that the preceding word or symbol is a trademark or service mark that has been registered with a national trademark office. A trademark is a symbol, word, or wor ...
on the name COR-TEN. The name COR-TEN refers to the two distinguishing properties of this type of steel:
corrosion Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engi ...
resistance and
tensile strength Ultimate tensile strength (UTS), often shortened to tensile strength (TS), ultimate strength, or F_\text within equations, is the maximum stress that a material can withstand while being stretched or pulled before breaking. In brittle materials t ...
. Although USS sold its discrete plate business to
International Steel Group International Steel Group (ISG) was an American steel company, headquartered in Cleveland, Ohio, which was established by the New York investment firm WL Ross & Co LLC to acquire the assets of bankrupt steel companies and combine them together in ...
(now ArcelorMittal) in 2003, it still sells COR-TEN branded material in strip-mill plate and sheet forms. The original COR-TEN received the standard designation A242 (COR-TEN A) from the
ASTM International ASTM International, formerly known as American Society for Testing and Materials, is an international standards organization that develops and publishes voluntary consensus technical standards for a wide range of materials, products, systems, ...
standards group. Newer ASTM grades are A588 (COR-TEN B) and A606 for thin sheet. All alloys are in common production and use. The surface oxidation of weathering steel takes six months, but surface treatments can accelerate the oxidation to as little as one hour.


History

The history of weathering steels began in the US in 1910s, when steels alloyed with different amounts of copper were exposed to the elements; the research continued into the 1920s and ca. 1926 it was discovered that phosphorus content also helps with the corrosion resistance. In 1933 the United States Steel Corporation decided to commercialize the results of their studies and patented a steel with exceptional mechanical resistance, primarily for use in railroad
hopper car A hopper car (US) or hopper wagon ( UIC) is a type of railroad freight car used to transport loose bulk commodities such as coal, ore, grain, and track ballast. Two main types of hopper car exist: covered hopper cars, which are equipped with ...
s, for the handling of heavy bulk loads including coal, metal
ore Ore is natural rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit.Encyclopædia Britannica. "Ore". Encyclopædia Britannica Online. Retrieved 7 Apr ...
s, other mineral products and grain. The controlled corrosion for which this material is now best known was a welcome benefit discovered soon after, prompting USS to apply the trademarked name Cor-Ten. Because of its inherent toughness, this steel is still used extensively for bulk transport and storage containers. Railroad passenger cars were also being built with Cor-Ten, albeit painted, by Pullman-Standard for the Southern Pacific from 1936, continuing through commuter coaches for the
Rock Island Line "Rock Island Line" is an American folk song. Ostensibly about the Chicago, Rock Island and Pacific Railroad, it appeared as a folk song as early as 1929. The first recorded performance of "Rock Island Line" was by inmates of the Arkansas Cummins ...
in 1949.“Railroad News and Editorial Comment,”''
Trains In rail transport, a train (from Old French , from Latin , "to pull, to draw") is a series of connected vehicles that run along a railway track and transport people or freight. Trains are typically pulled or pushed by locomotives (often know ...
'' magazine, January 1950
In 1964, the Moorestown Interchange was built over New Jersey Turnpike at milepost 37.02. This overpass is believed to be the first highway structure application of weathering steel. Other states including Iowa, Ohio, and Michigan followed soon after. Those were followed by
York University York University (french: Université York), also known as YorkU or simply YU, is a public university, public research university in Toronto, Ontario, Canada. It is Canada's fourth-largest university, and it has approximately 55,700 students, 7,0 ...
Footbridge in the United Kingdom in 1967. Since then, the practice of using weather steel in bridges has expanded to many countries.


Properties

''Weathering'' refers to the chemical composition of these steels, allowing them to exhibit increased resistance to atmospheric corrosion compared to other steels. This is because the steel forms a protective layer on its surface under the influence of the weather. The corrosion-retarding effect of the protective layer is produced by the particular distribution and concentration of alloying elements in it. It is not yet clear how exactly the patina formation differs from usual rusting, but it's established that drying of the wetted surface is necessary and that copper is the most important alloying element. The layer protecting the surface develops and regenerates continuously when subjected to the influence of the weather. In other words, the steel is allowed to rust in order to form the protective coating. The mechanical properties of weathering steels depend on which alloy and how thick the material is.


ASTM A242

The original A242 alloy has a
yield strength In materials science and engineering, the yield point is the point on a stress-strain curve that indicates the limit of elastic behavior and the beginning of plastic behavior. Below the yield point, a material will deform elastically and ...
of and ultimate tensile strength of for light-medium rolled shapes and plates up to thick. It has yield strength of and ultimate strength of for medium weight rolled shapes and plates from thick. The thickest rolled sections and plates – from thick have yield strength of and ultimate strength of . ASTM A242 is available in Type 1 and Type 2. Both have different applications based on the thickness. Type 1 is often used in housing structures, construction industry and freight cars. The Type 2 steel, which is also called Corten B, is used primarily in urban furnishing, passenger ships or cranes.


ASTM A588

A588 has a yield strength of at least , and ultimate tensile strength of for all rolled
shapes A shape or figure is a graphical representation of an object or its external boundary, outline, or external surface, as opposed to other properties such as color, texture, or material type. A plane shape or plane figure is constrained to lie o ...
and plate thicknesses up to thick. Plates from have yield strength at least and ultimate tensile strength at least , and plates from thick have yield strength at least and ultimate tensile strength at least .


Uses

Weathering steel is popularly used in outdoor sculptures for its distressed antique appearance. One example is the large
Chicago Picasso The Chicago Picasso (often just ''The Picasso'') is an untitled monumental sculpture by Pablo Picasso in Daley Plaza in Chicago, Illinois. ''The Picasso'' "precipitated an aesthetic shift in civic and urban planning, broadening the idea of public ...
sculpture, which stands in the plaza of the Daley Center Courthouse in Chicago, which is also constructed of weathering steel. Other examples include Barnett Newman's ''
Broken Obelisk ''Broken Obelisk'' is a sculpture designed by Barnett Newman between 1963 and 1967. Fabricated from three tons of Cor-Ten steel, which acquires a rust-colored patina, it is the largest and best known of his six sculptures. Four multiples of ...
''; several of Robert Indiana's ''Numbers'' sculptures and his original '' Love'' sculpture; numerous works by
Richard Serra Richard Serra (born November 2, 1938) is an American artist known for his large-scale sculptures made for site-specific landscape, Urban area, urban, and Architecture, architectural settings. Serra's sculptures are notable for their material q ...
; the '' Alamo'' sculpture in Manhattan, NY; the Barclays Center,
Brooklyn Brooklyn () is a borough of New York City, coextensive with Kings County, in the U.S. state of New York. Kings County is the most populous county in the State of New York, and the second-most densely populated county in the United States, be ...
, New York; the ''
Angel of the North The ''Angel of the North'' is a contemporary sculpture by Antony Gormley, located in Gateshead, Tyne and Wear, England. Completed in 1998, it is believed to be the largest sculpture of an angel in the world and is viewed by an estimated 33 m ...
'', Gateshead; and Broadcasting Tower at
Leeds Beckett University Leeds Beckett University (LBU), formerly known as Leeds Metropolitan University (LMU) and before that as Leeds Polytechnic, is a public university in Leeds, West Yorkshire, England. It has campuses in the city centre and Headingley. The univ ...
. It is also used in bridge and other large structural applications such as the
New River Gorge Bridge The New River Gorge Bridge is a steel arch bridge long over the New River Gorge near Fayetteville, West Virginia, in the Appalachian Mountains of the eastern United States. With an arch long, the New River Gorge Bridge was the world's longest sin ...
, the second span of the Newburgh–Beacon Bridge (1980), and the creation of the Australian Centre for Contemporary Art (ACCA) and MONA. It is very widely used in marine transportation, in the construction of
intermodal container An intermodal container, often called a shipping container, is a large standardized shipping container, designed and built for intermodal freight transport, meaning these containers can be used across different modes of transport – from ship ...
s as well as visible sheet piling along recently widened sections of London's M25 motorway. The first use of weathering steel for architectural applications was the John Deere World Headquarters in Moline, Illinois. The building was designed by architect Eero Saarinen, and completed in 1964. The main buildings of Odense University, designed by
Knud Holscher Knud Helmuth Holscher (born 6 May 1930 in Rødby, Denmark) is a Danish architect and industrial designer. For many years he was a partner in KHR Architects with Svend Axelsson and designed many of their works together. Biography Holscher studied ...
and Jørgen Vesterholt and built 1971–1976, are clad in weathering steel, earning them the nickname ''Rustenborg'' (Danish for "rusty fortress"). In 1977, Robert Indiana created a
Hebrew Hebrew (; ; ) is a Northwest Semitic language of the Afroasiatic language family. Historically, it is one of the spoken languages of the Israelites and their longest-surviving descendants, the Jews and Samaritans. It was largely preserved ...
version of the ''Love'' sculpture made from weathering steel using the four-letter word
ahava Ahava Dead Sea Laboratories, Limited ( he, אהבה, ''Love'') is an Israeli cosmetics company with headquarters in Lod that manufactures skin care products made of mud and mineral-based compounds from the Dead Sea. The company has flagship ...
(אהבה, "love" in Hebrew) for the Israel Museum Art Garden in
Jerusalem Jerusalem (; he, יְרוּשָׁלַיִם ; ar, القُدس ) (combining the Biblical and common usage Arabic names); grc, Ἱερουσαλήμ/Ἰεροσόλυμα, Hierousalḗm/Hierosóluma; hy, Երուսաղեմ, Erusałēm. i ...
, Israel. In Denmark, all masts for supporting the catenary on electrified railways are made of weathering steel for aesthetic reasons. Weathering steel was used in 1971 for the Highliner electric cars built by the
St. Louis Car Company The St. Louis Car Company was a major United States manufacturer of railroad passenger cars, streetcars, interurbans, trolleybuses and locomotives that existed from 1887 to 1974, based in St. Louis, Missouri. History The St. Louis Car Company ...
for Illinois Central Railroad. The use of weathering steel was seen as a cost-cutting move in comparison with the contemporary railcar standard of stainless steel. A subsequent order in 1979 was built to similar specs, including weathering steel bodies, by Bombardier. The cars were painted, a standard practice for weathering steel railcars. The durability of weathering steel did not live up to expectations, with rust holes appearing in the railcars. Painting may have contributed to the problem, as painted weathering steel is no more corrosion-resistant than conventional steel, because the protective patina will not form in time to prevent corrosion over a localized area of attack such as a small paint failure. These cars have been retired by 2016. Weathering steel was used to build the exterior of Barclays Center, made up of 12,000 pre-weathered steel panels engineered by ASI Limited & SHoP Construction. The ''New York Times'' says of the material, "While it can look suspiciously unfinished to the casual observer, it has many fans in the world of art and architecture."


Disadvantages

Using weathering steel in construction presents several challenges. Ensuring that weld-points weather at the same rate as the other materials may require special welding techniques or material. Weathering steel is not rust-proof in itself: if water is allowed to accumulate on the surface of the steel, it will experience a higher corrosion rate, so provision for drainage must be made. Weathering steel is sensitive to humid subtropical climates, and in such environments it is possible that the protective patina may not stabilize but instead continue to corrode. For example, the former Omni Coliseum, built in 1972 in
Atlanta Atlanta ( ) is the capital and most populous city of the U.S. state of Georgia. It is the seat of Fulton County, the most populous county in Georgia, but its territory falls in both Fulton and DeKalb counties. With a population of 498,715 ...
, never stopped rusting and eventually large holes appeared in the structure. This was a major factor in the decision to demolish it just 25 years after construction. The same thing can happen in environments laden with sea salt. Hawaii's Aloha Stadium, built in 1975, is one example of this. Weathering steel's normal surface weathering can also lead to rust stains on nearby surfaces. The rate at which some weathering steels form the desired patina varies strongly with the presence of atmospheric pollutants which catalyze corrosion. While the process is generally successful in large urban centers, the weathering rate is much slower in more rural environments. Uris Hall, a social sciences building on
Cornell University Cornell University is a private statutory land-grant research university based in Ithaca, New York. It is a member of the Ivy League. Founded in 1865 by Ezra Cornell and Andrew Dickson White, Cornell was founded with the intention to tea ...
's main campus in Ithaca, a small town in
Upstate New York Upstate New York is a geographic region consisting of the area of New York State that lies north and northwest of the New York City metropolitan area. Although the precise boundary is debated, Upstate New York excludes New York City and Long Is ...
, did not achieve the predicted surface finish on its Bethlehem Steel Mayari-R weathering steel framing within the predicted time. Rainwater runoff from the slowly rusting steel stained the numerous large windows and increased maintenance costs. Corrosion without the formation of a protective layer apparently led to the need for emergency structural reinforcement and galvanizing in 1974, less than two years after opening. The U.S. Steel Tower in
Pittsburgh, Pennsylvania Pittsburgh ( ) is a city in the Commonwealth of Pennsylvania, United States, and the county seat of Allegheny County. It is the most populous city in both Allegheny County and Western Pennsylvania, the second-most populous city in Pennsylva ...
, was constructed by U.S. Steel in part to showcase COR-TEN steel. The initial weathering of the material resulted in a discoloration, known as "bleeding" or "runoff", of the surrounding city sidewalks and nearby buildings. A cleanup effort was orchestrated by the corporation once weathering was complete to clean the markings. A few of the nearby sidewalks were left uncleaned, and remain a rust color. This problem has been reduced in newer formulations of weathering steel. Staining can be prevented if the structure can be designed so that water does not drain from the steel onto concrete where stains would be visible.


See also

* Iron (disambiguation) * Iron pillar (disambiguation), with some characteristics similar to weathering steel * Steel (disambiguation) *
Weathering Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs ''in situ'' (on site, with little or no movement) ...


References


External links


Report on Weathering Steel in TxDOT Bridges
from the
Texas Department of Transportation The Texas Department of Transportation (TxDOT ) is a government agency in the American state of Texas. Though the public face of the agency is generally associated with the construction and maintenance of the state's immense state highway system ...
(4464 KB). Contains recommended details to avoid staining. ''Note: wrapping of piers was later found not to be cost-effective.''
A Primer on Weathering Steel
from ''STRUCTURE'' magazine (2005)

from Colorado and London (2020) {{Iron and steel production Structural steel Steels Sculpture materials U.S. Steel