Chemical waste
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Chemical waste is any excess, unusable, or unwanted
chemical A chemical substance is a form of matter having constant chemical composition and characteristic properties. Some references add that chemical substance cannot be separated into its constituent elements by physical separation methods, i.e., w ...
, especially those that cause damage to human health or the environment. Chemical waste may be classified as hazardous waste, non-hazardous waste, universal waste, and
household hazardous waste Household hazardous waste (HHW) was a term coined by Dave Galvin from Seattle, Washington in 1982 as part of the fulfillment of a US EPA grant. This new term was reflective of the recent passage of the Resource Conservation and Recovery Act of ...
. Hazardous waste is a material that displays one or more of four characteristics: ignitability, corrosivity, reactivity, and toxicity. This information, along with disposal requirements, is typically available on the Material Safety Data Sheet (MSDS). Chemical waste that is radioactive, radioactive waste, requires special means of handling and disposal. Biohazardous waste, although often chemical, falls into four categories and is handled differently.


Laboratory chemical waste in the US

The
U.S. Environmental Protection Agency The Environmental Protection Agency (EPA) is an Independent agencies of the United States government, independent executive agency of the United States federal government tasked with environmental protection matters. President Richard Nixon pro ...
(EPA) prohibits disposing of certain materials down drains. Therefore, when hazardous chemical waste is generated in a laboratory setting, it is usually stored on-site in an appropriate waste carboy where it is later collected and disposed of by a specialist contractor in order to meet safety, health, and legislative requirements. For example, many university's Environment, Health, and Safety (EHS) divisions/departments serve the collection and oversight role.
Organic solvents A solvent (s) (from the Latin '' solvō'', "loosen, untie, solve") is a substance that dissolves a solute, resulting in a solution. A solvent is usually a liquid but can also be a solid, a gas, or a supercritical fluid. Water is a solvent for p ...
and other organic waste is typically incinerated. Some chemical wastes are recycled, such as waste elemental mercury.


Laboratory waste containers

Packaging, labeling, and storage are the three requirements for disposing of chemical waste. (These guidelines are not applicable to biohazardous waste and radioactive waste).


Packaging

For packaging, chemical liquid waste containers should only be filled up to 75% capacity to allow for vapor expansion and to reduce potential spills which could occur from moving overfilled containers. Container material must be compatible with the stored hazardous waste. In addition to the general packaging requirements mentioned above, incompatible materials should never be mixed in a single container (see below). Precipitates,
solid Solid is one of the four fundamental states of matter (the others being liquid, gas, and plasma). The molecules in a solid are closely packed together and contain the least amount of kinetic energy. A solid is characterized by structural ...
s, or other non-fluid wastes are typically stored separate from liquid waste.


Labeling

All containers should be labeled with the group name from the chemical waste category and an itemized list of the contents. All chemicals or anything contaminated with chemicals pose a significant hazard. All waste must be appropriately packaged.


Storage

When storing chemical wastes, the containers must be in good condition and should remain closed unless waste is being added. The container should be sturdy and leak-proof and must be labeled. All liquid waste must be stored in leak-proof containers with a screw-top or other secure lid, not
parafilm Parafilm is a semi-transparent, flexible film composed of a blend of waxes and polyolefins. It is a ductile, malleable, non-toxic, edible, tasteless and odorless, and self-sealing thermoplastic. The name ''Parafilm'' is a registered trademark o ...
or other loose-fitting lids that can become dislodged in transit. A secondary containment (e.g., flammable cabinet or large plastic bin, etc.) should be used to capture spills and leaks from the primary container and segregate incompatible
hazardous wastes Hazardous waste is waste that has substantial or potential threats to public health or the environment. Hazardous waste is a type of dangerous goods. They usually have one or more of the following hazardous traits: ignitability, reactivity, cor ...
, such as
acids In computer science, ACID ( atomicity, consistency, isolation, durability) is a set of properties of database transactions intended to guarantee data validity despite errors, power failures, and other mishaps. In the context of databases, a ...
and bases.


Chemical compatibility guidelines

Many chemicals may react adversely when combined. It is recommended that incompatible chemicals be stored in separate areas of the lab.
Acids In computer science, ACID ( atomicity, consistency, isolation, durability) is a set of properties of database transactions intended to guarantee data validity despite errors, power failures, and other mishaps. In the context of databases, a ...
should be separated from alkalis, metals,
cyanides Cyanide is a naturally occurring, rapidly acting, toxic chemical that can exist in many different forms. In chemistry, a cyanide () is a chemical compound that contains a functional group. This group, known as the cyano group, consists of a ...
, sulfides,
azides In chemistry, azide is a linear, polyatomic anion with the formula and structure . It is the conjugate base of hydrazoic acid . Organic azides are organic compounds with the formula , containing the azide functional group. The dominant applicat ...
phosphides In chemistry, a phosphide is a compound containing the ion or its equivalent. Many different phosphides are known, with widely differing structures. Most commonly encountered on the binary phosphides, i.e. those materials consisting only of phos ...
, and oxidizers, as when acids combine with these types of compounds, violent
exothermic reactions In thermodynamics, an exothermic process () is a thermodynamic process or reaction that releases energy from the system to its surroundings, usually in the form of heat, but also in a form of light (e.g. a spark, flame, or flash), electricity (e ...
can occur possibly causing flammable gas, and in some cases explosions. Oxidizers should be separated from acids, organic materials,
metal A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typicall ...
s, reducing agents, and
ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous wa ...
, as when oxidizers combine with these types of compounds, flammable and sometimes toxic compounds can be created.


Environmental pollution


Pharmaceuticals


PPCPs


River pollution


Textile industry

The
textile industry The textile industry is primarily concerned with the design, production and distribution of yarn, cloth and clothing. The raw material may be natural, or synthetic using products of the chemical industry. Industry process Cotton manufacturi ...
is one of the largest polluters in the
globalized Globalization, or globalisation (Commonwealth English; see spelling differences), is the process of interaction and integration among people, companies, and governments worldwide. The term ''globalization'' first appeared in the early 20t ...
world of mostly free market dominated socioeconomic systems. Chemically polluted textile wastewater degrades the quality of the
soil Soil, also commonly referred to as earth or dirt Dirt is an unclean matter, especially when in contact with a person's clothes, skin, or possessions. In such cases, they are said to become dirty. Common types of dirt include: * Debri ...
and
water Water (chemical formula ) is an Inorganic compound, inorganic, transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living ...
. The pollution comes from the type of conduct of chemical treatments used e.g., in pretreatment, dyeing, printing, and finishing operations that many or most market-driven companies use despite "eco-friendly alternatives". Textile industry wastewater (TIWW) is considered to be one the largest polluters of water and soil
ecosystem An ecosystem (or ecological system) consists of all the organisms and the physical environment with which they interact. These biotic and abiotic components are linked together through nutrient cycles and energy flows. Energy enters the syste ...
s, causing e.g., "carcinogenic, mutagenic, genotoxic, cytotoxic and allergenic threats to living organisms". The textile industry uses over 8000 chemicals in its supply chain, also pollutes the environment with large amounts of
microplastics Microplastics are fragments of any type of plastic less than in length, according to the U.S. National Oceanic and Atmospheric Administration (NOAA) and the European Chemicals Agency. They cause pollution by entering natural ecosystems from a v ...
and has been identified in one review as the biggest pollution causing production sector. A campaign of big clothing brands like Nike, Adidas and Puma to voluntarily reform their manufacturing supply chains to commit to achieve zero discharges of hazardous chemicals by 2020 (global goal) appears to have failed. Textile industry also creates a lot of pollution that leads to externalities which causes big problems in the economy. The problem usually occurs when there is no division of ownership rights. This means that problem of pollution is mainly caused because of lacking information about which company pollutes and at what scale the damage was caused by the pollution.


Planetary boundary

A study by ''"Scienmag"'' defines a '
planetary boundary Planetary boundaries is a concept highlighting human-caused perturbations of Earth systems making them relevant in a way not accommodated by the environmental boundaries separating the three ages within the Holocene epoch. Crossing a planetary ...
' for novel entities such as
plastic Plastics are a wide range of synthetic or semi-synthetic materials that use polymers as a main ingredient. Their plasticity makes it possible for plastics to be moulded, extruded or pressed into solid objects of various shapes. This adaptab ...
and chemical pollution. The study reported that the boundary has been crossed.


Regulation of chemical waste

Chemical waste may fall under regulation such as
COSHH The Control of Substances Hazardous to Health Regulations 2002 is a United Kingdom Statutory Instrument which states general requirements imposed on employers to protect employees and other persons from the hazards of substances used at work by ...
in the
United Kingdom The United Kingdom of Great Britain and Northern Ireland, commonly known as the United Kingdom (UK) or Britain, is a country in Europe, off the north-western coast of the European mainland, continental mainland. It comprises England, Scotlan ...
or the Clean Water Act and
Resource Conservation and Recovery Act The Resource Conservation and Recovery Act (RCRA), enacted in 1976, is the principal federal law in the United States governing the disposal of solid waste and hazardous waste.United States. Resource Conservation and Recovery Act. , , ''et seq., ...
in the
United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territori ...
. In the U.S., the Environmental Protection Agency (EPA) and the Occupational Safety and Health Administration (OSHA), as well as state and local regulations, also regulate chemical use and disposal.


Chemical waste in Canadian aquaculture

Chemical waste in oceans is becoming a major issue for marine life. There have been many studies conducted to try and prove the effects of chemicals in our oceans. In Canada, many of the studies concentrated on the Atlantic provinces, where fishing and aquaculture are an important part of the economy. In New Brunswick, a study was done on the sea urchin in an attempt to identify the effects of toxic and chemical waste on life beneath the ocean, specifically the waste from salmon farms. Sea urchins were used to check the levels of metals in the environment. It is advantageous to use green sea urchins because they are widely distributed, abundant in many locations, and easily accessible. By investigating the concentrations of metals in the green sea urchins, the impacts of chemicals from salmon aquaculture activity could be assessed and detected. Samples were taken at 25-metre intervals along a transect in the direction of the main tidal flow. The study found that there were impacts to at least 75 meters based on the intestine metal concentrations.


See also

* Industrial waste *
List of waste types Waste comes in many different forms and may be categorized in a variety of ways. The types listed here are not necessarily exclusive and there may be considerable overlap so that one waste entity may fall into one to many types. * Agricultural ...
*
Municipal solid waste Municipal solid waste (MSW), commonly known as trash or garbage in the United States and rubbish in Britain, is a waste type consisting of everyday items that are discarded by the public. "Garbage" can also refer specifically to food waste ...
* Radioactive waste *
Toxic waste Toxic waste is any unwanted material in all forms that can cause harm (e.g. by being inhaled, swallowed, or absorbed through the skin). Mostly generated by industry, consumer products like televisions, computers, and phones contain toxic chemi ...
*
Waste management Waste management or waste disposal includes the processes and actions required to manage waste from its inception to its final disposal. This includes the collection, transport, treatment and disposal of waste, together with monitorin ...
*
Water pollution Water pollution (or aquatic pollution) is the contamination of water bodies, usually as a result of human activities, so that it negatively affects its uses. Water bodies include lakes, rivers, oceans, aquifers, reservoirs and groundwater. ...


References


Further reading

*


External links


Industrial Materials Recycling
– US EPA {{DEFAULTSORT:Chemical Waste Waste Water pollution