Carbonic maceration
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Carbonic maceration is a
winemaking Winemaking or vinification is the production of wine, starting with the selection of the fruit, its fermentation into alcohol, and the bottling of the finished liquid. The history of wine-making stretches over millennia. The science of wine and ...
technique, often associated with the
French wine French wine is produced all throughout France, in quantities between 50 and 60 million hectolitres per year, or 7–8 billion bottles. France is one of the largest wine producers in the world, along with Italian, Spanish, and Amer ...
region of
Beaujolais Beaujolais ( , ) is a French ''Appellation d'Origine Contrôlée'' (AOC) wine generally made of the Gamay grape, which has a thin skin and is low in tannins. Like most AOC wines they are not labeled varietally. Whites from the region, which mak ...
, in which whole
grapes A grape is a fruit, botanically a berry, of the deciduous woody vines of the flowering plant genus ''Vitis''. Grapes are a non- climacteric type of fruit, generally occurring in clusters. The cultivation of grapes began perhaps 8,000 years ago, ...
are
fermented Fermentation is a metabolic process that produces chemical changes in organic substrates through the action of enzymes. In biochemistry, it is narrowly defined as the extraction of energy from carbohydrates in the absence of oxygen. In food p ...
in a
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is trans ...
rich environment before crushing. Conventional
alcoholic fermentation Ethanol fermentation, also called alcoholic fermentation, is a biological process which converts sugars such as glucose, fructose, and sucrose into cellular energy, producing ethanol and carbon dioxide as by-products. Because yeasts perform this ...
involves crushing the grapes to free the juice and pulp from the skin with
yeast Yeasts are eukaryotic, single-celled microorganisms classified as members of the fungus kingdom. The first yeast originated hundreds of millions of years ago, and at least 1,500 species are currently recognized. They are estimated to constit ...
serving to convert sugar into
ethanol Ethanol (abbr. EtOH; also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound. It is an alcohol with the chemical formula . Its formula can be also written as or (an ethyl group linked to a ...
. Carbonic maceration ferments most of the juice while it is still inside the grape, although grapes at the bottom of the vessel are crushed by
gravity In physics, gravity () is a fundamental interaction which causes mutual attraction between all things with mass or energy. Gravity is, by far, the weakest of the four fundamental interactions, approximately 1038 times weaker than the stro ...
and undergo conventional fermentation. The resulting
wine Wine is an alcoholic drink typically made from fermented grapes. Yeast consumes the sugar in the grapes and converts it to ethanol and carbon dioxide, releasing heat in the process. Different varieties of grapes and strains of yeasts are m ...
is fruity with very low
tannin Tannins (or tannoids) are a class of astringent, polyphenolic biomolecules that bind to and precipitate proteins and various other organic compounds including amino acids and alkaloids. The term ''tannin'' (from Anglo-Norman ''tanner'' ...
s. It is ready to drink quickly but lacks the structure for long-term aging. In extreme cases such as
Beaujolais nouveau Beaujolais nouveau ( , ) is a red wine made from Gamay grapes produced in the Beaujolais region of France. It is a '' vin de primeur'', fermented for just a few weeks before being released for sale on the third Thursday of November. Distributo ...
, the period between picking and bottling can be less than six weeks. During carbonic maceration, an
anaerobic Anaerobic means "living, active, occurring, or existing in the absence of free oxygen", as opposed to aerobic which means "living, active, or occurring only in the presence of oxygen." Anaerobic may also refer to: * Anaerobic adhesive, a bonding a ...
environment is created by pumping carbon dioxide into a sealed container filled with whole grape clusters. The carbon dioxide gas
permeate In physics and engineering, permeation (also called imbuing) is the penetration of a permeate (a fluid such as a liquid, gas, or vapor) through a solid. It is directly related to the concentration gradient of the permeate, a material's intrins ...
s through the grape skins and begins to stimulate fermentation at an
intracellular This glossary of biology terms is a list of definitions of fundamental terms and concepts used in biology, the study of life and of living organisms. It is intended as introductory material for novices; for more specific and technical definitions ...
level. The entire process takes place inside each intact berry. Ethanol is produced as a by-product of this process but studies have shown that other unique chemical reactions take place that have a distinctive effect on the wine.


History

The process of carbonic maceration occurs naturally in a partial state without deliberate intervention and has occurred in some form throughout history. If grapes are stored in a closed container, the force of gravity will crush those at the bottom, releasing grape juice. Ambient yeasts present on the grape skins will interact with the sugars in the grape juice to start conventional ethanol fermentation. Carbon dioxide is released as a by-product and, being denser than
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as ...
, will push out the oxygen through any permeable surface (such as slight gaps between wood planks), creating a mostly anaerobic environment for the uncrushed grape clusters to go through carbonic maceration. Some of the earliest documented studies of the process were conducted by the French scientist Louis Pasteur, who noted in 1872 that grapes contained in an oxygen-rich environment before crushing and fermentation produced wines of different flavors than grapes produced in a carbon dioxide-rich environment. This was because the fermentation process had already started within the individual grape clusters before yeasts were introduced during conventional fermentation.J. Robinson (ed) ''"The Oxford Companion to Wine"'' Third Edition pg 138 Oxford University Press 2006


Wine production

The use of carbonic maceration is closely associated with the production of
Beaujolais nouveau Beaujolais nouveau ( , ) is a red wine made from Gamay grapes produced in the Beaujolais region of France. It is a '' vin de primeur'', fermented for just a few weeks before being released for sale on the third Thursday of November. Distributo ...
wine from the
Gamay Gamay is a purple-colored grape variety used to make red wines, most notably grown in Beaujolais and in the Loire Valley around Tours. Its full name is Gamay Noir à Jus Blanc. It is a very old cultivar, mentioned as long ago as the 15th centu ...
grape in the Beaujolais region and some wines in the Rioja Alavesa and
Jumilla Jumilla () is a town and a municipality in southeastern Spain. It is located in the north east of the Region of Murcia, close to the towns of Cieza and Yecla. According to the 2018 census, the town population was 25,547. Geography The municip ...
areas of
Spain , image_flag = Bandera de España.svg , image_coat = Escudo de España (mazonado).svg , national_motto = ''Plus ultra'' (Latin)(English: "Further Beyond") , national_anthem = (English: "Royal March") , i ...
. This grape lends itself well to the production of simple, fruity wines and Beaujolais winemakers have been able to create a unique identity based on this distinctive style. Producers in other parts of
France France (), officially the French Republic ( ), is a country primarily located in Western Europe. It also comprises of overseas regions and territories in the Americas and the Atlantic, Pacific and Indian Oceans. Its metropolitan area ...
and in the
New World The term ''New World'' is often used to mean the majority of Earth's Western Hemisphere, specifically the Americas."America." ''The Oxford Companion to the English Language'' (). McArthur, Tom, ed., 1992. New York: Oxford University Press, p. ...
have frequently utilized carbonic maceration for their own Gamay production, or with other
grape varieties This list of grape varieties includes cultivated grapes, whether used for wine, or eating as a table grape, fresh or dried (raisin, currant, sultana). For a complete list of all grape species including those unimportant to agriculture, see Viti ...
. Winemakers in the
Languedoc The Province of Languedoc (; , ; oc, Lengadòc ) is a former province of France. Most of its territory is now contained in the modern-day region of Occitanie in Southern France. Its capital city was Toulouse. It had an area of approximately ...
and
Rhône wine The Rhône wine region in Southern France is situated in the Rhône valley and produces numerous wines under various ''Appellation d'origine contrôlée'' (AOC) designations. The region's major appellation in production volume is Côtes du Rhôn ...
regions will sometimes employ the technique on coarse and tannic grapes like
Carignan Carignan (also known as Mazuelo, Bovale Grande, Cariñena, Carinyena, Samsó, Carignane, and Carignano) is a red grape variety of Spanish origin that is more commonly found in French wine but is widely planted throughout the western Mediterra ...
, especially if they are to be blended with other varieties. In California, the process is sometimes used with
Valdiguié Valdiguié is a red wine grape grown primarily in the Languedoc-Roussillon region of southern France, where it is generally known by the alias Gros Auxerrois. In California it has been known as Napa Gamay or Gamay 15. Until 1980 Napa Gamay was b ...
grapes, producing what is labeled a "
Nouveau A ''nouveau'' ( ), or ''vin (de) primeur'', is a wine which may be sold in the same year in which it was harvested. The most widely exported ''nouveau'' wine is French wine Beaujolais ''nouveau'' which is released on the third Thursday of N ...
" wine. The process is almost always used in conjunction with red wine production since some of the flavor compounds produced by volatile
phenols In organic chemistry, phenols, sometimes called phenolics, are a class of chemical compounds consisting of one or more hydroxyl groups (— O H) bonded directly to an aromatic hydrocarbon group. The simplest is phenol, . Phenolic compounds are ...
tend to form undesirable flavors with white wine
grape varieties This list of grape varieties includes cultivated grapes, whether used for wine, or eating as a table grape, fresh or dried (raisin, currant, sultana). For a complete list of all grape species including those unimportant to agriculture, see Viti ...
.


Other techniques

Semi-carbonic maceration is the winemaking technique where grapes are put through a short period of carbonic maceration, followed by conventional yeast fermentations. This is the process used in producing Beaujolais nouveau wines. To an extent, most wines were historically treated to some form of semi or partial carbonic fermentation (as noted in the history section above) with the amount depending on the shape and size of the vessel the grapes were stored in before crushing. The deeper the vessel, the greater the proportion of grapes that could be exposed to an anaerobic environment caused by the release of carbon dioxide from the crushed grapes on the bottom.J. Robinson (ed) ''"The Oxford Companion to Wine"'' Third Edition pg 620 Oxford University Press 2006 An alternative name for carbonic maceration is "whole grape fermentation", which is distinct from the process of "whole bunch fermentation" common in the
Burgundy wine Burgundy wine ( or ') is made in the Burgundy region of eastern France, in the valleys and slopes west of the Saône, a tributary of the Rhône. The most famous wines produced here, and those commonly referred to as "Burgundies," are dry red win ...
production of Pinot noir. With "whole bunch fermentation", whole clusters of grapes (including stems) are fermented before being crushed. This builds a large "cap" of grape skins, with pathways created by the stems, allowing juice to flow more evenly through caps, increasing the levels of skin contact, or maceration.J. Robinson (ed) ''"The Oxford Companion to Wine"'' Third Edition pg 767 Oxford University Press 2006


Coffee production

Carbonic maceration techniques (e.g. semi-carbonic maceration) have recently been adapted to coffee processing. The ripe coffee cherries are placed inside a hermetic stainless steel tank and left to undergo an anaerobic fermentation. This fermentation process brings out intense aromas, with a taste profile akin to red wine and whisky. These coffee beans usually produce a full-body cup. Known varieties processed with semi-carbonic maceration are Red and Yellow Catuai. Details of fermentation techniques have recently appeared in various specialty coffee media.Newton, Tany
"How Does Fermentation Affect Coffee Flavour Development?"
'' Perfect Daily Grind'', WWW, 14 July 2017. Retrieved on 2 December 2018.


References

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