Calotypes
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Calotype or talbotype is an early photographic process introduced in 1841 by William Henry Fox Talbot, using
paper Paper is a thin sheet material produced by mechanically or chemically processing cellulose fibres derived from wood, rags, grasses or other vegetable sources in water, draining the water through fine mesh leaving the fibre evenly distribu ...
coated with
silver iodide Silver iodide is an inorganic compound with the formula Ag I. The compound is a bright yellow solid, but samples almost always contain impurities of metallic silver that give a gray coloration. The silver contamination arises because AgI is hi ...
. Paper texture effects in calotype photography limit the ability of this early process to record low contrast details and textures. The term ''calotype'' comes from the
Ancient Greek Ancient Greek includes the forms of the Greek language used in ancient Greece and the ancient world from around 1500 BC to 300 BC. It is often roughly divided into the following periods: Mycenaean Greek (), Dark Ages (), the Archaic pe ...
(), "beautiful", and (), "impression".


The process

Talbot made his first successful camera photographs in 1835 using paper sensitised with
silver chloride Silver chloride is a chemical compound with the chemical formula Ag Cl. This white crystalline solid is well known for its low solubility in water (this behavior being reminiscent of the chlorides of Tl+ and Pb2+). Upon illumination or heat ...
, which darkened in proportion to its exposure to light. This early "photogenic drawing" process was a ''printing-out'' process, i.e., the paper had to be exposed in the camera until the image was fully visible. A very long exposure—typically an hour or more—was required to produce an acceptable negative. In late 1840, Talbot worked out a very different ''developing-out'' process (a concept pioneered by the
daguerreotype Daguerreotype (; french: daguerréotype) was the first publicly available photographic process; it was widely used during the 1840s and 1850s. "Daguerreotype" also refers to an image created through this process. Invented by Louis Daguerre a ...
process introduced in 1839), in which only an extremely faint or completely invisible
latent image {{citations needed, date=November 2015 A latent image is an invisible image produced by the exposure to light of a photosensitive material such as photographic film. When photographic film is developed, the area that was exposed darkens and for ...
had to be produced in the camera, which could be done in a minute or two if the subject was in bright sunlight. The paper, shielded from further exposure to daylight, was then removed from the camera and the latent image was chemically developed into a fully visible image. This major improvement was introduced to the public as the ''calotype'' or ''talbotype'' process in 1841. The light-sensitive
silver halide A silver halide (or silver salt) is one of the chemical compounds that can form between the Chemical element, element silver (Ag) and one of the halogens. In particular, bromine (Br), chlorine (Cl), iodine (I) and fluorine (F) may each combine wi ...
in calotype paper was
silver iodide Silver iodide is an inorganic compound with the formula Ag I. The compound is a bright yellow solid, but samples almost always contain impurities of metallic silver that give a gray coloration. The silver contamination arises because AgI is hi ...
, created by the reaction of
silver nitrate Silver nitrate is an inorganic compound with chemical formula . It is a versatile precursor to many other silver compounds, such as those used in photography. It is far less sensitive to light than the halides. It was once called ''lunar causti ...
with
potassium iodide Potassium iodide is a chemical compound, medication, and dietary supplement. It is a medication used for treating hyperthyroidism, in radiation emergencies, and for protecting the thyroid gland when certain types of radiopharmaceuticals are u ...
. First, "iodised paper" was made by brushing one side of a sheet of high-quality writing paper with a solution of silver nitrate, drying it, dipping it in a solution of potassium iodide, then drying it again. At this stage, the balance of the chemicals was such that the paper was practically insensitive to light and could be stored indefinitely. When wanted for use, the side initially brushed with silver nitrate was now brushed with a "gallo-nitrate of silver" solution consisting of silver nitrate,
acetic acid Acetic acid , systematically named ethanoic acid , is an acidic, colourless liquid and organic compound with the chemical formula (also written as , , or ). Vinegar is at least 4% acetic acid by volume, making acetic acid the main componen ...
and
gallic acid Gallic acid (also known as 3,4,5-trihydroxybenzoic acid) is a trihydroxybenzoic acid with the formula C6 H2( OH)3CO2H. It is classified as a phenolic acid. It is found in gallnuts, sumac, witch hazel, tea leaves, oak bark, and other plants ...
, then lightly blotted and exposed in the camera. Development was effected by brushing on more of the "gallo-nitrate of silver" solution while gently warming the paper. When development was complete, the calotype was rinsed, blotted, then either stabilized by washing it in a solution of
potassium bromide Potassium bromide ( K Br) is a salt, widely used as an anticonvulsant and a sedative in the late 19th and early 20th centuries, with over-the-counter use extending to 1975 in the US. Its action is due to the bromide ion ( sodium bromide is equa ...
, which converted the remaining silver iodide into
silver bromide Silver bromide (AgBr) is a soft, pale-yellow, water-insoluble salt well known (along with other silver halides) for its unusual sensitivity to light. This property has allowed silver halides to become the basis of modern photographic materials. A ...
in a condition such that it would only slightly discolour when exposed to light, or "
fixed Fixed may refer to: * ''Fixed'' (EP), EP by Nine Inch Nails * ''Fixed'', an upcoming 2D adult animated film directed by Genndy Tartakovsky * Fixed (typeface), a collection of monospace bitmap fonts that is distributed with the X Window System * F ...
" in a hot solution of sodium thiosulphate, then known as ''hyposulphite of soda'' and commonly called "hypo", which dissolved the silver iodide and allowed it to be entirely washed out, leaving only the silver particles of the developed image and making the calotype completely insensitive to light. The calotype process produced a
translucent In the field of optics, transparency (also called pellucidity or diaphaneity) is the physical property of allowing light to pass through the material without appreciable scattering of light. On a macroscopic scale (one in which the dimensions ...
original negative image from which multiple positives could be made by simple
contact print A contact print is a photographic image produced from film; sometimes from a film negative, and sometimes from a film positive or paper negative. In a darkroom an exposed and developed piece of film or photographic paper is placed emulsion sid ...
ing. This gave it an important advantage over the daguerreotype process, which produced an opaque original positive that could be duplicated only by copying it with a camera. Although calotype paper could be used to make positive prints from calotype negatives, Talbot's earlier silver chloride paper, commonly called ''salted paper'', was normally used for that purpose. It was simpler and less expensive, and Talbot himself considered the appearance of salted paper prints to be more attractive. The longer exposure required to make a salted print was at worst a minor inconvenience when making a contact print by sunlight. Calotype negatives were often impregnated with wax to improve their transparency and make the grain of the paper less conspicuous in the prints. Talbot is sometimes erroneously credited with introducing the principle of latent image development. The bitumen process used in private experiments by
Nicéphore Niépce Joseph Nicéphore Niépce (; 7 March 1765 – 5 July 1833), commonly known or referred to simply as Nicéphore Niépce, was a French inventor, usually credited with the invention of photography. Niépce developed heliography, a technique he us ...
during the 1820s involved the chemical development of a latent image, as did the widely used daguerreotype process introduced to the public by Niépce's partner and successor
Louis Daguerre Louis-Jacques-Mandé Daguerre ( , ; 18 November 1787 – 10 July 1851) was a French artist and photographer, recognized for his invention of the eponymous daguerreotype process of photography. He became known as one of the fathers of photog ...
in 1839. Talbot was, however, the first to apply it to a paper-based process and to a negative-positive process, thereby pioneering the various developed-out negative-positive processes which have dominated non-electronic photography up to the present.


Popularity

Despite their flexibility and the ease with which they could be made, calotypes did not displace the daguerreotype. In part, this was the result of Talbot having
patent A patent is a type of intellectual property that gives its owner the legal right to exclude others from making, using, or selling an invention for a limited period of time in exchange for publishing an enabling disclosure of the invention."A ...
ed his processes in England and beyond. Unlike Talbot, Daguerre who had been granted a stipend by the French state in exchange for making his process publicly available, did not patent his invention. In Scotland, where the English patent law was not applicable at the time, members of the Edinburgh Calotype Club and other Scottish early photographers successfully adopted the paper-negative photo technology. In
England England is a country that is part of the United Kingdom. It shares land borders with Wales to its west and Scotland to its north. The Irish Sea lies northwest and the Celtic Sea to the southwest. It is separated from continental Europe ...
, the Calotype Society was organized in London around 1847 attracting a dozen enthusiasts. In 1853, twelve years after the introduction of paper-negative photography to the public, Talbot's patent restriction was lifted. In addition, the calotype produced a less clear image than the daguerreotype. The use of paper as a negative meant that the texture and fibers of the paper were visible in prints made from it, leading to an image that was slightly grainy or fuzzy compared to daguerreotypes, which were usually sharp and clear. Nevertheless, calotypes—and the salted paper prints that were made from them—remained popular in the
United Kingdom The United Kingdom of Great Britain and Northern Ireland, commonly known as the United Kingdom (UK) or Britain, is a country in Europe, off the north-western coast of the continental mainland. It comprises England, Scotland, Wales and ...
and on the European continent outside France in the 1850s, especially among the amateur calotypists, who prized the aesthetics of calotypes and also wanted to differentiate from commercial photographers, until the
collodion process The collodion process is an early photographic process. The collodion process, mostly synonymous with the "collodion wet plate process", requires the photographic material to be coated, sensitized, exposed, and developed within the span of about ...
enabled both to make glass negatives combining the sharpness of a daguerreotype with the replicability of a calotype later in the nineteenth century. British photographers also brought the calotype to
India India, officially the Republic of India (Hindi: ), is a country in South Asia. It is the List of countries and dependencies by area, seventh-largest country by area, the List of countries and dependencies by population, second-most populous ...
, where, for example, in 1848,
John McCosh John McCosh or John MacCosh or James McCosh ( Kirkmichael, Ayrshire, 5 March 1805 – 18 January / 16 March 1885) was a Scottish army surgeon who made documentary photographs whilst serving in India and Burma. His photographs during the Second A ...
, a surgeon in the
East India Company The East India Company (EIC) was an English, and later British, joint-stock company founded in 1600 and dissolved in 1874. It was formed to trade in the Indian Ocean region, initially with the East Indies (the Indian subcontinent and Sou ...
, took the first image of the Maharajah Duleep Singh.


See also

*
Albumen print The albumen print, also called albumen silver print, was published in January 1847 by Louis Désiré Blanquart-Evrard, and was the first commercially exploitable method of producing a photographic print on a paper base from a negative. It ...
*
Ambrotype The ambrotype (from grc, ἀμβροτός — “immortal”, and  — “impression”) also known as a collodion positive in the UK, is a positive photograph on glass made by a variant of the wet plate collodion process. Like a p ...
*
Collodion process The collodion process is an early photographic process. The collodion process, mostly synonymous with the "collodion wet plate process", requires the photographic material to be coated, sensitized, exposed, and developed within the span of about ...
*
Daguerreotype Daguerreotype (; french: daguerréotype) was the first publicly available photographic process; it was widely used during the 1840s and 1850s. "Daguerreotype" also refers to an image created through this process. Invented by Louis Daguerre a ...
*
Tintype A tintype, also known as a melainotype or ferrotype, is a photograph made by creating a direct positive on a thin sheet of metal coated with a dark lacquer or enamel and used as the support for the photographic emulsion. Tintypes enjoyed their ...


References


Further reading

* Aronold, H. J. P. ''William Henry Fox Talbot pioneer of photography and man of science.'' London: Hutchinson Benham, 1977. * Baxter, W. R. ''The Calotype familiarly explained'', ''Photography: including the Daguerreotype, Calotype & Chrysotype''. London: H. Renshaw, 1842, 2nd edition. * Buckland, G. ''Fox Talbot & the invention of photography''. Boston: Gootine, London Scholar Press, 1980. *Eder, Josef Maria. ''History of Photography.'' New York: Dover Publications, 1978. Translated by Edward Epstean. * Greene, A. ''Primitive Photography: A Guide to Making Cameras, Lenses, and Calotypes.'' Focal Press, 2002. * Lassam, and Seabourne. ''W H Fox Talbot: Scientist, photographer, classical scholar 1800 – 1877: A further assessment.'' Lacock, 1977. * Marshall, F. A. S. ''Photography: The importance of its applications in preserving pictorial records. Containing a practical description of the Talbotype process.'' London: Hering & Remington; Peterborough, T. Chadwell & J. Clarke, 1855. * Meier, Alf B. ''Basic Photography — a manual for the training of fashion photographers.'' Frankfurt/M.: Jentzen oHG, 1992. * Taylor, Roger, with Larry J. Schaaf
''Impressed by Light: British Photographs from Paper Negatives, 1840–1860.''
New York: The Metropolitan Museum of Art, 2007. Available online, including a biographical dictionary of 500 calotypists.


External links


The Calotype Society (flickr group)''All the Mighty World: The Photographs of Roger Fenton, 1852–1860''
exhibition catalog fully online as PDF from The Metropolitan Museum of Art, which contains material on calotype. * Research databas
''Photographic Exhibitions in Britain, 1839–1865''
which contain
1705 records for calotype
{{photography subject Photographic processes dating from the 19th century Photography in the United Kingdom