California Gulch
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The California Gulch site consists of approximately 18 square miles in Lake County, Colorado. The area includes the city of
Leadville The City of Leadville is a statutory city that is the county seat, the most populous community, and the only incorporated municipality in Lake County, Colorado, United States. The city population was 2,602 at the 2010 census and an estimated ...
, parts of the Leadville Historic Mining District and a section of the
Arkansas River The Arkansas River is a major tributary of the Mississippi River. It generally flows to the east and southeast as it traverses the U.S. states of Colorado, Kansas, Oklahoma, and Arkansas. The river's source basin lies in the western United ...
from the confluence of California Gulch downstream to the confluence of Two-Bit Gulch. The site was listed as a
Superfund Superfund is a United States federal environmental remediation program established by the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA). The program is administered by the Environmental Protection Agency ...
site in 1983.


History

Mining in the Leadville area began in 1859 when prospectors working in the channels of the Arkansas River tributaries discovered gold at the mouth of California Gulch. In April 1860, one of the richest discoveries of placer gold in Colorado was discovered at California Gulch. By 1872, placer mining in California Gulch yielded more than $2,500,000, roughly equivalent to $47,674,478 today. In 1876, piles of sand once considered bothersome to placer gold miners, were discovered to contain lead carbonates and were traced back to California Gulch. This discovery propelled a rush of miners to the area. The town of Leadville was founded a year later by mine owners Horace Austin Warner Tabor and
August Meyer August Robert Meyer (August 20, 1851 – December 1, 1905) was an American mining engineer, founding organizer of Leadville, Colorado, and developed the park and boulevard system for Kansas City, Missouri as first president of the Commission of P ...
. Mining, mineral processing, and smelting in and near Leadville produced gold, silver, lead, copper, manganese, and zinc for more than 130 years. Wastes generated during the mining and ore processing contained metals, such as cadmium, copper, lead, and zinc. These wastes remained on the land surface and migrated through the environment by washing into streams and leaching contaminants into surface water and groundwater. Investigation of the site began in the mid-1980s. California Gulch was designated a Superfund Site in 1983, shortly after the
Environmental Protection Agency A biophysical environment is a biotic and abiotic surrounding of an organism or population, and consequently includes the factors that have an influence in their survival, development, and evolution. A biophysical environment can vary in scale ...
created the program. In 1998, EPA and the state of Colorado signed agreements to provide public access to open space near the Arkansas River. State and local governments purchased more than 2,300 acres of ranch land that serve as wildlife habitat and recreational resources. A soccer complex was built on part of the site in 2009 and in 2013 a 21,000 square foot skate park opened. In 2014, the
Colorado Parks and Wildlife Colorado Parks and Wildlife manages the state parks system and the wildlife of the U.S. state of Colorado. , the division managed the 42 state parks and 307 wildlife areas of Colorado. , the Colorado Natural Areas Program had 93 designated s ...
Commission honored the site with a Gold Medal Trout Waters designation. The designation highlights the Upper Arkansas River's improved water quality and revitalized habitats for trout and other wildlife.


Superfund site

California Gulch is one of the many Superfund sites in Colorado. The Superfund program is responsible for cleaning up contaminated land and responding to environmental emergencies, oil spills and natural disasters in the United States. California Gulch was placed on the National Priorities List (NPL) in 1983 due to health risks associated with people ingesting and touching contaminants from the former mining operations found in soil, sediment, surface water, groundwater, liquid waste, solid waste, and
sludge Sludge is a semi-solid slurry that can be produced from a range of industrial processes, from water treatment, wastewater treatment or on-site sanitation systems. For example, it can be produced as a settled suspension obtained from conventional ...
. A preliminary estimate in 2006 for the damages to aquatic and terrestrial environments was between $53 million and $68 million. The second largest settlement in Colorado history was reached in 2008 when the parties agreed on a $20.5 million natural resource damages settlement. Since the 1850s byproduct materials, such as
tailings In mining, tailings are the materials left over after the process of separating the valuable fraction from the uneconomic fraction ( gangue) of an ore. Tailings are different to overburden, which is the waste rock or other material that ove ...
and
slag Slag is a by-product of smelting ( pyrometallurgical) ores and used metals. Broadly, it can be classified as ferrous (by-products of processing iron and steel), ferroalloy (by-product of ferroalloy production) or non-ferrous/base metals (by-p ...
, were left by mining operations. High levels of heavy metals and mine drainage raised concern of high blood lead levels in residents, particularly in children. This
hazardous waste Hazardous waste is waste that has substantial or potential threats to public health or the environment. Hazardous waste is a type of dangerous goods. They usually have one or more of the following hazardous traits: ignitability, reactivity, cor ...
and low-pH water also reduced
biological diversity Biodiversity or biological diversity is the variety and variability of life on Earth. Biodiversity is a measure of variation at the genetic ('' genetic variability''), species ('' species diversity''), and ecosystem ('' ecosystem diversity'') ...
and caused stress in the
ecosystem An ecosystem (or ecological system) consists of all the organisms and the physical environment with which they interact. These biotic and abiotic components are linked together through nutrient cycles and energy flows. Energy enters the syst ...
, decreasing the trout populations. The most concerning contaminants are
arsenic Arsenic is a chemical element with the symbol As and atomic number 33. Arsenic occurs in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Arsenic is a metalloid. It has various allotropes, b ...
,
cadmium Cadmium is a chemical element with the Symbol (chemistry), symbol Cd and atomic number 48. This soft, silvery-white metal is chemically similar to the two other stable metals in group 12 element, group 12, zinc and mercury (element), mercury. Li ...
,
copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pink ...
,
lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, ...
,
manganese Manganese is a chemical element with the Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of ...
, and
zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
. Since 1995, removal and remedial activities have been conducted through federal, state, and PRP actions to consolidate, contain and control more than 350,000 cubic yards of contaminated soils,
sediments Sediment is a naturally occurring material that is broken down by processes of weathering and erosion, and is subsequently transported by the action of wind, water, or ice or by the force of gravity acting on the particles. For example, sa ...
and mine-processing wastes. Potentially Responsible Parties (PRPs) and the EPA work on the cleanup by conducting drainage controls to prevent acid mine runoff, cleanup of residential properties, reuse of slag, and consolidation and containment of contaminated soils, sediments, and mine-processing wastes. The Yak Treatment Plant was also built and it is still in operation. The EPA divided the site into 12 Operable Units (OUs), with the twelfth OU surrounding the whole NPL site and tests the groundwater conditions. The residential areas of Leadville and Lake County are in OU9. The EPA found concentrations of lead in the soil in some areas that exceeded the soil action levels of 3,500 parts per million, causing risk of
lead poisoning Lead poisoning, also known as plumbism and saturnism, is a type of metal poisoning caused by lead in the body. The brain is the most sensitive. Symptoms may include abdominal pain, constipation, headaches, irritability, memory problems, infertil ...
in the population. EPA completed various Five-Year Reviews with the purpose of evaluating the implementation and performance of the Environmental remedy to determine if it is or will be protective of human health (
public health Public health is "the science and art of preventing disease, prolonging life and promoting health through the organized efforts and informed choices of society, organizations, public and private, communities and individuals". Analyzing the det ...
) and the environment. The last one was published in February 2017. Current actions for long-term protection include assessment of institutional controls for OUs 1, 2, 4 and 10 to guarantee the continue safety levels, implementation of institutional controls for OU-5, possible investigations in OU-3, and updates and implementation of operation and maintenance plans for OUs 5 and 7. The EPA has deleted 9 OUs and proposed to delete several other OUs from the NPL. The EPA and the Colorado Department of Public Health and Environment proposed to delete OUs 4, 5 and 7 from the NPL in August 2014. Despite the risk of exposure being low, Pregnant and nursing women, and young children are encouraged to test their blood-lead levels. Lake County continues to offer free blood-lead testing.


12 operable units

* OU1
Water treatment Water treatment is any process that improves the quality of water to make it appropriate for a specific end-use. The end use may be drinking, industrial water supply, irrigation, river flow maintenance, water recreation or many other uses, inc ...
is ongoing since 1992. * OU2 Zoned for industrial mining and includes the Malta Gulch drainage. EPA deleted OU2 from the Superfund program’s National Priorities List (NPL) in June 2001. This abandoned lab used to be an ore mill from the early 1970's thru 1986. To extract the silver, the ore was pulverized and put through a cyanide leach process. * OU3 Slag has been removed and consolidated into the Arkansas Valley slag pile. Based on current land use, EPA determined that slag does not pose elevated health risks. * OU4 Water diversion channels and settling ponds were constructed to prevent heavy metals from flowing into the surface water. * OU5 Location of historic smelter sites and a Zinc-Lead mill site. “Smelter waste, waste rock, and tailings from the milling process were consolidated and capped with a soil cover on site.” * OU6 Design of the Environmental remediation is ongoing. It includes large improvements on the clean water diversion systems, reduction of the amount of
acid rock drainage In computer science, ACID ( atomicity, consistency, isolation, durability) is a set of properties of database transactions intended to guarantee data validity despite errors, power failures, and other mishaps. In the context of databases, a se ...
(ARD) generated, enhancements on the current ARD collection system and retention ponds, and implementation of land use restrictions to protect engineered remedies and reduce exposure to contaminants that will remain in place. * OU7
ASARCO Asarco LLC (American Smelting and Refining Company) is a mining, smelting, and refining company based in Tucson, Arizona, which mines and processes primarily copper. The company has been a subsidiary of Grupo México since 1999. Its three larg ...
, a PRP, consolidated and capped this tailings pile in 2002. * OU8 EPA deleted OU8 from the NPL in January 2010 after the removal of tailings, non-residential soils and stabilizing a channel in 2002 by a PRP. * OU9 Located in the residential areas of Leadville and Lake County. EPA found concentrations of lead in the soil in some areas of this OU exceeded the soil action levels of 3,500 parts per million, causing risk of lead contamination in the population. In the mid and late 1990s, 2 programs were launched in Leadville and Lake County respectively with the goal of reducing children's exposure to lead and to educate the community about lead. Performance goals for the remedy were met in 2006. In 2009, EPA completed soil sampling and remediation for property owners that responded to a final call. EPA deleted OU9 from the NPL in September 2011. * OU10 Zoned for industrial mining, it includes part of the Oregon Gulch drainage and the Oregon Gulch Tailing Impoundment. EPA deleted this OU from the NPL in April 2001. * OU11 Located by the Arkansas River. EPA signed a Record of Decision in 2005 and completed field work in 2010. EPA is still monitoring and maintaining the reclaimed areas until the revegetation is deemed mature and self-sustaining. * OU12 Monitoring of the surface and groundwater quality of this operable unit is ongoing. Remedy also includes a technical impracticability waiver for specific action levels and institutional controls.


Hazards

According to the EPA, the Current Human Exposure status of the California Gulch site is considered to be Not Under Control. Operable Unit 12, responsible for Sitewide Surface and Groundwater Quality, is currently in the remedial action phase of cleanup. This phase includes construction or implementation of the project design, but not complete cleanup. In order for the human exposure status of the site to be considered under control, contamination levels must be safe and controls must be in place to prevent human exposure. Since the area is a major water supply to surrounding homes and businesses, monitoring of lead levels in the groundwater is currently ongoing and thus far indicates that contaminant levels have declined or remained stable. Although risk may be low, blood lead levels are a major concern, especially for pregnant women, nursing mothers, and children as contaminants can cause a variety of adverse health effects such as cell toxicity or neurodevelopmental defects. As a result, current blood-lead testing, outreach and education programs are being implemented in the Lake County area. The next step in the cleanup process is to conduct a 5-year review to determine the success of the current plan in protecting human health and the environment.


Leadville status

The population in Leadville has been relatively stable for the last 30 years. Since 1983, several residential areas were able to be removed from the Superfund site designation due to the ongoing cleanup by the EPA. Residents were relieved to no longer be overshadowed by the Superfund stigma. Real estate values have continued to increase, which is in sync with the market in Colorado. According to Trulia, Leadville has seen an increase of $46,000 (26%) in the median home price in the last year. Similarly, in the last year the price per square foot has increased from $131 to $188. These statistics indicate that the spill has not had a significant adverse impact on the growth for Leadville; however, it also highlights the need for ongoing monitoring and sustainable solutions for existing and expanding residents. The Arkansas River was named a “gold medal” trout stream in January 2014. The designation significantly helped tourism revenue for the town. Guides reported a 25% increase in trout guided tours after the designation. Even locals who used to overlook the Arkansas river for fishing, now enjoy what is now the longest segment of Gold Medal trout water in CO. The Denver Post quoted Stu Pappenfort, a river ranger with the Arkansas Headwaters Recreation Area, as saying, “When I was a kid and we used to come out here fishing, we skipped over the Arkansas and went to the Taylor and the Gunnison. The heavy metals really impacted the size of the fish. There was a good number of them, but not the ones you wanted to hold up in the picture. So we skipped over it.” As a result of the clean up efforts and the Gold Medal designation, there were over 100,000 anglers fishing the Arkansas between Leadville and Parkdale in 2012.


References

{{Coord, 39, 13, 27.96, N, 106, 20, 58.09, W, display=title Geography of Lake County, Colorado Mining in Colorado Superfund sites in Colorado