Bromo(tetrahydrothiophene)gold(I)
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Bromo(tetrahydrothiophene)gold(I) is a
coordination complex A coordination complex consists of a central atom or ion, which is usually metallic and is called the ''coordination centre'', and a surrounding array of bound molecules or ions, that are in turn known as '' ligands'' or complexing agents. ...
of
gold Gold is a chemical element with the symbol Au (from la, aurum) and atomic number 79. This makes it one of the higher atomic number elements that occur naturally. It is a bright, slightly orange-yellow, dense, soft, malleable, and ductile me ...
. It is related to the more commonly used
chloro(tetrahydrothiophene)gold(I) Chloro(tetrahydrothiophene)gold(I), abbreviated (tht)AuCl, is a coordination complex of gold Gold is a chemical element with the symbol Au (from la, aurum) and atomic number 79. This makes it one of the higher atomic number elements that oc ...
. Similarly, the
tetrahydrothiophene Tetrahydrothiophene is an organosulfur compound with the formula (CH2)4S. The molecule consists of a five-membered saturated ring with four methylene groups and a sulfur atom. It is the saturated analog of thiophene. It is a volatile, colorles ...
ligand is labile and is readily substituted with other stronger ligands, to give linear gold bromide complexes. This compound may be prepared by reaction of tetrabromoauric acid (formed from tetrachloroauric acid and hydrobromic acid) with
tetrahydrothiophene Tetrahydrothiophene is an organosulfur compound with the formula (CH2)4S. The molecule consists of a five-membered saturated ring with four methylene groups and a sulfur atom. It is the saturated analog of thiophene. It is a volatile, colorles ...
.


References

{{sulfur compounds Gold(I) compounds Bromo complexes Thiolanes Gold–halogen compounds Gold–sulfur compounds