Bose–Einstein condensate
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In condensed matter physics, a Bose–Einstein condensate (BEC) is a state of matter that is typically formed when a gas of bosons at very low
densities Density (volumetric mass density or specific mass) is the substance's mass per unit of volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' can also be used. Mathematicall ...
is cooled to
temperature Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measured with a thermometer. Thermometers are calibrated in various temperature scales that historically have relied o ...
s very close to absolute zero (−273.15 °C or −459.67 °F). Under such conditions, a large fraction of bosons occupy the lowest
quantum state In quantum physics, a quantum state is a mathematical entity that provides a probability distribution for the outcomes of each possible measurement on a system. Knowledge of the quantum state together with the rules for the system's evolution i ...
, at which point microscopic quantum mechanical phenomena, particularly wavefunction interference, become apparent macroscopically. A BEC is formed by cooling a gas of extremely low density (about 100,000 times less dense than normal air) to ultra-low temperatures. This state was first predicted, generally, in 1924–1925 by
Albert Einstein Albert Einstein ( ; ; 14 March 1879 – 18 April 1955) was a German-born theoretical physicist, widely acknowledged to be one of the greatest and most influential physicists of all time. Einstein is best known for developing the theor ...
following and crediting a pioneering paper by Satyendra Nath Bose on the new field now known as quantum statistics. In 1995, the Bose-Einstein condensate was created by Eric Cornell and
Carl Wieman Carl Edwin Wieman (born March 26, 1951) is an American physicist and educationist at Stanford University, and currently the A.D White Professor at Large at Cornell University. In 1995, while at the University of Colorado Boulder, he and Eric All ...
of the University of Colorado at Boulder using
rubidium Rubidium is the chemical element with the symbol Rb and atomic number 37. It is a very soft, whitish-grey solid in the alkali metal group, similar to potassium and caesium. Rubidium is the first alkali metal in the group to have a density higher ...
atoms; later that year, Wolfgang Ketterle of MIT produced a BEC using
sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable ...
atoms. In 2001 Cornell, Wieman and Ketterle shared the
Nobel Prize in Physics ) , image = Nobel Prize.png , alt = A golden medallion with an embossed image of a bearded man facing left in profile. To the left of the man is the text "ALFR•" then "NOBEL", and on the right, the text (smaller) "NAT•" then " ...
"for the achievement of Bose-Einstein condensation in dilute gases of alkali atoms, and for early fundamental studies of the properties of the condensates."


History

Bose first sent a paper to Einstein on the quantum statistics of light quanta (now called
photon A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they alwa ...
s), in which he derived Planck's quantum radiation law without any reference to classical physics. Einstein was impressed, translated the paper himself from English to German and submitted it for Bose to the ''
Zeitschrift für Physik ''Zeitschrift für Physik'' (English: ''Journal for Physics'') is a defunct series of German peer-reviewed physics journals established in 1920 by Springer Berlin Heidelberg. The series stopped publication in 1997, when it merged with other jour ...
'', which published it in 1924. (The Einstein manuscript, once believed to be lost, was found in a library at
Leiden University Leiden University (abbreviated as ''LEI''; nl, Universiteit Leiden) is a public research university in Leiden, Netherlands. The university was founded as a Protestant university in 1575 by William, Prince of Orange, as a reward to the city o ...
in 2005.) Einstein then extended Bose's ideas to matter in two other papers. The result of their efforts is the concept of a Bose gas, governed by Bose–Einstein statistics, which describes the statistical distribution of identical particles with
integer An integer is the number zero (), a positive natural number (, , , etc.) or a negative integer with a minus sign ( −1, −2, −3, etc.). The negative numbers are the additive inverses of the corresponding positive numbers. In the languag ...
spin, now called bosons. Bosons, particles that include the
photon A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are massless, so they alwa ...
as well as
atom Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas, a ...
s such as
helium-4 Helium-4 () is a stable isotope of the element helium. It is by far the more abundant of the two naturally occurring isotopes of helium, making up about 99.99986% of the helium on Earth. Its nucleus is identical to an alpha particle, and cons ...
(), are allowed to share a quantum state. Einstein proposed that cooling bosonic atoms to a very low temperature would cause them to fall (or "condense") into the lowest accessible
quantum state In quantum physics, a quantum state is a mathematical entity that provides a probability distribution for the outcomes of each possible measurement on a system. Knowledge of the quantum state together with the rules for the system's evolution i ...
, resulting in a new form of matter. In 1938, Fritz London proposed the BEC as a mechanism for superfluidity in and
superconductivity Superconductivity is a set of physical properties observed in certain materials where electrical resistance vanishes and magnetic flux fields are expelled from the material. Any material exhibiting these properties is a superconductor. Unlike ...
. The quest to produce a Bose–Einstein condensate in the laboratory was stimulated by a paper published in 1976 by two Program Directors at the National Science Foundation (William Stwalley and Lewis Nosanow). This led to the immediate pursuit of the idea by four independent research groups; these were led by Isaac Silvera (
University of Amsterdam The University of Amsterdam (abbreviated as UvA, nl, Universiteit van Amsterdam) is a public research university located in Amsterdam, Netherlands. The UvA is one of two large, publicly funded research universities in the city, the other being ...
), Walter Hardy (
University of British Columbia The University of British Columbia (UBC) is a public research university with campuses near Vancouver and in Kelowna, British Columbia. Established in 1908, it is British Columbia's oldest university. The university ranks among the top thr ...
), Thomas Greytak (
Massachusetts Institute of Technology The Massachusetts Institute of Technology (MIT) is a private land-grant research university in Cambridge, Massachusetts. Established in 1861, MIT has played a key role in the development of modern technology and science, and is one of th ...
) and David Lee (
Cornell University Cornell University is a private statutory land-grant research university based in Ithaca, New York. It is a member of the Ivy League. Founded in 1865 by Ezra Cornell and Andrew Dickson White, Cornell was founded with the intention to tea ...
). On 5 June 1995, the first gaseous condensate was produced by Eric Cornell and
Carl Wieman Carl Edwin Wieman (born March 26, 1951) is an American physicist and educationist at Stanford University, and currently the A.D White Professor at Large at Cornell University. In 1995, while at the University of Colorado Boulder, he and Eric All ...
at the University of Colorado at Boulder
NIST The National Institute of Standards and Technology (NIST) is an agency of the United States Department of Commerce whose mission is to promote American innovation and industrial competitiveness. NIST's activities are organized into physical sci ...
JILA lab, in a gas of
rubidium Rubidium is the chemical element with the symbol Rb and atomic number 37. It is a very soft, whitish-grey solid in the alkali metal group, similar to potassium and caesium. Rubidium is the first alkali metal in the group to have a density higher ...
atoms cooled to 170 nanokelvins (nK). Shortly thereafter, Wolfgang Ketterle at MIT produced a Bose–Einstein Condensate in a gas of
sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable ...
atoms. For their achievements Cornell, Wieman, and Ketterle received the 2001
Nobel Prize in Physics ) , image = Nobel Prize.png , alt = A golden medallion with an embossed image of a bearded man facing left in profile. To the left of the man is the text "ALFR•" then "NOBEL", and on the right, the text (smaller) "NAT•" then " ...
. These early studies founded the field of ultracold atoms, and hundreds of research groups around the world now routinely produce BECs of dilute atomic vapors in their labs. Since 1995, many other atomic species have been condensed, and BECs have also been realized using molecules, quasi-particles, and photons.


Critical temperature

This transition to BEC occurs below a critical temperature, which for a uniform
three-dimensional Three-dimensional space (also: 3D space, 3-space or, rarely, tri-dimensional space) is a geometric setting in which three values (called '' parameters'') are required to determine the position of an element (i.e., point). This is the inform ...
gas consisting of non-interacting particles with no apparent internal degrees of freedom is given by: :T_=\left(\frac\right)^\frac \approx 3.3125 \ \frac where: : Interactions shift the value and the corrections can be calculated by mean-field theory. This formula is derived from finding the gas degeneracy in the Bose gas using Bose–Einstein statistics.


Derivation


Ideal Bose gas

For an ideal Bose gas we have the equation of state: :\frac=\fracg_(f)+\frac\frac where v=V/N is the per particle volume, \lambda the thermal wavelength, f the
fugacity In chemical thermodynamics, the fugacity of a real gas is an effective partial pressure which replaces the mechanical partial pressure in an accurate computation of the chemical equilibrium constant. It is equal to the pressure of an ideal gas whic ...
and :g_\alpha (f)=\sum \limits_^\infty \frac It is noticeable that g_ is a monotonically growing function of f in f \in , 1/math>, which are the only values for which the series converge. Recognizing that the second term on the right-hand side contains the expression for the average occupation number of the fundamental state \langle n_0 \rangle, the equation of state can be rewritten as :\frac=\fracg_(f)+\frac \Leftrightarrow \frac\lambda^3=\frac-g_(f) Because the left term on the second equation must always be positive, \frac>g_(f) and because g_(f)\le g_(1), a stronger condition is :\frac>g_(1) which defines a transition between a gas phase and a condensed phase. On the critical region it is possible to define a critical temperature and thermal wavelength: :\lambda_c^3=g_(1)v=\zeta(3/2)v :T_c=\frac recovering the value indicated on the previous section. The critical values are such that if T or \lambda >\lambda_c we are in the presence of a Bose–Einstein condensate. Understanding what happens with the fraction of particles on the fundamental level is crucial. As so, write the equation of state for f=1, obtaining :\frac=1-\left(\frac\right)^3 and equivalently \frac=1-\left(\frac\right)^. So, if T\ll T_c the fraction \frac \approx 1 and if T \gg T_c the fraction \frac \approx 0. At temperatures near to absolute 0, particles tend to condensate in the fundamental state, which is the state with momentum \vec=0.


Models


Bose Einstein's non-interacting gas

Consider a collection of ''N'' non-interacting particles, which can each be in one of two
quantum state In quantum physics, a quantum state is a mathematical entity that provides a probability distribution for the outcomes of each possible measurement on a system. Knowledge of the quantum state together with the rules for the system's evolution i ...
s, , 0\rangle and , 1\rangle. If the two states are equal in energy, each different configuration is equally likely. If we can tell which particle is which, there are 2^N different configurations, since each particle can be in , 0\rangle or , 1\rangle independently. In almost all of the configurations, about half the particles are in , 0\rangle and the other half in , 1\rangle. The balance is a statistical effect: the number of configurations is largest when the particles are divided equally. If the particles are indistinguishable, however, there are only ''N''+1 different configurations. If there are ''K'' particles in state , 1\rangle, there are particles in state , 0\rangle. Whether any particular particle is in state , 0\rangle or in state , 1\rangle cannot be determined, so each value of ''K'' determines a unique quantum state for the whole system. Suppose now that the energy of state , 1\rangle is slightly greater than the energy of state , 0\rangle by an amount ''E''. At temperature ''T'', a particle will have a lesser probability to be in state , 1\rangle by e^. In the distinguishable case, the particle distribution will be biased slightly towards state , 0\rangle. But in the indistinguishable case, since there is no statistical pressure toward equal numbers, the most-likely outcome is that most of the particles will collapse into state , 0\rangle. In the distinguishable case, for large ''N'', the fraction in state , 0\rangle can be computed. It is the same as flipping a coin with probability proportional to ''p'' = exp(−''E''/''T'') to land tails. In the indistinguishable case, each value of ''K'' is a single state, which has its own separate Boltzmann probability. So the probability distribution is exponential: :\, P(K)= C e^ = C p^K. For large ''N'', the normalization constant ''C'' is . The expected total number of particles not in the lowest energy state, in the limit that N\rightarrow \infty, is equal to : \sum_ C p^n=p/(1-p) It does not grow when ''N'' is large; it just approaches a constant. This will be a negligible fraction of the total number of particles. So a collection of enough Bose particles in thermal equilibrium will mostly be in the ground state, with only a few in any excited state, no matter how small the energy difference. Consider now a gas of particles, which can be in different momentum states labeled , k\rangle. If the number of particles is less than the number of thermally accessible states, for high temperatures and low densities, the particles will all be in different states. In this limit, the gas is classical. As the density increases or the temperature decreases, the number of accessible states per particle becomes smaller, and at some point, more particles will be forced into a single state than the maximum allowed for that state by statistical weighting. From this point on, any extra particle added will go into the ground state. To calculate the transition temperature at any density, integrate, over all momentum states, the expression for maximum number of excited particles, : :\, N = V \int = V \int :\, p(k)= e^. When the integral (also known as Bose–Einstein integral) is evaluated with factors of k_B and ℏ restored by dimensional analysis, it gives the critical temperature formula of the preceding section. Therefore, this integral defines the critical temperature and particle number corresponding to the conditions of negligible
chemical potential In thermodynamics, the chemical potential of a species is the energy that can be absorbed or released due to a change of the particle number of the given species, e.g. in a chemical reaction or phase transition. The chemical potential of a speci ...
\mu. In Bose–Einstein statistics distribution, \mu is actually still nonzero for BECs; however, \mu is less than the ground state energy. Except when specifically talking about the ground state, \mu can be approximated for most energy or momentum states as \mu \approx 0.


Bogoliubov theory for weakly interacting gas

Nikolay Bogoliubov considered perturbations on the limit of dilute gas, finding a finite pressure at zero temperature and positive chemical potential. This leads to corrections for the ground state. The Bogoliubov state has pressure (''T'' = 0): P = gn^2/2. The original interacting system can be converted to a system of non-interacting particles with a dispersion law.


Gross–Pitaevskii equation

In some simplest cases, the state of condensed particles can be described with a nonlinear Schrödinger equation, also known as Gross–Pitaevskii or Ginzburg–Landau equation. The validity of this approach is actually limited to the case of ultracold temperatures, which fits well for the most alkali atoms experiments. This approach originates from the assumption that the state of the BEC can be described by the unique wavefunction of the condensate \psi(\vec). For a system of this nature, , \psi(\vec), ^2 is interpreted as the particle density, so the total number of atoms is N=\int d\vec, \psi(\vec), ^2 Provided essentially all atoms are in the condensate (that is, have condensed to the ground state), and treating the bosons using mean-field theory, the energy (E) associated with the state \psi(\vec) is: :E=\int d\vec\left \nabla\psi(\vec), ^2+V(\vec), \psi(\vec), ^2+\fracU_0, \psi(\vec), ^4\right/math> Minimizing this energy with respect to infinitesimal variations in \psi(\vec), and holding the number of atoms constant, yields the Gross–Pitaevski equation (GPE) (also a non-linear
Schrödinger equation The Schrödinger equation is a linear partial differential equation that governs the wave function of a quantum-mechanical system. It is a key result in quantum mechanics, and its discovery was a significant landmark in the development of th ...
): :i\hbar\frac = \left(-\frac+V(\vec)+U_0, \psi(\vec), ^2\right)\psi(\vec) where: : In the case of zero external potential, the dispersion law of interacting Bose–Einstein-condensed particles is given by so-called Bogoliubov spectrum (for \ T= 0): : = \sqrt The Gross-Pitaevskii equation (GPE) provides a relatively good description of the behavior of atomic BEC's. However, GPE does not take into account the temperature dependence of dynamical variables, and is therefore valid only for \ T= 0. It is not applicable, for example, for the condensates of excitons, magnons and photons, where the critical temperature is comparable to room temperature.


Numerical solution

The Gross-Pitaevskii equation is a partial differential equation in space and time variables. Usually it does not have analytic solution and different numerical methods, such as split-step Crank-Nicolson and Fourier spectral methods, are used for its solution. There are different Fortran and C programs for its solution for contact interaction and long-range dipolar interaction which can be freely used.


Weaknesses of Gross–Pitaevskii model

The Gross–Pitaevskii model of BEC is a physical approximation valid for certain classes of BECs. By construction, the GPE uses the following simplifications: it assumes that interactions between condensate particles are of the contact two-body type and also neglects anomalous contributions to
self-energy In quantum field theory, the energy that a particle has as a result of changes that it causes in its environment defines self-energy \Sigma, and represents the contribution to the particle's energy, or effective mass, due to interactions between ...
. These assumptions are suitable mostly for the dilute three-dimensional condensates. If one relaxes any of these assumptions, the equation for the condensate
wavefunction A wave function in quantum physics is a mathematical description of the quantum state of an isolated quantum system. The wave function is a complex-valued probability amplitude, and the probabilities for the possible results of measurements ...
acquires the terms containing higher-order powers of the wavefunction. Moreover, for some physical systems the amount of such terms turns out to be infinite, therefore, the equation becomes essentially non-polynomial. The examples where this could happen are the Bose–Fermi composite condensates, effectively lower-dimensional condensates, and dense condensates and superfluid clusters and droplets. It is found that one has to go beyond the Gross-Pitaevskii equation. For example, the logarithmic term \psi \ln , \psi, ^2 found in the Logarithmic Schrödinger equation must be added to the Gross-Pitaevskii equation along with a Ginzburg-Sobyanin contribution to correctly determine that the speed of sound scales as the cubic root of pressure for Helium-4 at very low temperatures in close agreement with experiment.


Other

However, it is clear that in a general case the behaviour of Bose–Einstein condensate can be described by coupled evolution equations for condensate density, superfluid velocity and distribution function of elementary excitations. This problem was solved in 1977 by Peletminskii et al. in microscopical approach. The Peletminskii equations are valid for any finite temperatures below the critical point. Years after, in 1985, Kirkpatrick and Dorfman obtained similar equations using another microscopical approach. The Peletminskii equations also reproduce Khalatnikov hydrodynamical equations for superfluid as a limiting case.


Superfluidity of BEC and Landau criterion

The phenomena of superfluidity of a Bose gas and superconductivity of a strongly-correlated Fermi gas (a gas of Cooper pairs) are tightly connected to Bose–Einstein condensation. Under corresponding conditions, below the temperature of phase transition, these phenomena were observed in
helium-4 Helium-4 () is a stable isotope of the element helium. It is by far the more abundant of the two naturally occurring isotopes of helium, making up about 99.99986% of the helium on Earth. Its nucleus is identical to an alpha particle, and cons ...
and different classes of superconductors. In this sense, the superconductivity is often called the superfluidity of Fermi gas. In the simplest form, the origin of superfluidity can be seen from the weakly interacting bosons model.


Experimental observation


Superfluid helium-4

In 1938, Pyotr Kapitsa, John Allen and Don Misener discovered that
helium-4 Helium-4 () is a stable isotope of the element helium. It is by far the more abundant of the two naturally occurring isotopes of helium, making up about 99.99986% of the helium on Earth. Its nucleus is identical to an alpha particle, and cons ...
became a new kind of fluid, now known as a superfluid, at temperatures less than 2.17 K (the lambda point). Superfluid helium has many unusual properties, including zero
viscosity The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the int ...
(the ability to flow without dissipating energy) and the existence of
quantized vortices In physics, a quantum vortex represents a quantized flux circulation of some physical quantity. In most cases, quantum vortices are a type of topological defect exhibited in superfluids and superconductors. The existence of quantum vortices was fi ...
. It was quickly believed that the superfluidity was due to partial Bose–Einstein condensation of the liquid. In fact, many properties of superfluid helium also appear in gaseous condensates created by Cornell, Wieman and Ketterle (see below). Superfluid helium-4 is a liquid rather than a gas, which means that the interactions between the atoms are relatively strong; the original theory of Bose–Einstein condensation must be heavily modified in order to describe it. Bose–Einstein condensation remains, however, fundamental to the superfluid properties of helium-4. Note that helium-3, a fermion, also enters a superfluid phase (at a much lower temperature) which can be explained by the formation of bosonic Cooper pairs of two atoms (see also
fermionic condensate A fermionic condensate or Fermi–Dirac condensate is a superfluid phase formed by fermionic particles at low temperatures. It is closely related to the Bose–Einstein condensate, a superfluid phase formed by bosonic atoms under similar cond ...
).


Dilute atomic gases

The first "pure" Bose–Einstein condensate was created by Eric Cornell,
Carl Wieman Carl Edwin Wieman (born March 26, 1951) is an American physicist and educationist at Stanford University, and currently the A.D White Professor at Large at Cornell University. In 1995, while at the University of Colorado Boulder, he and Eric All ...
, and co-workers at JILA on 5 June 1995. They cooled a dilute vapor of approximately two thousand rubidium-87 atoms to below 170 nK using a combination of
laser cooling Laser cooling includes a number of techniques in which atoms, molecules, and small mechanical systems are cooled, often approaching temperatures near absolute zero. Laser cooling techniques rely on the fact that when an object (usually an atom) ...
(a technique that won its inventors Steven Chu, Claude Cohen-Tannoudji, and
William D. Phillips William Daniel Phillips (born November 5, 1948) is an American physicist. He shared the Nobel Prize in Physics, in 1997, with Steven Chu and Claude Cohen-Tannoudji. Biography Phillips was born to William Cornelius Phillips of Juniata, Pennsylvan ...
the 1997
Nobel Prize in Physics ) , image = Nobel Prize.png , alt = A golden medallion with an embossed image of a bearded man facing left in profile. To the left of the man is the text "ALFR•" then "NOBEL", and on the right, the text (smaller) "NAT•" then " ...
) and magnetic evaporative cooling. About four months later, an independent effort led by Wolfgang Ketterle at MIT condensed sodium-23. Ketterle's condensate had a hundred times more atoms, allowing important results such as the observation of quantum mechanical interference between two different condensates. Cornell, Wieman and Ketterle won the 2001
Nobel Prize in Physics ) , image = Nobel Prize.png , alt = A golden medallion with an embossed image of a bearded man facing left in profile. To the left of the man is the text "ALFR•" then "NOBEL", and on the right, the text (smaller) "NAT•" then " ...
for their achievements. A group led by Randall Hulet at Rice University announced a condensate of
lithium Lithium (from el, λίθος, lithos, lit=stone) is a chemical element with the symbol Li and atomic number 3. It is a soft, silvery-white alkali metal. Under standard conditions, it is the least dense metal and the least dense soli ...
atoms only one month following the JILA work. Lithium has attractive interactions, causing the condensate to be unstable and collapse for all but a few atoms. Hulet's team subsequently showed the condensate could be stabilized by confinement quantum pressure for up to about 1000 atoms. Various isotopes have since been condensed.


Velocity-distribution data graph

In the image accompanying this article, the velocity-distribution data indicates the formation of a Bose–Einstein condensate out of a gas of
rubidium Rubidium is the chemical element with the symbol Rb and atomic number 37. It is a very soft, whitish-grey solid in the alkali metal group, similar to potassium and caesium. Rubidium is the first alkali metal in the group to have a density higher ...
atoms. The false colors indicate the number of atoms at each velocity, with red being the fewest and white being the most. The areas appearing white and light blue are at the lowest velocities. The peak is not infinitely narrow because of the Heisenberg uncertainty principle: spatially confined atoms have a minimum width velocity distribution. This width is given by the curvature of the magnetic potential in the given direction. More tightly confined directions have bigger widths in the ballistic velocity distribution. This anisotropy of the peak on the right is a purely quantum-mechanical effect and does not exist in the thermal distribution on the left. This graph served as the cover design for the 1999 textbook ''Thermal Physics'' by Ralph Baierlein.


Quasiparticles

Bose–Einstein condensation also applies to quasiparticles in solids.
Magnon A magnon is a quasiparticle, a collective excitation of the electrons' spin structure in a crystal lattice. In the equivalent wave picture of quantum mechanics, a magnon can be viewed as a quantized spin wave. Magnons carry a fixed amount of en ...
s, excitons, and polaritons have integer spin which means they are
bosons In particle physics, a boson ( ) is a subatomic particle whose spin quantum number has an integer value (0,1,2 ...). Bosons form one of the two fundamental classes of subatomic particle, the other being fermions, which have odd half-integer spi ...
that can form condensates. Magnons, electron spin waves, can be controlled by a magnetic field. Densities from the limit of a dilute gas to a strongly interacting Bose liquid are possible. Magnetic ordering is the analog of superfluidity. In 1999 condensation was demonstrated in antiferromagnetic , at temperatures as great as 14 K. The high transition temperature (relative to atomic gases) is due to the magnons' small mass (near that of an electron) and greater achievable density. In 2006, condensation in a ferromagnetic yttrium-iron-garnet thin film was seen even at room temperature, with optical pumping. Excitons, electron-hole pairs, were predicted to condense at low temperature and high density by Boer et al., in 1961. Bilayer system experiments first demonstrated condensation in 2003, by Hall voltage disappearance. Fast optical exciton creation was used to form condensates in sub-kelvin in 2005 on. Polariton condensation was first detected for exciton-polaritons in a quantum well microcavity kept at 5 K.


In zero gravity

In June 2020, the
Cold Atom Laboratory The Cold Atom Laboratory (CAL) is an experimental instrument on board the ISS, which launched in 2018. It creates an extremely cold microgravity environment in order to study behaviour of atoms in these conditions. Timeline The CAL was developed ...
experiment on board the
International Space Station The International Space Station (ISS) is the largest Modular design, modular space station currently in low Earth orbit. It is a multinational collaborative project involving five participating space agencies: NASA (United States), Roscosmos ( ...
successfully created a BEC of rubidium atoms and observed them for over a second in free-fall. Although initially just a proof of function, early results showed that, in the microgravity environment of the ISS, about half of the atoms formed into a magnetically insensitive halo-like cloud around the main body of the BEC.


Peculiar properties


Quantized vortices

As in many other systems, vortices can exist in BECs. Vortices can be created, for example, by "stirring" the condensate with lasers, rotating the confining trap, or by rapid cooling across the phase transition. The vortex created will be a quantum vortex with core shape determined by the interactions. Fluid circulation around any point is quantized due to the single-valued nature of the order BEC order parameter or wavefunction, that can be written in the form \psi(\vec)=\phi(\rho,z)e^ where \rho, z and \theta are as in the cylindrical coordinate system, and \ell is the angular quantum number (a.k.a. the "charge" of the vortex). Since the energy of a vortex is proportional to the square of its angular momentum, in trivial topology only \ell=1 vortices can exist in the steady state; Higher-charge vortices will have a tendency to split into \ell=1 vortices, if allowed by the topology of the geometry. An axially symmetric (for instance, harmonic) confining potential is commonly used for the study of vortices in BEC. To determine \phi(\rho,z), the energy of \psi(\vec) must be minimized, according to the constraint \psi(\vec)=\phi(\rho,z)e^. This is usually done computationally, however, in a uniform medium, the following analytic form demonstrates the correct behavior, and is a good approximation: :\phi=\frac\,. Here, n is the density far from the vortex and x=\rho/(\ell \xi), where \xi=1/\sqrt is the healing length of the condensate. A singly charged vortex (\ell=1) is in the ground state, with its energy \epsilon_v given by :\epsilon_v=\pi n \frac\ln\left(1.464\frac\right) where \,b is the farthest distance from the vortices considered.(To obtain an energy which is well defined it is necessary to include this boundary b.) For multiply charged vortices (\ell >1) the energy is approximated by :\epsilon_v\approx \ell^2\pi n \frac\ln\left(\frac\right) which is greater than that of \ell singly charged vortices, indicating that these multiply charged vortices are unstable to decay. Research has, however, indicated they are metastable states, so may have relatively long lifetimes. Closely related to the creation of vortices in BECs is the generation of so-called dark
soliton In mathematics and physics, a soliton or solitary wave is a self-reinforcing wave packet that maintains its shape while it propagates at a constant velocity. Solitons are caused by a cancellation of nonlinear and dispersive effects in the me ...
s in one-dimensional BECs. These topological objects feature a phase gradient across their nodal plane, which stabilizes their shape even in propagation and interaction. Although solitons carry no charge and are thus prone to decay, relatively long-lived dark solitons have been produced and studied extensively.


Attractive interactions

Experiments led by Randall Hulet at Rice University from 1995 through 2000 showed that lithium condensates with attractive interactions could stably exist up to a critical atom number. Quench cooling the gas, they observed the condensate to grow, then subsequently collapse as the attraction overwhelmed the zero-point energy of the confining potential, in a burst reminiscent of a supernova, with an explosion preceded by an implosion. Further work on attractive condensates was performed in 2000 by the JILA team, of Cornell, Wieman and coworkers. Their instrumentation now had better control so they used naturally ''attracting'' atoms of rubidium-85 (having negative atom–atom scattering length). Through Feshbach resonance involving a sweep of the magnetic field causing spin flip collisions, they lowered the characteristic, discrete energies at which rubidium bonds, making their Rb-85 atoms repulsive and creating a stable condensate. The reversible flip from attraction to repulsion stems from quantum interference among wave-like condensate atoms. When the JILA team raised the magnetic field strength further, the condensate suddenly reverted to attraction, imploded and shrank beyond detection, then exploded, expelling about two-thirds of its 10,000 atoms. About half of the atoms in the condensate seemed to have disappeared from the experiment altogether, not seen in the cold remnant or expanding gas cloud.
Carl Wieman Carl Edwin Wieman (born March 26, 1951) is an American physicist and educationist at Stanford University, and currently the A.D White Professor at Large at Cornell University. In 1995, while at the University of Colorado Boulder, he and Eric All ...
explained that under current atomic theory this characteristic of Bose–Einstein condensate could not be explained because the energy state of an atom near absolute zero should not be enough to cause an implosion; however, subsequent mean-field theories have been proposed to explain it. Most likely they formed molecules of two rubidium atoms; energy gained by this bond imparts velocity sufficient to leave the trap without being detected. The process of creation of molecular Bose condensate during the sweep of the magnetic field throughout the Feshbach resonance, as well as the reverse process, are described by the exactly solvable model that can explain many experimental observations.


Current research

Compared to more commonly encountered states of matter, Bose–Einstein condensates are extremely fragile. The slightest interaction with the external environment can be enough to warm them past the condensation threshold, eliminating their interesting properties and forming a normal gas. Nevertheless, they have proven useful in exploring a wide range of questions in fundamental physics, and the years since the initial discoveries by the JILA and MIT groups have seen an increase in experimental and theoretical activity. Examples include experiments that have demonstrated interference between condensates due to
wave–particle duality Wave–particle duality is the concept in quantum mechanics that every particle or quantum entity may be described as either a particle or a wave. It expresses the inability of the classical physics, classical concepts "particle" or "wave" to fu ...
, the study of superfluidity and quantized vortices, the creation of bright matter wave
soliton In mathematics and physics, a soliton or solitary wave is a self-reinforcing wave packet that maintains its shape while it propagates at a constant velocity. Solitons are caused by a cancellation of nonlinear and dispersive effects in the me ...
s from Bose condensates confined to one dimension, and the slowing of light pulses to very low speeds using electromagnetically induced transparency. Vortices in Bose–Einstein condensates are also currently the subject of analogue gravity research, studying the possibility of modeling black holes and their related phenomena in such environments in the laboratory. Experimenters have also realized " optical lattices", where the interference pattern from overlapping lasers provides a periodic potential. These have been used to explore the transition between a superfluid and a Mott insulator, and may be useful in studying Bose–Einstein condensation in fewer than three dimensions, for example the
Tonks–Girardeau gas In physics, a Tonks–Girardeau gas is a Bose gas in which the repulsive interactions between bosonic particles confined to one dimension dominate the system's physics. It is named after physicists Marvin D. Girardeau and Lewi Tonks. It is not a B ...
. Further, the sensitivity of the pinning transition of strongly interacting bosons confined in a shallow one-dimensional optical lattice originally observed by Haller has been explored via a tweaking of the primary optical lattice by a secondary weaker one. Thus for a resulting weak bichromatic optical lattice, it has been found that the pinning transition is robust against the introduction of the weaker secondary optical lattice. Studies of vortices in nonuniform Bose–Einstein condensates as well as excitatons of these systems by the application of moving repulsive or attractive obstacles, have also been undertaken. Within this context, the conditions for order and chaos in the dynamics of a trapped Bose–Einstein condensate have been explored by the application of moving blue and red-detuned laser beams via the time-dependent Gross-Pitaevskii equation. Bose–Einstein condensates composed of a wide range of
isotope Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers ( mass num ...
s have been produced. Cooling fermions to extremely low temperatures has created degenerate gases, subject to the
Pauli exclusion principle In quantum mechanics, the Pauli exclusion principle states that two or more identical particles with half-integer spins (i.e. fermions) cannot occupy the same quantum state within a quantum system simultaneously. This principle was formula ...
. To exhibit Bose–Einstein condensation, the fermions must "pair up" to form bosonic compound particles (e.g.
molecule A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and b ...
s or Cooper pairs). The first molecular condensates were created in November 2003 by the groups of Rudolf Grimm at the
University of Innsbruck The University of Innsbruck (german: Leopold-Franzens-Universität Innsbruck; la, Universitas Leopoldino Franciscea) is a public research university in Innsbruck, the capital of the Austrian federal state of Tyrol, founded on October 15, 1669. ...
,
Deborah S. Jin Deborah Shiu-lan Jin (; November 15, 1968 – September 15, 2016) was an American physicist and fellow with the National Institute of Standards and Technology (NIST); Professor Adjunct, Department of Physics at the University of Colorado; and a ...
at the University of Colorado at Boulder and Wolfgang Ketterle at MIT. Jin quickly went on to create the first
fermionic condensate A fermionic condensate or Fermi–Dirac condensate is a superfluid phase formed by fermionic particles at low temperatures. It is closely related to the Bose–Einstein condensate, a superfluid phase formed by bosonic atoms under similar cond ...
, working with the same system but outside the molecular regime. In 1999, Danish physicist
Lene Hau Lene Vestergaard Hau (; born November 13, 1959) is a Danish physicist and educator. She is the Mallinckrodt Professor of Physics and of Applied Physics at Harvard University. In 1999, she led a Harvard University team who, by use of a Bose–E ...
led a team from
Harvard University Harvard University is a private Ivy League research university in Cambridge, Massachusetts. Founded in 1636 as Harvard College and named for its first benefactor, the Puritan clergyman John Harvard, it is the oldest institution of highe ...
which slowed a beam of light to about 17 meters per second using a superfluid. Hau and her associates have since made a group of condensate atoms recoil from a light pulse such that they recorded the light's phase and amplitude, recovered by a second nearby condensate, in what they term "slow-light-mediated atomic matter-wave amplification" using Bose–Einstein condensates: details are discussed in ''
Nature Nature, in the broadest sense, is the physical world or universe. "Nature" can refer to the phenomena of the physical world, and also to life in general. The study of nature is a large, if not the only, part of science. Although humans are ...
''. Another current research interest is the creation of Bose–Einstein condensates in microgravity in order to use its properties for high precision atom interferometry. The first demonstration of a BEC in weightlessness was achieved in 2008 at a drop tower in Bremen, Germany by a consortium of researchers led by Ernst M. Rasel from Leibniz University Hannover. The same team demonstrated in 2017 the first creation of a Bose–Einstein condensate in space and it is also the subject of two upcoming experiments on the
International Space Station The International Space Station (ISS) is the largest Modular design, modular space station currently in low Earth orbit. It is a multinational collaborative project involving five participating space agencies: NASA (United States), Roscosmos ( ...
. Researchers in the new field of
atomtronics Atomtronics is an emerging type of computing consisting of matter-wave circuits which coherently guide propagating ultra-cold atoms. The systems typically include components analogous to those found in electronic or optical systems, such as beam s ...
use the properties of Bose–Einstein condensates in the emerging quantum technology of matter-wave circuits. In 1970, BECs were proposed by Emmanuel David Tannenbaum for anti-
stealth technology Stealth technology, also termed low observable technology (LO technology), is a sub-discipline of military tactics and passive and active electronic countermeasures, which covers a range of methods used to make personnel, aircraft, ships, su ...
. In 2020, researchers reported the development of superconducting BEC and that there appears to be a "smooth transition between" BEC and Bardeen–Cooper–Shrieffer regimes.


Continuous Bose–Einstein condensation

Limitations of evaporative cooling have restricted atomic BECs to "pulsed" operation, involving a highly inefficient duty cycle that discards more than 99% of atoms to reach BEC. Achieving continuous BEC has been a major open problem of experimental BEC research, driven by the same motivations as continuous optical laser development: high flux, high coherence matter waves produced continuously would enable new sensing applications. Continuous BEC was achieved for the first time in 2022.


Dark matter

P. Sikivie and Q. Yang showed that
cold dark matter In cosmology and physics, cold dark matter (CDM) is a hypothetical type of dark matter. According to the current standard model of cosmology, Lambda-CDM model, approximately 27% of the universe is dark matter and 68% is dark energy, with only a sm ...
axions form a Bose–Einstein condensate by thermalisation because of gravitational self-interactions. Axions have not yet been confirmed to exist. However the important search for them has been greatly enhanced with the completion of upgrades to the Axion Dark Matter Experiment (ADMX) at the University of Washington in early 2018. In 2014, a potential dibaryon was detected at the Jülich Research Center at about 2380 MeV. The center claimed that the measurements confirm results from 2011, via a more replicable method. The particle existed for 10−23 seconds and was named d*(2380). This particle is hypothesized to consist of three up and three down quarks. It is theorized that groups of d* (d-stars) could form Bose–Einstein condensates due to prevailing low temperatures in the early universe, and that BECs made of such hexaquarks with trapped electrons could behave like
dark matter Dark matter is a hypothetical form of matter thought to account for approximately 85% of the matter in the universe. Dark matter is called "dark" because it does not appear to interact with the electromagnetic field, which means it does not ...
.


Isotopes

The effect has mainly been observed on alkaline atoms which have nuclear properties particularly suitable for working with traps. As of 2012, using ultra-low temperatures of 10^ K or below, Bose–Einstein condensates had been obtained for a multitude of isotopes, mainly of
alkali metal The alkali metals consist of the chemical elements lithium (Li), sodium (Na), potassium (K),The symbols Na and K for sodium and potassium are derived from their Latin names, ''natrium'' and ''kalium''; these are still the origins of the names ...
, alkaline earth metal, and
lanthanide The lanthanide () or lanthanoid () series of chemical elements comprises the 15 metallic chemical elements with atomic numbers 57–71, from lanthanum through lutetium. These elements, along with the chemically similar elements scandium and yt ...
atoms (, , , , , , , , , , , , , , and ). Research was finally successful in hydrogen with the aid of the newly developed method of 'evaporative cooling'. In contrast, the superfluid state of below is not a good example, because the interaction between the atoms is too strong. Only 8% of atoms are in the ground state of the trap near absolute zero, rather than the 100% of a true condensate. The bosonic behavior of some of these alkaline gases appears odd at first sight, because their nuclei have half-integer total spin. It arises from a subtle interplay of electronic and nuclear spins: at ultra-low temperatures and corresponding excitation energies, the half-integer total spin of the electronic shell and half-integer total spin of the nucleus are coupled by a very weak
hyperfine interaction In atomic physics, hyperfine structure is defined by small shifts in otherwise degenerate energy levels and the resulting splittings in those energy levels of atoms, molecules, and ions, due to electromagnetic multipole interaction between the ...
. The total spin of the atom, arising from this coupling, is an integer lower value. The chemistry of systems at room temperature is determined by the electronic properties, which is essentially fermionic, since room temperature thermal excitations have typical energies much higher than the hyperfine values.


In fiction

* In the 2016 film ''
Spectral ''Spectral'' is a 2016 3D military science fiction, supernatural horror fantasy and action-adventure thriller war film directed by Nic Mathieu. Written by himself, Ian Fried, and George Nolfi from a story by Fried and Mathieu. The film stars J ...
'', the US military battles mysterious enemy creatures fashioned out of Bose–Einstein condensates. * In the 2003 novel '' Blind Lake'', scientists observe sentient life on a planet 51 light-years away using telescopes powered by Bose–Einstein condensate-based quantum computers. * The video game franchise '' Mass Effect'' has cryonic ammunition whose
flavour text Flavor text is text for action figure character backgrounds, video games, playing cards, or within the pages of a role-playing game's rulebook. While appropriate to the product's or game's story concept, it usually has no effect on the mecha ...
describes it as being filled with Bose-Einstein condensates. Upon impact, the bullets rupture and spray super-cold liquid on the enemy.


See also

* Atom laser * Atomic coherence * Bose–Einstein correlations * Bose–Einstein condensation: a network theory approach * Bose–Einstein condensation of quasiparticles * Bose–Einstein statistics *
Cold Atom Laboratory The Cold Atom Laboratory (CAL) is an experimental instrument on board the ISS, which launched in 2018. It creates an extremely cold microgravity environment in order to study behaviour of atoms in these conditions. Timeline The CAL was developed ...
* Electromagnetically induced transparency *
Fermionic condensate A fermionic condensate or Fermi–Dirac condensate is a superfluid phase formed by fermionic particles at low temperatures. It is closely related to the Bose–Einstein condensate, a superfluid phase formed by bosonic atoms under similar cond ...
* Gas in a box * Gross–Pitaevskii equation *
Macroscopic quantum phenomena Macroscopic quantum phenomena are processes showing quantum behavior at the macroscopic scale, rather than at the atomic scale where quantum effects are prevalent. The best-known examples of macroscopic quantum phenomena are superfluidity and s ...
*
Macroscopic quantum self-trapping In quantum mechanics, macroscopic quantum self-trapping is when two Bose-Einstein condensates weakly linked by an energy barrier which particles can tunnel through, nevertheless end up with a higher average number of bosons on one side of the junc ...
*
Slow light Slow light is the propagation of an optical pulse or other modulation of an optical carrier at a very low group velocity. Slow light occurs when a propagating pulse is substantially slowed by the interaction with the medium in which the propagatio ...
* Super-heavy atom *
Superconductivity Superconductivity is a set of physical properties observed in certain materials where electrical resistance vanishes and magnetic flux fields are expelled from the material. Any material exhibiting these properties is a superconductor. Unlike ...
*
Superfluid film Superfluidity is a phenomenon where a fluid, or a fraction of a fluid, loses all its viscosity and can flow without resistance. This article is about thin films of such superfluids. Superfluid helium, for example, forms a 30-nm-thick film on t ...
*
Superfluid helium-4 Superfluid helium-4 is the superfluid form of helium-4, an isotope of the element helium. A superfluid is a state of matter in which matter behaves like a fluid with zero viscosity. The substance, which looks like a normal liquid, flows wit ...
*
Supersolid In condensed matter physics, a supersolid is a spatially ordered material with superfluid properties. In the case of helium-4, it has been conjectured since the 1960s that it might be possible to create a supersolid. Starting from 2017, a defin ...
* Tachyon condensation * Timeline of low-temperature technology * Ultracold atom * Wiener sausage


References


Further reading

* * , * * * * * * . * * . * * * * * . * * * * * C. J. Pethick and H. Smith, ''Bose–Einstein Condensation in Dilute Gases'', Cambridge University Press, Cambridge, 2001. * Lev P. Pitaevskii and S. Stringari, ''Bose–Einstein Condensation'', Clarendon Press, Oxford, 2003. * * Monique Combescot and Shiue-Yuan Shiau, "Excitons and Cooper Pairs: Two Composite Bosons in Many-Body Physics", Oxford University Press ().


External links


Bose–Einstein Condensation 2009 Conference
Bose–Einstein Condensation 2009 – Frontiers in Quantum Gases

General introduction to Bose–Einstein condensation

– for the achievement of Bose–Einstein condensation in dilute gases of alkali atoms, and for early fundamental studies of the properties of the condensates *
Bose–Einstein condensates at JILAAtomcool at Rice UniversityAtom Optics at UQEinstein's manuscript on the Bose–Einstein condensate discovered at Leiden UniversityBose–Einstein condensate on arxiv.orgEasy BEC machine
– information on constructing a Bose–Einstein condensate machine.
Verging on absolute zero – Cosmos Online

Lecture by W Ketterle at MIT in 2001Bose–Einstein Condensation at NIST
NIST The National Institute of Standards and Technology (NIST) is an agency of the United States Department of Commerce whose mission is to promote American innovation and industrial competitiveness. NIST's activities are organized into physical sci ...
resource on BEC {{DEFAULTSORT:Bose-Einstein Condensate Albert Einstein Condensed matter physics Exotic matter Phases of matter Articles containing video clips