Beryllium nitrate
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Beryllium nitrate is an
inorganic compound In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemis ...
with the idealized
chemical formula In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, ...
Be(NO3)2. The formula suggests a salt, but, as for many beryllium compounds, the compound is highly covalent. Little of its chemistry is well known. "When added to water, brown fumes are evolved; when hydrolyzed in sodium hydroxide solution, both nitrate and nitrite ions are produced."


Synthesis and reactions

The straw-colored adduct Be(NO3)2(N2O4) forms upon treatment of beryllium chloride with
dinitrogen tetroxide Dinitrogen tetroxide, commonly referred to as nitrogen tetroxide (NTO), and occasionally (usually among ex-USSR/Russia rocket engineers) as amyl, is the chemical compound N2O4. It is a useful reagent in chemical synthesis. It forms an equilibrium ...
: :BeCl2 + 3N2O4 → Be(NO3)2(N2O4) + 2NOCl Upon heating, this adduct loses N2O4 and produces colorless Be(NO3)2. Further heating of Be(NO3)2 induces conversion to basic beryllium nitrate, which adopts a structure akin to that for basic berylium acetate. Unlike the basic acetate, with its six lipophilic methyl groups, the basic nitrate is insoluble in most solvents.


References

Beryllium compounds Nitrates {{inorganic-compound-stub