Ammonium ferric citrate
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Ammonium ferric citrate (also known as Ferric Ammonium Citrate or Ammoniacal ferrous citrate) has the formula (NH4)5 e(C6H4O7)2 A distinguishing feature of this compound is that it is very soluble in water, in contrast to ferric citrate which is not very soluble. In its crystal structure each
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of
citric acid Citric acid is an organic compound with the chemical formula HOC(CO2H)(CH2CO2H)2. It is a colorless weak organic acid. It occurs naturally in citrus fruits. In biochemistry, it is an intermediate in the citric acid cycle, which occurs in ...
has lost four protons. The deprotonated hydroxyl group and two of the carboxylate groups ligate to the ferric center, while the third carboxylate group coordinates with the ammonium.


Uses

Ammonium ferric citrate has a range of uses, including: * As a food ingredient, it has an
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number 381, and is used as an
acidity regulator Acidity regulators, or pH control agents, are food additives used to change or maintain pH (acidity or basicity). They can be organic or mineral acids, bases, neutralizing agents, or buffering agents. Typical agents include the following acids ...
. Most notably used in the Scottish beverage
Irn-Bru Irn-Bru ( "iron brew", ) is a Scottish carbonated soft drink, often described as "Scotland's other national drink" (after whisky). Introduced in 1901, the drink is produced in Westfield, Cumbernauld, North Lanarkshire, by A.G. Barr of Glasgo ...
. * Water purification * As a reducing agent of metal salts of low activity like gold and
silver Silver is a chemical element with the symbol Ag (from the Latin ', derived from the Proto-Indo-European ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, white, lustrous transition metal, it exhibits the highest electrical ...
* With
potassium ferricyanide Potassium ferricyanide is the chemical compound with the formula K3 e(CN)6 This bright red salt contains the octahedrally coordinated 3−.html" ;"title="e(CN)6sup>3−">e(CN)6sup>3− ion. It is soluble in water and its solution shows some g ...
as part of the
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photographic process * Used in Kligler's Iron Agar (KIA) test to identify
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bacteria by observing their metabolism of different sugars, producing
hydrogen sulfide Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is poisonous, corrosive, and flammable, with trace amounts in ambient atmosphere having a characteristic foul odor of rotten eggs. The under ...
* In medical imaging, ammonium ferric citrate is used as a
contrast medium A contrast agent (or contrast medium) is a substance used to increase the contrast of structures or fluids within the body in medical imaging. Contrast agents absorb or alter external electromagnetism or ultrasound, which is different from radio ...
. * As a
hematinic A hematinic is a nutrient required for the formation of blood cells in the process of hematopoiesis. The main hematinics are iron, B12 Vitamin B12, also known as cobalamin, is a water-soluble vitamin involved in metabolism. It is one of e ...


See also

*
Food additive Food additives are substances added to food to preserve Taste, flavor or enhance taste, appearance, or other sensory qualities. Some additives have been used for centuries as part of an effort to preserve food, for example vinegar (pickling), sal ...
*
List of food additives Food additives are substances added to food to preserve flavor or enhance its taste, appearance, or other qualities. Purposes Additives are used for many purposes but the main uses are: ;Acids : Food acids are added to make flavors "sharper", ...


References

{{DEFAULTSORT:Ammonium Ferric Citrate Ammonium compounds Citrates Iron(III) compounds MRI contrast agents Photographic chemicals Double salts