Aluminium molybdate
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Aluminium molybdate is the
chemical compound A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element ...
Al2(MoO4)3. It forms in certain hydrodesulfurization catalysts when alumina is doped with excess molybdenum. When
molybdates In chemistry a molybdate is a compound containing an oxoanion with molybdenum in its highest oxidation state of 6. Molybdenum can form a very large range of such oxoanions which can be discrete structures or polymeric extended structures, althou ...
are used to inhibit corrosion in aluminum piping, the protective film formed is hydrated aluminum molybdate. Although small quantities of aluminum molybdate form during aluminothermic reduction of molybdia, mechanical activation inhibits their formation. Large-scale samples can be prepared via sol-gel synthesis, and have been proposed for
molybdenum-99 Molybdenum (42Mo) has 33 known isotopes, ranging in atomic mass from 83 to 115, as well as four metastable nuclear isomers. Seven isotopes occur naturally, with atomic masses of 92, 94, 95, 96, 97, 98, and 100. All unstable isotopes of molybdenum ...
storage in
nuclear medicine Nuclear medicine or nucleology is a medical specialty involving the application of radioactive substances in the diagnosis and treatment of disease. Nuclear imaging, in a sense, is " radiology done inside out" because it records radiation emi ...
. The room temperature
crystal structure In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric patterns ...
was refined using
time-of-flight Time of flight (ToF) is the measurement of the time taken by an object, particle or wave (be it acoustic, electromagnetic, etc.) to travel a distance through a medium. This information can then be used to measure velocity or path length, or as a w ...
powder
neutron diffraction Neutron diffraction or elastic neutron scattering is the application of neutron scattering to the determination of the atomic and/or magnetic structure of a material. A sample to be examined is placed in a beam of thermal or cold neutrons to o ...
data. It is
monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic s ...
and
isostructural Isostructural chemical compounds have similar chemical structures. " Isomorphous" when used in the relation to crystal structures is not synonymous: in addition to the same atomic connectivity that characterises isostructural compounds, isomorphous ...
with Fe2(MoO4)3 and Cr2(MoO4)3. At high temperatures, the crystal rearranges to βAl2(MoO4)3, isostructural with scandium tungstate. Aluminum molybdate has a very low
thermal expansion coefficient Thermal expansion is the tendency of matter to change its shape, area, volume, and density in response to a change in temperature, usually not including phase transitions. Temperature is a monotonic function of the average molecular kinetic ...
near room temperature.


References


External links


Aluminium Molybdate MSDS
{{Molybdates Molybdates Aluminium compounds