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Zeolitic
Zeolites are microporous, crystalline aluminosilicate materials commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula ･y where is either a metal ion or H+. These positive ions can be exchanged for others in a contacting electrolyte solution. exchanged zeolites are particularly useful as solid acid catalysts. The term ''zeolite'' was originally coined in 1756 by Swedish mineralogist Axel Fredrik Cronstedt, who observed that rapidly heating a material, believed to have been stilbite, produced large amounts of steam from water that had been adsorbed by the material. Based on this, he called the material ''zeolite'', from the Greek , meaning "to boil" and , meaning "stone". Zeolites occur naturally but are also produced industrially on a large scale. , 253 unique zeolite frameworks have been identified, and over 40 naturally occurring zeolite frameworks are known. Every new zeolite structure that is ob ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Microporous Material
A microporous material is a material containing pores with diameters less than 2 nm. Examples of microporous materials include zeolites and metal-organic frameworks. Porous materials are classified into several kinds by their size. The recommendations of a panel convened by the International Union of Pure and Applied Chemistry (IUPAC) are: See page 1745. *Microporous materials have pore diameters of less than 2 nm. *Mesoporous materials have pore diameters between 2 nm and 50 nm. * Macroporous materials have pore diameters of greater than 50 nm. Micropores may be defined differently in other contexts. For example, in the context of porous aggregations such as soil, micropores are defined as cavities with sizes less than 30 μm. Uses in laboratories Microporous materials are often used in laboratory environments to facilitate contaminant-free exchange of gases. Mold spores, bacteria, and other airborne contaminants will become trapped, while gases ar ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ionic Bond
Ionic bonding is a type of chemical bonding that involves the electrostatic attraction between oppositely charged ions, or between two atoms with sharply different electronegativities, and is the primary interaction occurring in ionic compounds. It is one of the main types of bonding along with covalent bonding and metallic bonding. Ions are atoms (or groups of atoms) with an electrostatic charge. Atoms that gain electrons make negatively charged ions (called anions). Atoms that lose electrons make positively charged ions (called cations). This transfer of electrons is known as electrovalence in contrast to covalence. In the simplest case, the cation is a metal atom and the anion is a nonmetal atom, but these ions can be of a more complex nature, e.g. molecular ions like or . In simpler words, an ionic bond results from the transfer of electrons from a metal to a non-metal in order to obtain a full valence shell for both atoms. It is important to recognize that ''clean'' ion ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sodalite
Sodalite ( ) is a tectosilicate mineral with the formula , with royal blue varieties widely used as an ornamental gemstone. Although massive sodalite samples are opaque, crystals are usually transparent to translucent. Sodalite is a member of the sodalite group with hauyne, nosean, lazurite and tugtupite. First discovered by Europeans in 1811 in the Ilimaussaq intrusive complex in Greenland, sodalite did not become important as an ornamental stone until 1891 when vast deposits of fine material were discovered in Ontario, Canada. Structure The structure of sodalite was first studied by Linus Pauling in 1930. It is a cubic mineral of space group P3n ( space group 218) which consists of an aluminosilicate cage network with Na+ cations and chloride anions in the interframework. (There may be small amounts of other cations and anions instead.) This framework forms a zeolite cage structure. Each unit cell has two cavities, which have almost the same structure as the borate cag ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Truncated Octahedron
In geometry, the truncated octahedron is the Archimedean solid that arises from a regular octahedron by removing six pyramids, one at each of the octahedron's vertices. The truncated octahedron has 14 faces (8 regular hexagons and 6 squares), 36 edges, and 24 vertices. Since each of its faces has point symmetry the truncated octahedron is a 6- zonohedron. It is also the Goldberg polyhedron GIV(1,1), containing square and hexagonal faces. Like the cube, it can tessellate (or "pack") 3-dimensional space, as a permutohedron. The truncated octahedron was called the "mecon" by Buckminster Fuller. Its dual polyhedron is the tetrakis hexahedron. If the original truncated octahedron has unit edge length, its dual tetrakis hexahedron has edge lengths and . Construction A truncated octahedron is constructed from a regular octahedron with side length 3''a'' by the removal of six right square pyramids, one from each point. These pyramids have both base side length (''a'') and lateral ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Structural Formula
The structural formula of a chemical compound is a graphic representation of the molecular structure (determined by structural chemistry methods), showing how the atoms are possibly arranged in the real three-dimensional space. The chemical bonding within the molecule is also shown, either explicitly or implicitly. Unlike other chemical formula types, which have a limited number of symbols and are capable of only limited descriptive power, structural formulas provide a more complete geometric representation of the molecular structure. For example, many chemical compounds exist in different isomeric forms, which have different enantiomeric structures but the same molecular formula. There are multiple types of ways to draw these structural formulas such as: Lewis Structures, condensed formulas, skeletal formulas, Newman projections, Cyclohexane conformations, Haworth projections, and Fischer projections. Several systematic chemical naming formats, as in chemical databases, are ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
FAU And LTA
FAU or Fau may refer to: Education * Florida Atlantic University, in Boca Raton, Florida, U.S. * University of Erlangen–Nuremberg (German: ), in Bavaria, Germany People * Felix Anudike-Uzomah (born 2002), American football player * André Fau (1896–1982), French visual artist and poet * Fernand Fau (1858–1919), French illustrator and cartoonist * Michel Fau (born 1964), French comedian Places * Le Fau, France * Fau (river), in Haute-Saône, France Politics * Uruguayan Anarchist Federation (Spanish: ) * Free Workers' Union (German: ), a union in Germany * Broad Front UNEN (Spanish: ), a political coalition in Argentina Other uses * FAU (gene), encoding 40S ribosomal protein S30 * Fau (letter), or digamma, an archaic letter of the Greek alphabet * F. Arthur Uebel (FAU), German manufacturer of clarinets * Friends' Ambulance Unit, a British ambulance service * Uruguayan Air Force (Spanish: ) * Automobile Federation of Ukraine * Faujasite Faujasite (FAU-typ ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Zeolite Mordenite (with Al Substitution)
Zeolites are microporous, crystalline aluminosilicate materials commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula ･y where is either a metal ion or H+. These positive ions can be exchanged for others in a contacting electrolyte solution. exchanged zeolites are particularly useful as solid acid catalysts. The term ''zeolite'' was originally coined in 1756 by Swedish mineralogist Axel Fredrik Cronstedt, who observed that rapidly heating a material, believed to have been stilbite, produced large amounts of steam from water that had been adsorbed by the material. Based on this, he called the material ''zeolite'', from the Greek , meaning "to boil" and , meaning "stone". Zeolites occur naturally but are also produced industrially on a large scale. , 253 unique zeolite frameworks have been identified, and over 40 naturally occurring zeolite frameworks are known. Every new zeolite structure that is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Fluid Catalytic Cracking
Fluid Catalytic Cracking (FCC) is the conversion process used in petroleum refineries to convert the high-boiling point, high-molecular weight hydrocarbon fractions of petroleum (crude oils) into gasoline, olefinic gases, and other petroleum products. The cracking of petroleum hydrocarbons was originally done by thermal cracking, now virtually replaced by catalytic cracking, which yields greater volumes of high octane rating gasoline; and produces by-product gases, with more carbon-carbon double bonds (i.e. olefins), that are of greater economic value than the gases produced by thermal cracking. The feedstock to the FCC conversion process usually is heavy gas oil (HGO), which is that portion of the petroleum (crude oil) that has an initial boiling-point temperature of or higher, at atmospheric pressure, and that has an average molecular weight that ranges from about 200 to 600 or higher; heavy gas oil also is known as “heavy vacuum gas oil” (HVGO). In the fluid catalytic ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Solid Acid Catalyst
In acid catalysis and base catalysis, a chemical reaction is catalyzed by an acid or a base. By Brønsted–Lowry acid–base theory, the acid is the proton (hydrogen ion, H+) donor and the base is the proton acceptor. Typical reactions catalyzed by proton transfer are esterifications and aldol reactions. In these reactions, the conjugate acid of the carbonyl group is a better electrophile than the neutral carbonyl group itself. Depending on the chemical species that act as the acid or base, catalytic mechanisms can be classified as either specific catalysis and general catalysis. Many enzymes operate by general catalysis. Applications and examples Brønsted acids Acid catalysis is mainly used for organic chemical reactions. Many acids can function as sources for the protons. Acid used for acid catalysis include hydrofluoric acid (in the alkylation process), phosphoric acid, toluenesulfonic acid, polystyrene sulfonate, heteropoly acids, zeolites. Strong acids catalyze the hy ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molecular Sieve
A molecular sieve is a material with pores (very small holes) of uniform size. These pore diameters are similar in size to small molecules, and thus large molecules cannot enter or be adsorbed, while smaller molecules can. As a mixture of molecules migrate through the stationary bed of porous, semi-solid substance referred to as a sieve (or matrix), the components of highest molecular weight (which are unable to pass into the molecular pores) leave the bed first, followed by successively smaller molecules. Some molecular sieves are used in size-exclusion chromatography, a separation technique that sorts molecules based on their size. Other molecular sieves are used as desiccants (some examples include activated charcoal and silica gel). The pore diameter of a molecular sieve is measured in ångströms (Å) or nanometres (nm). According to IUPAC notation, microporous materials have pore diameters of less than 2 nm (20 Å) and macroporous materials have pore diameters of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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