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Vanadium
Vanadium is a chemical element with the symbol V and atomic number 23. It is a hard, silvery-grey, malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer ( passivation) somewhat stabilizes the free metal against further oxidation. Spanish scientist Andrés Manuel del Río discovered compounds of vanadium in 1801 in Mexico by analyzing a new lead-bearing mineral he called "brown lead". Though he initially presumed its qualities were due to the presence of a new element, he was later erroneously convinced by French chemist Hippolyte Victor Collet-Descotils that the element was just chromium. Then in 1830, Nils Gabriel Sefström generated chlorides of vanadium, thus proving there was a new element, and named it "vanadium" after the Scandinavian goddess of beauty and fertility, Vanadís (Freyja). The name was based on the wide range of colors found in vanadium compounds. Del Rio's lead mineral was ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vanadium Redox Battery
The vanadium redox battery (VRB), also known as the vanadium flow battery (VFB) or vanadium redox flow battery (VRFB), is a type of rechargeable flow battery. It employs vanadium ions as charge carriers. The battery uses vanadium's ability to exist in a solution in four different oxidation states to make a battery with a single electroactive element instead of two. For several reasons, including their relative bulkiness, vanadium batteries are typically used for grid energy storage, i.e., attached to power plants/electrical grids. Pissoort explored the possibility of VRFB's in the 1930s.P. A. Pissoort, in FR Patent 754065 (1933) NASA researchers and Pellegri and Spaziante followed suit in the 1970s,A. Pelligri and P. M. Spaziante, in GB Patent 2030349 (1978), to Oronzio de Nori Impianti Elettrochimici S.p.A. but neither was successful. Maria Skyllas-Kazacos presented the first successful demonstration of dissolved vanadium in a solution of sulfuric acid in the 1980s.M. Rych ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vanadium(V) Oxide
Vanadium(V) oxide (''vanadia'') is the inorganic compound with the formula V2 O5. Commonly known as vanadium pentoxide, it is a brown/yellow solid, although when freshly precipitated from aqueous solution, its colour is deep orange. Because of its high oxidation state, it is both an amphoteric oxide and an oxidizing agent. From the industrial perspective, it is the most important compound of vanadium, being the principal precursor to alloys of vanadium and is a widely used industrial catalyst. The mineral form of this compound, shcherbinaite, is extremely rare, almost always found among fumaroles. A mineral trihydrate, V2O5·3H2O, is also known under the name of navajoite. Chemical properties Reduction to lower oxides Upon heating a mixture of vanadium(V) oxide and vanadium(III) oxide, comproportionation occurs to give vanadium(IV) oxide, as a deep-blue solid: :V2O5 + V2O3 → 4 VO2 The reduction can also be effected by oxalic acid, carbon monoxide, and sulfur ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Vanadinite
Vanadinite is a mineral belonging to the apatite group of phosphates, with the chemical formula Pb5( V O4)3 Cl. It is one of the main industrial ores of the metal vanadium and a minor source of lead. A dense, brittle mineral, it is usually found in the form of red hexagonal crystals. It is an uncommon mineral, formed by the oxidation of lead ore deposits such as galena. First discovered in 1801 in Mexico, vanadinite deposits have since been unearthed in South America, Europe, Africa, and North America. Origins Vanadinite is an uncommon mineral, only occurring as the result of chemical alterations to a pre-existing material. It is therefore known as a secondary mineral. It is found in arid climates and forms by oxidation of primary lead minerals. Vanadinite is especially found in association with the lead sulfide, galena. Other associated minerals include wulfenite, limonite, and barite. It was originally discovered in Mexico by the Spanish mineralogist Andrés Manuel d ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Andrés Manuel Del Río
Andrés Manuel del Río y Fernández (10 November 1764 – 23 March 1849) was a Spanish– Mexican scientist, naturalist and engineer who discovered compounds of ''vanadium'' in 1801. He proposed that the element be given the name ''panchromium'', or later, ''erythronium'', but his discovery was not credited at the time, and his names were not used. Education Andrés del Río studied analytical chemistry and metallurgy in Spain, where he was born. He received his bachelor's degree from the University of Alcalá de Henares in 1780 at the age of fifteen. The government gave him a scholarship to enter the Royal Academy of Mines in Almadén, Spain, as of June 1782. He showed great aptitude. In 1783 he was given a travel grant by the Spanish Ministry of Mines. He used it to study in Paris, with the chemist Jean Darcet at the Collège de France. Del Río continued his studies at the Mining Academy in Freiberg, Germany, under the direction of Abraham Gottlob Werner in 1789. In ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
High-speed Steel
High-speed steel (HSS or HS) is a subset of tool steels, commonly used as cutting tool material. It is often used in power-saw blades and drill bits. It is superior to the older high-carbon steel tools used extensively through the 1940s in that it can withstand higher temperatures without losing its temper (hardness). This property allows HSS to cut faster than high carbon steel, hence the name ''high-speed steel''. At room temperature, in their generally recommended heat treatment, HSS grades generally display high hardness (above Rockwell hardness 60) and abrasion resistance (generally linked to tungsten and vanadium content often used in HSS) compared with common carbon and tool steels. History In 1868 English metallurgist Robert Forester Mushet developed Mushet steel, considered the forerunner of modern high-speed steels. It consisted of 2% carbon, 2.5% manganese, and 7% tungsten. The major advantage of this steel was that it hardened when air cooled from a temperature ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nils Gabriel Sefström
Nils Gabriel Sefström (2 June 1787 – 30 November 1845) was a Swedish chemist. Sefström was a student of Berzelius and, when studying the brittleness of steel in 1830, he rediscovered a new chemical element, to which he gave the name vanadium. Vanadium was first discovered by the Spanish-Mexican mineralogist Andrés Manuel del Río in 1801. He named it erythronium. Friedrich Wöhler later confirmed that vanadium and erythronium were the same substance. Sefström was member of the Royal Swedish Academy of Sciences from 1815. The Spitzbergen glacier Sefströmbreen, and the mountain ridge of Sefströmkammen Sefströmkammen is a mountain ridge in Nordenskiöld Land at Spitsbergen, Svalbard. It has a length of about six kilometers, extending along Aurdalen from Søre Aurdalsbre, and comprises the peak of Hamretoppen and other peaks. The ridge is na ..., are named after him. References Further reading * - subscription required * - subscription required Svenskt ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Alloy
An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductility, opacity, and luster, but may have properties that differ from those of the pure metals, such as increased strength or hardness. In some cases, an alloy may reduce the overall cost of the material while preserving important properties. In other cases, the mixture imparts synergistic properties to the constituent metal elements such as corrosion resistance or mechanical strength. Alloys are defined by a metallic bonding character. The alloy constituents are usually measured by mass percentage for practical applications, and in atomic fraction for basic science studies. Alloys are usually classified as substitutional or interstitial alloys, depending on the atomic arrangement that forms the alloy. They can be further classified as hom ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Henry Enfield Roscoe
Sir Henry Enfield Roscoe (7 January 1833 – 18 December 1915) was a British chemist. He is particularly noted for early work on vanadium, photochemical studies, and his assistance in creating Oxo (food), in its earlier liquid form. Life and work Henry Enfield Roscoe was born in London, the son of Henry Roscoe (1800–1836) and Maria Roscoe, née Fletcher (1798–1885), and grandson of William Roscoe (1753–1831). Stanley Jevons the Australian economist was a cousin. Roscoe studied at the Liverpool Institute for Boys and University College London. He then went to Heidelberg to work under Robert Bunsen, who became a lifelong friend. He also befriended William Dittmar. In 1857, Roscoe returned to England with Dittmar and was appointed to the chair of chemistry at Owens College, Manchester, with Dittmar as his assistant. In 1858 the state of the college was such that the ''Manchester Guardian'' called it "a mortifying failure". In the same year Roscoe was accosted by a tr ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Steel
Steel is an alloy made up of iron with added carbon to improve its strength and fracture resistance compared to other forms of iron. Many other elements may be present or added. Stainless steels that are corrosion- and oxidation-resistant typically need an additional 11% chromium. Because of its high tensile strength and low cost, steel is used in buildings, infrastructure, tools, ships, trains, cars, machines, electrical appliances, weapons, and rockets. Iron is the base metal of steel. Depending on the temperature, it can take two crystalline forms (allotropic forms): body-centred cubic and face-centred cubic. The interaction of the allotropes of iron with the alloying elements, primarily carbon, gives steel and cast iron their range of unique properties. In pure iron, the crystal structure has relatively little resistance to the iron atoms slipping past one another, and so pure iron is quite ductile, or soft and easily formed. In steel, small amounts of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Chromium
Chromium is a chemical element with the symbol Cr and atomic number 24. It is the first element in group 6. It is a steely-grey, lustrous, hard, and brittle transition metal. Chromium metal is valued for its high corrosion resistance and hardness. A major development in steel production was the discovery that steel could be made highly resistant to corrosion and discoloration by adding metallic chromium to form stainless steel. Stainless steel and chrome plating ( electroplating with chromium) together comprise 85% of the commercial use. Chromium is also greatly valued as a metal that is able to be highly polished while resisting tarnishing. Polished chromium reflects almost 70% of the visible spectrum, and almost 90% of infrared light. The name of the element is derived from the Greek word χρῶμα, ''chrōma'', meaning color, because many chromium compounds are intensely colored. Industrial production of chromium proceeds from chromite ore (mostly FeCr2O4) to produce ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfuric Acid
Sulfuric acid (American spelling and the preferred IUPAC name) or sulphuric acid ( Commonwealth spelling), known in antiquity as oil of vitriol, is a mineral acid composed of the elements sulfur, oxygen and hydrogen, with the molecular formula . It is a colorless, odorless and viscous liquid that is miscible with water. Pure sulfuric acid does not exist naturally on Earth due to its strong affinity to water vapor; it is hygroscopic and readily absorbs water vapor from the air. Concentrated sulfuric acid is highly corrosive towards other materials, from rocks to metals, since it is an oxidant with powerful dehydrating properties. Phosphorus pentoxide is a notable exception in that it is not dehydrated by sulfuric acid, but to the contrary dehydrates sulfuric acid to sulfur trioxide. Upon addition of sulfuric acid to water, a considerable amount of heat is released; thus the reverse procedure of adding water to the acid should not be performed since the heat released ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Transition Metal
In chemistry, a transition metal (or transition element) is a chemical element in the d-block of the periodic table (groups 3 to 12), though the elements of group 12 (and less often group 3) are sometimes excluded. They are the elements that can use d orbitals as Valence electron#Valence_shell, valence orbitals to form chemical bonds. The lanthanide and actinide elements (the f-block) are called inner transition metals and are sometimes considered to be transition metals as well. Since they are metals, they are lustrous and have good electrical and thermal conductivity. Most (with the exception of Group 11 element, group 11 and Group 12 element, group 12) are hard and strong, and have high melting and boiling temperatures. They form compounds in any of two or more different oxidation states and bind to a variety of ligands to form coordination complexes that are often coloured. They form many useful alloys and are often employed as catalysts in elemental form or in compounds such ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
