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Toluene
Toluene (), also known as toluol (), is a substituted aromatic hydrocarbon. It is a colorless, water-insoluble liquid with the smell associated with paint thinners. It is a mono-substituted benzene derivative, consisting of a methyl group (CH3) attached to a phenyl group. As such, its systematic IUPAC name is methylbenzene. Toluene is predominantly used as an industrial feedstock and a solvent. As the solvent in some types of paint thinner, permanent markers, contact cement and certain types of glue, toluene is sometimes used as a recreational inhalant and has the potential of causing severe neurological harm. History The compound was first isolated in 1837 through a distillation of pine oil by the Polish chemist Filip Walter, who named it ''rétinnaphte''. In 1841, French chemist Henri Étienne Sainte-Claire Deville isolated a hydrocarbon from balsam of Tolu (an aromatic extract from the tropical Colombian tree ''Myroxylon balsamum''), which Deville recognized as simila ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Solvent
A solvent (s) (from the Latin '' solvō'', "loosen, untie, solve") is a substance that dissolves a solute, resulting in a solution. A solvent is usually a liquid but can also be a solid, a gas, or a supercritical fluid. Water is a solvent for polar molecules and the most common solvent used by living things; all the ions and proteins in a cell are dissolved in water within the cell. The quantity of solute that can dissolve in a specific volume of solvent varies with temperature. Major uses of solvents are in paints, paint removers, inks, and dry cleaning. Specific uses for organic solvents are in dry cleaning (e.g. tetrachloroethylene); as paint thinners ( toluene, turpentine); as nail polish removers and solvents of glue (acetone, methyl acetate, ethyl acetate); in spot removers (hexane, petrol ether); in detergents ( citrus terpenes); and in perfumes (ethanol). Solvents find various applications in chemical, pharmaceutical, oil, and gas industries, including in chemi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Benzene
Benzene is an organic chemical compound with the molecular formula C6H6. The benzene molecule is composed of six carbon atoms joined in a planar ring with one hydrogen atom attached to each. Because it contains only carbon and hydrogen atoms, benzene is classed as a hydrocarbon. Benzene is a natural constituent of petroleum and is one of the elementary petrochemicals. Due to the cyclic continuous pi bonds between the carbon atoms, benzene is classed as an aromatic hydrocarbon. Benzene is a colorless and highly flammable liquid with a sweet smell, and is partially responsible for the aroma of gasoline. It is used primarily as a precursor to the manufacture of chemicals with more complex structure, such as ethylbenzene and cumene, of which billions of kilograms are produced annually. Although benzene is a major industrial chemical, it finds limited use in consumer items because of its toxicity. History Discovery The word "''benzene''" derives from "''gum benzoin''" (benz ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Inhalant
Inhalants are a broad range of household and industrial chemicals whose volatile vapors or pressurized gases can be concentrated and breathed in via the nose or mouth to produce intoxication, in a manner not intended by the manufacturer. They are inhaled at room temperature through volatilization (in the case of gasoline or acetone) or from a pressurized container (e.g., nitrous oxide or butane), and do not include drugs that are sniffed after burning or heating. For example, amyl nitrite (poppers), nitrous oxide and toluene – a solvent widely used in contact cement, permanent markers, and certain types of glue – are considered inhalants, but smoking tobacco, cannabis, and crack are not, even though these drugs are inhaled as smoke or vapor. While a few inhalants are prescribed by medical professionals and used for medical purposes, as in the case of inhaled anesthetics and nitrous oxide (an anxiolytic and pain relief agent prescribed by dentists), this article focuse ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electrophilic Aromatic Substitution
Electrophilic aromatic substitution is an organic reaction in which an atom that is attached to an aromatic system (usually hydrogen) is replaced by an electrophile. Some of the most important electrophilic aromatic substitutions are aromatic nitration, aromatic halogenation, aromatic sulfonation, and alkylation and acylation Friedel–Crafts reaction. Illustrative reactions The most widely practised example of this reaction is the ethylation of benzene. :: Approximately 24,700,000 tons were produced in 1999. (After dehydrogenation and polymerization, the commodity plastic polystyrene is produced.) In this process, acids are used as catalyst to generate the incipient carbocation. Many other electrophilic reactions of benzene are conducted, although on a much smaller scale; they are valuable routes to key intermediates. The nitration of benzene is achieved via the action of the nitronium ion as the electrophile. The sulfonation with fuming sulfuric acid gives benzenesul ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Xylene
In organic chemistry, xylene or xylol (; IUPAC name: dimethylbenzene) are any of three organic compounds with the formula . They are derived from the substitution of two hydrogen atoms with methyl groups in a benzene ring; which hydrogens are substituted determines which of three structural isomers results. It is a colorless, flammable, slightly greasy liquid of great industrial value. The mixture is referred to as both xylene and, more precisely, xylenes. Mixed xylenes refers to a mixture of the xylenes plus ethylbenzene. The four compounds have identical empirical formulas . Typically the four compounds are produced together by various catalytic reforming and pyrolysis methods. Occurrence and production Xylenes are an important petrochemical produced by catalytic reforming and also by coal carbonisation in the manufacture of coke fuel. They also occur in crude oil in concentrations of about 0.5–1%, depending on the source. Small quantities occur in gasoline and aircra ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Methylcyclohexane
Methylcyclohexane (cyclohexylmethane) is an organic compound with the molecular formula is CH3C6H11. Classified as saturated hydrocarbon, it is a colourless liquid with a faint odor. Methylcyclohexane is used as a solvent. It is mainly converted in naphtha reformers to toluene.M. Larry Campbell. "Cyclohexane" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2012. Methylcyclohexane is also used in some correction fluids (such as White-Out) as a solvent. Production and use It can be also produced by hydrogenation of toluene: :CH3C6H5 + 3 H2 → CH3C6H11 Methylcyclohexane, as a component of a mixture, is usually dehydrogenated to toluene, which increases the octane rating of gasoline. : It is also one of a host substances in jet fuel surrogate blends, e.g., for Jet A fuel. Solvent Methylcyclohexane is used as an organic solvent, with properties similar to related saturated hydrocarbons such as heptane. It is also a solvent in many types of correc ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Filip Neriusz Walter
Filip Neriusz Walter or Philippe Walter (31 May 1810 – 9 April 1847) was a Polish chemist and pioneer of organic chemistry who worked in Paris. A pioneer of organic chemistry, he was extracted and characterized several compounds including toluene and octene. Life Walter was one of the youngest students of the Jagiellonian University in Kraków, where he studied history and chemistry in 1825–28. Subsequently, he studied at Berlin University, receiving a Ph.D. with his dissertation ''On Combination of Oxalic Acid and Alkali''. Simultaneously he served as assistant to Professor Eilhard Mitscherlich.Stefan Sękowski, Stefan Szostkiewicz, ''Serce i retorta'' (The Heart and the Retort), Warsaw, Wiedza Powszechna, 1957. On the outbreak of the November 1830 Uprising, he went to Warsaw and joined the Polish Army. He served as adjutant to Colonel Samuel Różycki, commander of the 7th infantry regiment. In 1831, aged 21, he was named professor of chemistry at the Jagiellonian Universi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Permanent Marker
A permanent marker or indelible marker is a type of marker pen that is used to create permanent or semi-permanent writing on an object. In general, the ink comprises a main carrier solvent, a glyceride, a pyrrolidone, a resin and a colorant, making it water resistant. It is capable of writing on a variety of surfaces from paper to metal to stone. They come in a variety of tip sizes (ultra fine to wide), shapes (chisel point, bullet tip, and wide bristle), and colors (metallic, or ultraviolet reactive). Most markers have alcohol-based solvents. Other types, called paint markers, like spray paint, contain volatile organic compounds which evaporate to dry the ink. Due to compounds such as toluene and xylene often being present in permanent markers, they have a potential for abuse as a recreational drug. The permanent marker was invented in 1952 by Sidney Rosenthal. Applications General purpose They are used for writing on metals, plastics, ceramics, wood, stone, cardboard etc. H ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Methyl
In organic chemistry, a methyl group is an alkyl derived from methane, containing one carbon atom bonded to three hydrogen atoms, having chemical formula . In formulas, the group is often abbreviated as Me. This hydrocarbon group occurs in many organic compounds. It is a very stable group in most molecules. While the methyl group is usually part of a larger molecule, bounded to the rest of the molecule by a single covalent bond (), it can be found on its own in any of three forms: methanide anion (), methylium cation () or methyl radical (). The anion has eight valence electrons, the radical seven and the cation six. All three forms are highly reactive and rarely observed. Methyl cation, anion, and radical Methyl cation The methylium cation () exists in the gas phase, but is otherwise not encountered. Some compounds are considered to be sources of the cation, and this simplification is used pervasively in organic chemistry. For example, protonation of methanol gives ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Auguste André Thomas Cahours
August André Thomas Cahours (1813–1891) was a French chemist and scientist whose contribution to organic chemistry was one of the greatest in history. He discovered, among other things, the processes of synthesis of several chemical molecules, including toluene, xylene, several organo-magnesiums, and derivatives of phosphine and arsine. He was a professor at the École Polytechnique and the École Centrale des Arts et Manufactures. In 1868 he was elected as a member of the Académie des sciences (chemistry section) and in 1880 became a commander of the Légion d'honneur. Sociétés savantes de France Early life Auguste Cahours was born in on 2 October 1813. He was the first of the two children of Rose Adelaide Cartron ...[...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Aromatic Hydrocarbon
Aromatic compounds, also known as "mono- and polycyclic aromatic hydrocarbons", are organic compounds containing one or more aromatic rings. The parent member of aromatic compounds is benzene. The word "aromatic" originates from the past grouping of molecules based on smell, before their general chemical properties are understood. The current definition of aromatic compounds does not have any relation with their smell. Heteroarenes are closely related, since at least one carbon atom of CH group is replaced by one of the heteroatoms oxygen, nitrogen, or sulfur. Examples of non-benzene compounds with aromatic properties are furan, a heterocyclic compound with a five-membered ring that includes a single oxygen atom, and pyridine, a heterocyclic compound with a six-membered ring containing one nitrogen atom. Hydrocarbons without an aromatic ring are called aliphatic. Benzene ring model Benzene, C6H6, is the least complex aromatic hydrocarbon, and it was the first one named as su ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tolu Balsam
Tolu balsam or balsam of Tolu is a balsam that originates from South America ( Colombia, Peru, Venezuela). It is similar to (and frequently confounded with) the balsam of Peru. It is tapped from the living trunks of ''Myroxylon balsamum var. balsamum''. The fresh balsam of Tolu is a brownish, sticky, semifluid mass. It gradually becomes a brittle solid, but softens again when it is warm. The balsam contains a fairly large amount of benzyl and cinnamyl esters of benzoic and cinnamic acid (benzyl benzoate, benzyl cinnamate). Collection Balsam of Tolu is obtained by cutting a V-shaped wound on the trunk of ''Myroxylon balsamum'' var. ''balsamum'' and fixing a calabash there to catch the exuded resin. Uses The resin is still used in certain cough syrup formulas. However its main use in the modern era is in perfumery, where it is valued for its warm, mellow yet somewhat spicy scent. It is also used as a natural remedy for skin rashes. It is a well known cause of contact dermat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
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