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Thermal Diffusivity
In heat transfer analysis, thermal diffusivity is the thermal conductivity divided by density and specific heat capacity at constant pressure. It measures the rate of transfer of heat of a material from the hot end to the cold end. It has the SI derived unit of m2/s. Thermal diffusivity is usually denoted by lowercase alpha (), but , , (kappa), , and are also used. The formula is: :\alpha = \frac where * is thermal conductivity (W/(m·K)) * is specific heat capacity (J/(kg·K)) * is density (kg/m3) Together, can be considered the volumetric heat capacity (J/(m3·K)). As seen in the heat equation, :\frac = \alpha \nabla^2 T, one way to view thermal diffusivity is as the ratio of the time derivative of temperature to its curvature, quantifying the rate at which temperature concavity is "smoothed out". In a sense, thermal diffusivity is a contrasting measure to thermal inertia In thermodynamics, a material's thermal effusivity, thermal inertia or thermal responsivity ...
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Heat Transfer
Heat transfer is a discipline of thermal engineering that concerns the generation, use, conversion, and exchange of thermal energy (heat) between physical systems. Heat transfer is classified into various mechanisms, such as thermal conduction, thermal convection, thermal radiation, and transfer of energy by phase changes. Engineers also consider the transfer of mass of differing chemical species (mass transfer in the form of advection), either cold or hot, to achieve heat transfer. While these mechanisms have distinct characteristics, they often occur simultaneously in the same system. Heat conduction, also called diffusion, is the direct microscopic exchanges of kinetic energy of particles (such as molecules) or quasiparticles (such as lattice waves) through the boundary between two systems. When an object is at a different temperature from another body or its surroundings, heat flows so that the body and the surroundings reach the same temperature, at which point they are in ...
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Aluminium
Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. It has a great affinity towards oxygen, and forms a protective layer of oxide on the surface when exposed to air. Aluminium visually resembles silver, both in its color and in its great ability to reflect light. It is soft, non-magnetic and ductile. It has one stable isotope, 27Al; this isotope is very common, making aluminium the twelfth most common element in the Universe. The radioactivity of 26Al is used in radiodating. Chemically, aluminium is a post-transition metal in the boron group; as is common for the group, aluminium forms compounds primarily in the +3 oxidation state. The aluminium cation Al3+ is small and highly charged; as such, it is polarizing, and bonds aluminium forms tend towards covalency. The strong affinity tow ...
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Thermal Effusivity
In thermodynamics, a material's thermal effusivity, thermal inertia or thermal responsivity is a measure of its ability to exchange thermal energy with its surroundings. It is defined as the square root of the product of the material's thermal conductivity (\lambda) and its volumetric heat capacity (\rho c_p). :e = \sqrt The SI units for thermal effusivity are \sqrt / (), or, equivalently, / ( \sqrt). Thermal effusivity is a parameter that emerges upon applying solutions of the heat equation to heat flow through a thin surface-like region. It becomes particularly useful when the region is selected adjacent to a material's actual surface. Knowing the effusivity and equilibrium temperature of each of two material bodies then enables an estimate of their interface temperature T_m when placed into thermal contact. :T_m = \frac Specialty sensors have also been developed based on this relationship to measure effusivity. Thermal effusivity and thermal diffusivity are related quant ...
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Thermodiffusion
Thermophoresis (also thermomigration, thermodiffusion, the Soret effect, or the Ludwig–Soret effect) is a phenomenon observed in mixtures of mobile particles where the different particle types exhibit different responses to the force of a temperature gradient. This phenomenon tends to move light molecules to hot regions and heavy molecules to cold regions. The term ''thermophoresis'' most often applies to aerosol mixtures whose mean free path \lambda is comparable to its characteristic length scale L, but may also commonly refer to the phenomenon in all phases of matter. The term ''Soret effect'' normally applies to liquid mixtures, which behave according to different, less well-understood mechanisms than gaseous mixtures. Thermophoresis may not apply to thermomigration in solids, especially multi-phase alloys. Thermophoretic force The phenomenon is observed at the scale of one millimeter or less. An example that may be observed by the naked eye with good lighting is when the ...
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Laser Flash Analysis
The laser flash analysis or laser flash method is used to measure thermal diffusivity of a variety of different materials. An energy pulse heats one side of a plane-parallel sample and the resulting time dependent temperature rise on the backside due to the energy input is detected. The higher the thermal diffusivity of the sample, the faster the energy reaches the backside. A laser flash apparatus (LFA) to measure thermal diffusivity over a broad temperature range, is shown on the right hand side. In a one-dimensional, adiabatic case the thermal diffusivity a is calculated from this temperature rise as follows: : a = 0.1388 \cdot \frac Where * a is the thermal diffusivity in cm2/s * d is the thickness of the sample in cm * t_ is the time to the half maximum in s Measurement principle The laser flash method was developed by Parker et al. in 1961. In a vertical setup, a light source (e.g. laser, flashlamp) heats the sample from the bottom side and a detector on top detec ...
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Heat Equation
In mathematics and physics, the heat equation is a certain partial differential equation. Solutions of the heat equation are sometimes known as caloric functions. The theory of the heat equation was first developed by Joseph Fourier in 1822 for the purpose of modeling how a quantity such as heat diffuses through a given region. As the prototypical parabolic partial differential equation, the heat equation is among the most widely studied topics in pure mathematics, and its analysis is regarded as fundamental to the broader field of partial differential equations. The heat equation can also be considered on Riemannian manifolds, leading to many geometric applications. Following work of Subbaramiah Minakshisundaram and Åke Pleijel, the heat equation is closely related with spectral geometry. A seminal nonlinear variant of the heat equation was introduced to differential geometry by James Eells and Joseph Sampson in 1964, inspiring the introduction of the Ricci flow by Richard ...
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Polypropylene
Polypropylene (PP), also known as polypropene, is a thermoplastic polymer used in a wide variety of applications. It is produced via chain-growth polymerization from the monomer propylene. Polypropylene belongs to the group of polyolefins and is partially crystalline and non-polar. Its properties are similar to polyethylene, but it is slightly harder and more heat-resistant. It is a white, mechanically rugged material and has a high chemical resistance. Bio-PP is the bio-based counterpart of polypropylene (PP). Polypropylene is the second-most widely produced commodity plastic (after polyethylene). In 2019, the global market for polypropylene was worth $126.03 billion. Revenues are expected to exceed US$145 billion by 2019. The sales of this material are forecast to grow at a rate of 5.8% per year until 2021. History Phillips Petroleum chemists J. Paul Hogan and Robert Banks first demonstrated the polymerization of propylene in 1951. The stereoselective polymerizat ...
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PTFE
Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene that has numerous applications. It is one of the best-known and widely applied PFAS. The commonly known brand name of PTFE-based composition is Teflon by Chemours, a spin-off from DuPont, which originally discovered the compound in 1938. Polytetrafluoroethylene is a fluorocarbon solid, as it is a high- molecular-weight polymer consisting wholly of carbon and fluorine. PTFE is hydrophobic: neither water nor water-containing substances wet PTFE, as fluorocarbons exhibit only small London dispersion forces due to the low electric polarizability of fluorine. PTFE has one of the lowest coefficients of friction of any solid. Polytetrafluoroethylene is used as a non-stick coating for pans and other cookware. It is non-reactive, partly because of the strength of carbon–fluorine bonds, so it is often used in containers and pipework for reactive and corrosive chemicals. Where used as a lubrican ...
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Polycarbonate
Polycarbonates (PC) are a group of thermoplastic polymers containing carbonate groups in their chemical structures. Polycarbonates used in engineering are strong, tough materials, and some grades are optically transparent. They are easily worked, molded, and thermoformed. Because of these properties, polycarbonates find many applications. Polycarbonates do not have a unique resin identification code (RIC) and are identified as "Other", 7 on the RIC list. Products made from polycarbonate can contain the precursor monomer bisphenol A (BPA). Structure Carbonate esters have planar OC(OC)2 cores, which confers rigidity. The unique O=C bond is short (1.173 Å in the depicted example), while the C-O bonds are more ether-like (the bond distances of 1.326 Å for the example depicted). Polycarbonates received their name because they are polymers containing carbonate groups (−O−(C=O)−O−). A balance of useful features, including temperature resistance, impact resistance and ...
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Inconel 600
Inconel is a registered trademark of Special Metals Corporation for a family of austenitic nickel- chromium-based superalloys. Inconel alloys are oxidation-corrosion-resistant materials well suited for service in extreme environments subjected to pressure and heat. When heated, Inconel forms a thick, stable, passivating oxide layer protecting the surface from further attack. Inconel retains strength over a wide temperature range, attractive for high-temperature applications where aluminium and steel would succumb to creep as a result of thermally-induced crystal vacancies. Inconel's high-temperature strength is developed by solid solution strengthening or precipitation hardening, depending on the alloy.INCONEL alloy 718
Special Metals Corporation
Inconel alloys are typica ...
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International Journal Of Thermophysics
The ''International Journal of Thermophysics'' is a bimonthly peer-reviewed scientific journal published by Springer Science+Business Media. It was established in 1980. The editor-in-chief is currently Marc J. Assael (Professor of Thermophysical Properties, Aristotle University of Thessaloniki, Greece). The 2020 impact factor was 1.608. Scope This journal covers research on theory and experimental results pertaining to the thermophysical properties of solid states, liquids, and gases, encompassing temperature, pressure, wavelength and other variables of interest. Instruments, techniques, measurement, computer modeling, and related systems are also covered. Abstracting and indexing The journal is abstracted and indexed in: * Chemistry Citation Index * Current Contents/Physical, Chemical and Earth Sciences * Materials Science Citation Index * Reaction Citation Index * Science Citation Index * Academic OneFile * Astrophysics Data System * Chemical Engineering and Biotech ...
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Carbon Nanotube
A scanning tunneling microscopy image of a single-walled carbon nanotube Rotating single-walled zigzag carbon nanotube A carbon nanotube (CNT) is a tube made of carbon with diameters typically measured in nanometers. ''Single-wall carbon nanotubes'' (''SWCNTs'') are one of the allotropes of carbon, intermediate between fullerene cages and flat graphene, with diameters in the range of a nanometre. Although not made this way, single-wall carbon nanotubes can be idealized as cutouts from a two-dimensional Hexagonal tiling, hexagonal lattice of carbon atoms rolled up along one of the Bravais lattice vectors of the hexagonal lattice to form a hollow cylinder. In this construction, periodic boundary conditions are imposed over the length of this roll-up vector to yield a helical lattice of seamlessly bonded carbon atoms on the cylinder surface. ''Multi-wall carbon nanotubes'' (''MWCNTs'') consisting of nested single-wall carbon nanotubes weakly bound together by van der Waals in ...
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