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Pozzolana
Pozzolana or pozzuolana ( , ), also known as pozzolanic ash ( la, pulvis puteolanus), is a natural siliceous or siliceous- aluminous material which reacts with calcium hydroxide in the presence of water at room temperature (cf. pozzolanic reaction). In this reaction insoluble calcium silicate hydrate and calcium aluminate hydrate compounds are formed possessing cementitious properties. The designation pozzolana is derived from one of the primary deposits of volcanic ash used by the Romans in Italy, at Pozzuoli. The modern definition of pozzolana encompasses any volcanic material (pumice or volcanic ash), predominantly composed of fine volcanic glass, that is used as a pozzolan. Note the difference with the term pozzolan, which exerts no bearing on the specific origin of the material, as opposed to pozzolana, which can only be used for pozzolans of volcanic origin, primarily composed of volcanic glass. Historical use Pozzolanas such as Santorin earth were used in the Eastern M ...
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Roman Concrete
Roman concrete, also called , is a material that was used in construction in ancient Rome. Roman concrete was based on a hydraulic-setting cement. It is durable due to its incorporation of pozzolanic ash, which prevents cracks from spreading. By the middle of the 1st century the material was used frequently, often brick-faced, although variations in aggregate allowed different arrangements of materials. Further innovative developments in the material, called the concrete revolution, contributed to structurally complicated forms, such as the Pantheon dome, the world's largest and oldest unreinforced concrete dome. Roman concrete was normally faced with stone or brick, and interiors might be further decorated by stucco, fresco paintings, or thin slabs of fancy colored marbles. Made up of aggregate and a two-part cementitious system it differs significantly from modern concrete. The aggregates were typically far larger than in modern concrete as well, often amounting to rubble, ...
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Cement
A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel ( aggregate) together. Cement mixed with fine aggregate produces mortar for masonry, or with sand and gravel, produces concrete. Concrete is the most widely used material in existence and is behind only water as the planet's most-consumed resource. Cements used in construction are usually inorganic, often lime or calcium silicate based, which can be characterized as hydraulic or the less common non-hydraulic, depending on the ability of the cement to set in the presence of water (see hydraulic and non-hydraulic lime plaster). Hydraulic cements (e.g., Portland cement) set and become adhesive through a chemical reaction between the dry ingredients and water. The chemical reaction results in mineral hydrates that are not very water-soluble and so are quite durable i ...
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Cosa
Cosa was a Latin colony founded in southwestern Tuscany in 273 BC, on land confiscated from the Etruscans, to solidify the control of the Romans and offer the Republic a protected port. The Etruscan site (called ''Cusi'' or ''Cosia'') may have been where modern Orbetello stands; a fortification wall in polygonal masonry at Orbetello's lagoon may be in phase with the walls of Cosa. The position of Cosa is distinct, rising some 113 metres above sea level and is sited 140 km northwest of Rome on the Tyrrhenian Sea coast, on a hill near the small town of Ansedonia. The town experienced a hard life and was never truly a prosperous Roman city, although it has assumed a position of prominence in Roman archaeology owing to the circumstances of its excavation (cf. Dyson 2005, below). After the foundation, wars of the 3rd century BC affected the town. New colonists arrived in 197 BC. Cosa seems to have prospered until it was sacked in the 60s BC, perhaps by pirates - although an ...
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Pozzolan
Pozzolans are a broad class of siliceous and aluminous materials which, in themselves, possess little or no cementitious value but which will, in finely divided form and in the presence of water, react chemically with calcium hydroxide (Ca(OH)2) at ordinary temperature to form compounds possessing cementitious properties. The quantification of the capacity of a pozzolan to react with calcium hydroxide and water is given by measuring its pozzolanic activity. ''Pozzolana'' are naturally occurring pozzolans of volcanic origin. History Mixtures of calcined lime and finely ground, active aluminosilicate materials were pioneered and developed as inorganic binders in the Ancient world. Architectural remains of the Minoan civilization on Crete have shown evidence of the combined use of slaked lime and additions of finely ground potsherds for waterproof renderings in baths, cisterns and aqueducts. Evidence of the deliberate use of volcanic materials such as volcanic ashes or tuffs b ...
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Italy
Italy ( it, Italia ), officially the Italian Republic, ) or the Republic of Italy, is a country in Southern Europe. It is located in the middle of the Mediterranean Sea, and its territory largely coincides with the homonymous geographical region. Italy is also considered part of Western Europe, and shares land borders with France, Switzerland, Austria, Slovenia and the enclaved microstates of Vatican City and San Marino. It has a territorial exclave in Switzerland, Campione. Italy covers an area of , with a population of over 60 million. It is the third-most populous member state of the European Union, the sixth-most populous country in Europe, and the tenth-largest country in the continent by land area. Italy's capital and largest city is Rome. Italy was the native place of many civilizations such as the Italic peoples and the Etruscans, while due to its central geographic location in Southern Europe and the Mediterranean, the country has also historicall ...
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Lime (mineral)
Lime is a calcium-containing inorganic material composed primarily of oxides and hydroxide, usually calcium oxide and/or calcium hydroxide. It is also the name for calcium oxide which occurs as a product of coal-seam fires and in altered limestone xenoliths in volcanic ejecta. The International Mineralogical Association recognizes lime as a mineral with the chemical formula of CaO. The word ''lime'' originates with its earliest use as building mortar and has the sense of ''sticking or adhering''. These materials are still used in large quantities as building and engineering materials (including limestone products, cement, concrete, and mortar), as chemical feedstocks, and for sugar refining, among other uses. Lime industries and the use of many of the resulting products date from prehistoric times in both the Old World and the New World. Lime is used extensively for wastewater treatment with ferrous sulfate. The rocks and minerals from which these materials are deri ...
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Trass
Trass is the local name of a volcanic tuff occurring in the Eifel, where it is worked for hydraulic mortar. It is a grey or cream-coloured fragmental rock, largely composed of pumiceous dust, and may be regarded as a trachytic tuff. It much resembles the Italian pozzolana and is applied to like purposes. Mixed with lime and sand, or with Portland cement, it is extensively employed for hydraulic work, especially in the Netherlands; while the compact varieties have been used as a building material and as a fire-stone in ovens. Trass was formerly worked extensively in the Brohl valley and is now obtained from the valley of the Nette, near Andernach. See also *Pozzolan *Pozzolana *Pozzolanic reaction *Pumice Pumice (), called pumicite in its powdered or dust form, is a volcanic rock that consists of highly vesicular rough-textured volcanic glass, which may or may not contain crystals. It is typically light-colored. Scoria is another vesicular v ... References Natural ...
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Pozzolanic Activity
The pozzolanic activity is a measure for the degree of reaction over time or the reaction rate between a pozzolan and Ca2+ or calcium hydroxide (Ca(OH)2) in the presence of water. The rate of the pozzolanic reaction is dependent on the intrinsic characteristics of the pozzolan such as the specific surface area, the chemical composition and the active phase content. Physical surface adsorption is not considered as being part of the pozzolanic activity, because no irreversible molecular bonds are formed in the process. Reaction The pozzolanic reaction is the chemical reaction that occurs in portland cement upon the addition of pozzolans. It is the main reaction involved in the Roman concrete invented in Ancient Rome and used to build, for example, the Pantheon. The pozzolanic reaction converts a silica-rich precursor with no cementing properties, to a calcium silicate, with good cementing properties. In chemical terms, the pozzolanic reaction occurs between calcium hydroxide, al ...
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Pozzuoli
Pozzuoli (; ; ) is a city and ''comune'' of the Metropolitan City of Naples, in the Italian region of Campania. It is the main city of the Phlegrean Peninsula. History Pozzuoli began as the Greek colony of ''Dicaearchia'' ( el, Δικαιαρχία) founded in about 531 BC with the consent of nearby Cumae when refugees from Samos escaped from the tyranny of Polycrates. The Samnites occupied Dicaearchia in 421 BC after having conquered Cumae and may have changed its name to Fistelia. It enjoyed considerable political and commercial autonomy favoured by the excellent position of its port with the Campanian hinterland. The Roman occupation of Campania after the end of the 1st Samnite War from 341 BC marked the start of the Romanisation of the Greek-Samnite city. During the Second Punic War (218-201 BC), Rome experienced the strategic importance of the port of Puteoli and reinforced the defences and introduced a garrison to protect the town from Hannibal, who failed to cap ...
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Pozzolanic Reaction
The pozzolanic activity is a measure for the degree of reaction over time or the reaction rate between a pozzolan and Ca2+ or calcium hydroxide (Ca(OH)2) in the presence of water. The rate of the pozzolanic reaction is dependent on the intrinsic characteristics of the pozzolan such as the specific surface area, the chemical composition and the active phase content. Physical surface adsorption is not considered as being part of the pozzolanic activity, because no irreversible molecular bonds are formed in the process. Reaction The pozzolanic reaction is the chemical reaction that occurs in portland cement upon the addition of pozzolans. It is the main reaction involved in the Roman concrete invented in Ancient Rome and used to build, for example, the Pantheon. The pozzolanic reaction converts a silica-rich precursor with no cementing properties, to a calcium silicate, with good cementing properties. In chemical terms, the pozzolanic reaction occurs between calcium hydroxide, al ...
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Ancient Rome
In modern historiography, ancient Rome refers to Roman civilisation from the founding of the city of Rome in the 8th century BC to the collapse of the Western Roman Empire in the 5th century AD. It encompasses the Roman Kingdom (753–509 BC), Roman Republic (509–27 BC) and Roman Empire (27 BC–476 AD) until the fall of the western empire. Ancient Rome began as an Italic settlement, traditionally dated to 753 BC, beside the River Tiber in the Italian Peninsula. The settlement grew into the city and polity of Rome, and came to control its neighbours through a combination of treaties and military strength. It eventually dominated the Italian Peninsula, assimilated the Greek culture of southern Italy (Magna Grecia) and the Etruscan culture and acquired an Empire that took in much of Europe and the lands and peoples surrounding the Mediterranean Sea. It was among the largest empires in the ancient world, with an estimated 50 to 90 million inhabitants, roughly 20% of t ...
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Igneous Rock
Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rock is formed through the cooling and solidification of magma or lava. The magma can be derived from partial melts of existing rocks in either a planet's mantle or crust. Typically, the melting is caused by one or more of three processes: an increase in temperature, a decrease in pressure, or a change in composition. Solidification into rock occurs either below the surface as intrusive rocks or on the surface as extrusive rocks. Igneous rock may form with crystallization to form granular, crystalline rocks, or without crystallization to form natural glasses. Igneous rocks occur in a wide range of geological settings: shields, platforms, orogens, basins, large igneous provinces, extended crust and oceanic crust. Geological significance Igneous and metamorphic rocks make up 90–95% of th ...
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