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Kevlar
Kevlar (para-aramid) is a strong, heat-resistant synthetic fiber, related to other aramids such as Nomex and Technora. Developed by Stephanie Kwolek at DuPont in 1965, the high-strength material was first used commercially in the early 1970s as a replacement for steel in racing tires. It is typically spun into ropes or fabric sheets that can be used as such, or as an ingredient in composite material components. Kevlar has many applications, ranging from bicycle tires and racing sails to bulletproof vests, all due to its high tensile strength-to-weight ratio; by this measure it is five times stronger than steel. It is also used to make modern marching drumheads that withstand high impact; and for mooring lines and other underwater applications. A similar fiber called Twaron with the same chemical structure was developed by Akzo in the 1970s; commercial production started in 1986, and Twaron is now manufactured by Teijin. History Poly-paraphenylene terephthalamide (K2 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Stephanie Kwolek
Stephanie Louise Kwolek (; July 31, 1923 – June 18, 2014) was a Polish-American chemist who is known for inventing Kevlar. Her career at the DuPont company spanned more than 40 years. She discovered the first of a family of synthetic fibers of exceptional strength and stiffness: poly-paraphenylene terephthalamide. For her discovery, Kwolek was awarded the DuPont company's Lavoisier Medal for outstanding technical achievement. As of August 2019, she was the only female employee to have received that honor.Dan Samorodnitsky"Meet Stephanie Kwolek, the woman who gave us bulletproof vests and yoga pants"''Massive Science, July 31, 2019. In 1995 she became the fourth woman to be added to the National Inventors Hall of Fame. Kwolek won numerous awards for her work in polymer chemistry, including the National Medal of Technology, the IRI Achievement Award and the Perkin Medal. Early life and education Kwolek was one of two children born to Polish immigrant parents in the Pittsbur ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sailcloth
Sailcloth encompasses a wide variety of materials that span those from natural fibers, such as flax, hemp or cotton in various forms of sail canvas, to synthetic fibers, including nylon, polyester, aramids, and carbon fibers in a variety of woven, spun and molded textiles. History Western traditions Viking longships used wool for sailcloth. The cloth was woven in one of three ways, according to locality and tradition: plain weave with individual threads going over and under each other, three-shaft twill with two threads going over and under at each cross thread, and four-shaft twill with thread interwoven with two threads at a time in either direction. Such was the practice from the 11th through the 14th centuries. Doek is Dutch for cloth, which evolved into the English word "duck" in reference to sail canvas. Duck was typically made from cotton or linen (flax), with some use of hemp. These natural fibers have poor resistance to rot, UV light and water absorption. Linen is s ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bulletproof Vest
A bulletproof vest, also known as a ballistic vest or a bullet-resistant vest, is an item of body armor that helps absorb the impact and reduce or stop penetration to the torso from firearm-fired projectiles and fragmentation from explosions. The vest may come in a soft form, as worn by many police officers, prison guards, security guards, and some private citizens, used to protect against stabbing attacks or light projectiles, using metallic or para-aramid components. Soldiers, police tactical units, marines, and special operations forces wear hard armors, either in conjunction with soft armor or alone, to protect against rifle ammunition or fragmentation. History Early modern era In 1538, Francesco Maria della Rovere commissioned Filippo Negroli to create a bulletproof vest. In 1561, Maximilian II, Holy Roman Emperor is recorded as testing his armor against gun-fire. Similarly, in 1590 Sir Henry Lee expected his Greenwich armor to be "pistol proof". Its actual effectiv ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Aramid
Aramid fibers, short for aromatic polyamide, are a class of heat-resistant and strong synthetic fibers. They are used in aerospace and military applications, for ballistic-rated body armor fabric and ballistic composites, in marine cordage, marine hull reinforcement, and as an asbestos substitute. The chain molecules in the fibers are highly oriented along the fiber axis. As a result, a higher proportion of the chemical bond contributes more to fiber strength than in many other synthetic fibers. Aramids have a very high melting point (>500 °C). Common aramid brand names include Kevlar, Nomex, and Twaron. Terminology and chemical structure ''Aramid'' is a shortened form of aromatic polyamide. The term was introduced in 1972, accepted in 1974 by the Federal Trade Commission of the USA as the name of a generic category of fiber distinct from nylon, and adopted by the International Standards Organisation in 1977. Aromatic in the name refers to the presence of aromatic rin ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nomex
Nomex is a flame-resistant meta- aramid material developed in the early 1960s by DuPont and first marketed in 1967. Properties Nomex and related aramid polymers are related to nylon, but have aromatic backbones, and hence are more rigid and more durable. Nomex is an example of a ''meta'' variant of the aramids (Kevlar is a '' para'' aramid). Unlike Kevlar, Nomex strands cannot align during filament polymerization and have less strength: its ultimate tensile strength is 340 MPa. However, it has excellent thermal, chemical, and radiation resistance for a polymer material. It can withstand temperatures of up to 370 °C. Production Nomex is produced by condensation reaction from the monomers ''m''-phenylenediamine and isophthaloyl chloride. It is sold in both fiber and sheet forms and is used as a fabric where resistance from heat and flame is required. Nomex sheet is actually a calendered paper and made in a similar fashion. Nomex Type 410 paper was the first Nomex paper ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
DuPont
DuPont de Nemours, Inc., commonly shortened to DuPont, is an American multinational chemical company first formed in 1802 by French-American chemist and industrialist Éleuthère Irénée du Pont de Nemours. The company played a major role in the development of Delaware and first arose as a major supplier of gunpowder. DuPont developed many polymers such as Vespel, neoprene, nylon, Corian, Teflon, Mylar, Kapton, Kevlar, Zemdrain, M5 fiber, Nomex, Tyvek, Sorona, Corfam and Lycra in the 20th century, and its scientists developed many chemicals, most notably Freon (chlorofluorocarbons), for the refrigerant industry. It also developed synthetic pigments and paints including ChromaFlair. In 2015, DuPont and the Dow Chemical Company agreed to a reorganization plan in which the two companies would merge and split into three. As a merged entity, DuPont simultaneously acquired Dow and renamed itself to DowDuPont on August 31, 2017, and after 18 months spin off the merged en ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Terephthaloyl Chloride
Terephthaloyl chloride (TCL, 1,4-benzenedicarbonyl chloride) is the acyl chloride of terephthalic acid. It is a white solid. It is one of two precursors used to make Kevlar(R), the other being ''p''-phenylenediamine. TCL is used as a key component in performance polymers and aramid fibers, where it imparts flame resistance, chemical resistance, temperature stability, light weight, and very high strength. TCL is also an effective water scavenger, used to stabilize isocyanates and urethane prepolymers. Preparation Terephthalic acid dichloride is produced commercially by the reaction of 1,4-bis(trichloromethyl)benzene with terephthalic acid: : C6H4(CCl3)2 + C6H4(CO2H)2 → 2 C6H4(COCl)2 + 2 HCl It can also be obtained by chlorination of dimethyl terephthalate. Use TCL is used for making various copolymers and aramid polymers such as Heracron, Twaron and Kevlar Kevlar (para-aramid) is a strong, heat-resistant synthetic fiber, related to other aramids such as Nomex and ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
P-Phenylenediamine
''p''-Phenylenediamine (PPD) is an organic compound with the formula C6H4(NH2)2. This derivative of aniline is a white solid, but samples can darken due to air oxidation. It is mainly used as a component of engineering polymers and composites like kevlar. It is also an ingredient in hair dyes and is occasionally used as a substitute for henna. Production PPD is produced via three routes. Most commonly, 4-nitrochlorobenzene is treated with ammonia and the resulting 4-nitroaniline is then hydrogenated: :ClC6H4NO2 + 2 NH3 → H2NC6H4NO2 + NH4Cl :H2NC6H4NO2 + 3 H2 → H2NC6H4NH2 + 2 H2O In the DuPont route, aniline is converted to diphenyltriazine, which is then converted by acid-catalysis to 4-aminoazobenzene. Hydrogenation of the latter affords PPD.Robert A. Smiley "Phenylene- and Toluenediamines" in ''Ullmann's Encyclopedia of Industrial Chemistry'', 2002, Wiley-VCH, Weinheim. Uses Precursor to polymers PPD is a precursor to aramid plastics and fibers such as ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Composite Material
A composite material (also called a composition material or shortened to composite, which is the common name) is a material which is produced from two or more constituent materials. These constituent materials have notably dissimilar chemical or physical properties and are merged to create a material with properties unlike the individual elements. Within the finished structure, the individual elements remain separate and distinct, distinguishing composites from mixtures and solid solutions. Typical engineered composite materials include: * Reinforced concrete and masonry * Composite wood such as plywood *Reinforced plastics, such as fibre-reinforced polymer or fiberglass * Ceramic matrix composites ( composite ceramic and metal matrices) * Metal matrix composites *and other advanced composite materials There are various reasons where new material can be favoured. Typical examples include materials which are less expensive, lighter, stronger or more durable when compared with ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Polymer Chemistry
Polymer chemistry is a sub-discipline of chemistry that focuses on the structures of chemicals, chemical synthesis, and chemical and physical properties of polymers and macromolecules. The principles and methods used within polymer chemistry are also applicable through a wide range of other chemistry sub-disciplines like organic chemistry, analytical chemistry, and physical chemistry. Many materials have polymeric structures, from fully inorganic metals and ceramics to DNA and other biological molecules. However, polymer chemistry is typically related to synthetic and organic compositions. Synthetic polymers are ubiquitous in commercial materials and products in everyday use, such as plastics, and rubbers, and are major components of composite materials. Polymer chemistry can also be included in the broader fields of polymer science or even nanotechnology, both of which can be described as encompassing polymer physics and polymer engineering.Hans-Heinrich Moretto, Manfred ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Twaron
Twaron (a brand name of Teijin Aramid) is a para-aramid. It is a heat-resistant and strong synthetic fibre developed in the early 1970s by the Dutch company Akzo Nobel's division Enka BV, later Akzo Industrial Fibers. The research name of the para-aramid fibre was originally Fiber X, but it was soon called Arenka. Although the Dutch para-aramid fiber was developed only a little later than DuPont's Kevlar, the introduction of Twaron as a commercial product came much later than Kevlar due to financial problems at the AKZO company in the 1970s. History This is a chronology of the development of Twaron: * In 1960s a research program starts for "Fiber X." * In 1972 the ENKA Research laboratory develops a para-aramid called Arenka. * In 1973 Akzo decides to use sulfuric acid (H2SO4) as a solvent for spinning. * In 1974 New process route was found at Akzo Research laboratory, using N-methylpyrrolidone (NMP) with a co-solvent (auxiliary solvent) with an ionic component (Calcium Chlo ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Technora
Technora is an aramid that is useful for a variety of applications that require high strength or Chemical resistance, chemical resistance. It is a brand name of the company Teijin Aramid. Technora was used on January 25, 2004 to suspend the NASA Mars rover Opportunity rover, Opportunity from its parachute during descent. It was also later used by NASA as one of the materials, combined with nylon and Kevlar, making up the parachute that was used to perform a braking manoeuvre during atmospheric entry of the Perseverance rover that landed on Mars on February 18, 2021. Production Technora is produced by condensation polymerization of terephthaloyl chloride (TCl) with a mixture of p-phenylenediamine (PPD) and 3,4'-diaminodiphenylether (3,4'-ODA).Stephanie Kwolek, Hiroshi Mera, Tadahiko Takata “High-Performance Fibers” in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH, Weinheim. The polymer is closely related to Teijin Aramids's Twaron or DuPont's Kevlar. Techno ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
