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Detonator
A detonator, frequently a blasting cap, is a device used to trigger an explosive device. Detonators can be chemically, mechanically, or electrically initiated, the last two being the most common. The commercial use of explosives uses electrical detonators or the capped fuse which is a length of safety fuse to which an ordinary detonator has been joined. Many detonators' primary explosive is a material called ASA compound. This compound is formed from lead azide, lead styphnate and aluminium and is pressed into place above the base charge, usually TNT or tetryl in military detonators and PETN in commercial detonators. Other materials such as DDNP (diazo dinitro phenol) are also used as the primary charge to reduce the amount of lead emitted into the atmosphere by mining and quarrying operations. Old detonators used mercury fulminate as the primary, often mixed with potassium chlorate to yield better performance. A blasting cap is a small sensitive primary explosive dev ...
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Exploding-bridgewire Detonator
The exploding-bridgewire detonator (EBW, also known as exploding wire detonator) is a type of detonator used to initiate the detonation reaction in explosive materials, similar to a blasting cap because it is fired using an electric current. EBWs use a different physical mechanism than blasting caps, using more electricity delivered much more rapidly, and explode in a much more precise timing after the electric current is applied, by the process of exploding wire method. This has led to their common use in nuclear weapons. The slapper detonator is a more recent development along similar lines. History The EBW was invented by Luis Alvarez and Lawrence Johnston for the Fat Man–type bombs of the Manhattan Project, during their work in Los Alamos National Laboratory. The Fat Man Model 1773 EBW detonators used an unusual, high reliability detonator system with two EBW "horns" attached to a single booster charge, which then fired each of the 32 explosive lens units. Descr ...
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Detonator
A detonator, frequently a blasting cap, is a device used to trigger an explosive device. Detonators can be chemically, mechanically, or electrically initiated, the last two being the most common. The commercial use of explosives uses electrical detonators or the capped fuse which is a length of safety fuse to which an ordinary detonator has been joined. Many detonators' primary explosive is a material called ASA compound. This compound is formed from lead azide, lead styphnate and aluminium and is pressed into place above the base charge, usually TNT or tetryl in military detonators and PETN in commercial detonators. Other materials such as DDNP (diazo dinitro phenol) are also used as the primary charge to reduce the amount of lead emitted into the atmosphere by mining and quarrying operations. Old detonators used mercury fulminate as the primary, often mixed with potassium chlorate to yield better performance. A blasting cap is a small sensitive primary explosive dev ...
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Lead Azide
Lead(II) azide is an inorganic compound. More so than other azides, is explosive. It is used in detonators to initiate secondary explosives. In a commercially usable form, it is a white to buff powder. Preparation and handling Lead(II) azide is prepared by the reaction of sodium azide and lead(II) nitrate in aqueous solution. Lead(II) acetate can also be used. Thickeners such as dextrin or polyvinyl alcohol are often added to the solution to stabilize the precipitated product. In fact, it is normally shipped in a dextrinated solution that lowers its sensitivity. Production history Lead azide in its pure form was first prepared by Theodor Curtius in 1891. Due to sensitivity and stability concerns, the dextrinated form of lead azide (MIL-L-3055) was developed in the 1920s and 1930s with large scale production by DuPont Co beginning in 1932. Detonator development during World War II resulted in the need for a form of lead azide with a more brisant output. RD-1333 lead azide ( ...
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Lead(II) Azide
Lead(II) azide is an inorganic compound. More so than other azides, is explosive. It is used in detonators to initiate secondary explosives. In a commercially usable form, it is a white to buff powder. Preparation and handling Lead(II) azide is prepared by the reaction of sodium azide and lead(II) nitrate in aqueous solution. Lead(II) acetate can also be used. Thickeners such as dextrin or polyvinyl alcohol are often added to the solution to stabilize the precipitated product. In fact, it is normally shipped in a dextrinated solution that lowers its sensitivity. Production history Lead azide in its pure form was first prepared by Theodor Curtius in 1891. Due to sensitivity and stability concerns, the dextrinated form of lead azide (MIL-L-3055) was developed in the 1920s and 1930s with large scale production by DuPont Co beginning in 1932. Detonator development during World War II resulted in the need for a form of lead azide with a more brisant output. RD-1333 lead azide (MIL ...
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Fuse (explosives)
In an explosive, pyrotechnic device, or military munition, a fuse (or fuze) is the part of the device that initiates function. In common usage, the word fuse is used indiscriminately. However, when being specific (and in particular in a military context), the term ''fuse'' describes a simple pyrotechnic initiating device, like the cord on a firecracker whereas the term '' fuze'' is used when referring to a more sophisticated ignition device incorporating mechanical and/or electronic components, such as a proximity fuze for an M107 artillery shell, magnetic or acoustic fuze on a sea mine, spring-loaded grenade fuze, pencil detonator, or anti-handling device. History Documented evidence suggests that the earliest fuses were first used by the Song Chinese between the 10th and 12th centuries. After the Chinese invented gunpowder, they began adapting its explosive properties for use in military technology. By 1044 they were using gunpowder in simple grenades, bombs, ...
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Diazo Dinitro Phenol
Diazodinitrophenol (DDNP) was the first diazo compound produced; it was subsequently used to make dyes and explosives. It forms yellow crystals in pure form; however, the color of impure forms may vary from dark yellow to green to dark brown. It is soluble in acetic acid, acetone, concentrated hydrochloric acid, most non-polar solvents and is slightly soluble in water. A solution of cold sodium hydroxide may be used to destroy it. DDNP may be desensitized by immersing it in water, as it does not react in water at normal temperature. It is less sensitive to impact but more powerful than mercury fulminate and almost as powerful as lead azide. The sensitivity of DDNP to friction is much less than that of mercury fulminate and lead azide. DDNP is used with other materials to form priming mixtures, particularly where a high sensitivity to flame or heat is desired. DDNP is often used as an initiating explosive in propellant primer devices and is a substitute for lead styphnate in ...
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Diazodinitrophenol
Diazodinitrophenol (DDNP) was the first diazo compound produced; it was subsequently used to make dyes and explosives. It forms yellow crystals in pure form; however, the color of impure forms may vary from dark yellow to green to dark brown. It is soluble in acetic acid, acetone, concentrated hydrochloric acid, most non-polar solvents and is slightly soluble in water. A solution of cold sodium hydroxide may be used to destroy it. DDNP may be desensitized by immersing it in water, as it does not react in water at normal temperature. It is less sensitive to impact but more powerful than mercury fulminate and almost as powerful as lead azide. The sensitivity of DDNP to friction is much less than that of mercury fulminate and lead azide. DDNP is used with other materials to form priming mixtures, particularly where a high sensitivity to flame or heat is desired. DDNP is often used as an initiating explosive in propellant primer devices and is a substitute for lead styphna ...
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Fuse (explosive)
In an explosive, pyrotechnic device, or military munition, a fuse (or fuze) is the part of the device that initiates function. In common usage, the word fuse is used indiscriminately. However, when being specific (and in particular in a military context), the term ''fuse'' describes a simple pyrotechnic initiating device, like the cord on a firecracker whereas the term ''fuze'' is used when referring to a more sophisticated ignition device incorporating mechanical and/or electronic components, such as a proximity fuze for an M107 artillery shell, magnetic or acoustic fuze on a sea mine, spring-loaded grenade fuze, pencil detonator, or anti-handling device. History Documented evidence suggests that the earliest fuses were first used by the Song Chinese between the 10th and 12th centuries. After the Chinese invented gunpowder, they began adapting its explosive properties for use in military technology. By 1044 they were using gunpowder in simple grenades, bombs, and flamethr ...
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Nuclear Weapon
A nuclear weapon is an explosive device that derives its destructive force from nuclear reactions, either fission (fission bomb) or a combination of fission and fusion reactions ( thermonuclear bomb), producing a nuclear explosion. Both bomb types release large quantities of energy from relatively small amounts of matter. The first test of a fission ("atomic") bomb released an amount of energy approximately equal to . The first thermonuclear ("hydrogen") bomb test released energy approximately equal to . Nuclear bombs have had yields between 10 tons TNT (the W54) and 50 megatons for the Tsar Bomba (see TNT equivalent). A thermonuclear weapon weighing as little as can release energy equal to more than . A nuclear device no larger than a conventional bomb can devastate an entire city by blast, fire, and radiation. Since they are weapons of mass destruction, the proliferation of nuclear weapons is a focus of international relations policy. Nuclear weapons have been de ...
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Mercury(II) Fulminate
Mercury(II) fulminate, or Hg(CNO)2, is a primary explosive. It is highly sensitive to friction, heat and shock and is mainly used as a trigger for other explosives in percussion caps and detonators. Mercury(II) cyanate, though its chemical formula is identical, has a different atomic arrangement; the cyanate and fulminate anions are isomers. First used as a priming composition in small copper caps beginning in the 1820s, mercury fulminate quickly replaced flints as a means to ignite black powder charges in muzzle-loading firearms. Later, during the late 19th century and most of the 20th century, mercury fulminate became widely used in primers for self-contained rifle and pistol ammunition; it was the only practical detonator for firing projectiles until the early 20th century. Mercury fulminate has the distinct advantage over potassium chlorate of being non-corrosive, but it is known to weaken with time, by decomposing into its constituent elements. The reduced mercury which r ...
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Silver Azide
Silver azide is the chemical compound with the formula . It is a silver(I) salt of hydrazoic acid. It forms a colorless crystals. It is a well-known explosive. Structure and chemistry Silver azide can be prepared by treating an aqueous solution of silver nitrate with sodium azide. The silver azide precipitates as a white solid, leaving sodium nitrate in solution. : X-ray crystallography shows that is a coordination polymer with square planar coordinated by four azide ligands. Correspondingly, each end of each azide ligand is connected to a pair of centers. The structure consists of two-dimensional layers stacked one on top of the other, with weaker Ag–N bonds between layers. The coordination of can alternatively be described as highly distorted 4 + 2 octahedral, the two more distant nitrogen atoms being part of the layers above and below. In its most characteristic reaction, the solid decomposes explosively, releasing nitrogen gas: : The first step in this decompos ...
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Plastic Explosive
Plastic explosive is a soft and hand-moldable solid form of explosive material. Within the field of explosives engineering, plastic explosives are also known as putty explosives or blastics. Plastic explosives are especially suited for explosive demolition. Common plastic explosives include Semtex and C-4. The first manufactured plastic explosive was gelignite in 1875, invented by Alfred Nobel. Usage Plastic explosives are especially suited for explosive demolition of obstacles and fortifications by engineers, combat engineers and criminals as they can be easily formed into the best shapes for cutting structural members and have a high enough velocity of detonation and density for metal cutting work. An early use of plastic explosives was in the warhead of the Petard demolition mortar of the British Armoured Vehicle Royal Engineers (AVRE); said mortar was used to destroy concrete fortifications encountered during Operation Overlord (D-Day). The original use of Nobel 808 s ...
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