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Crucible
A crucible is a ceramic or metal container in which metals or other substances may be melted or subjected to very high temperatures. While crucibles were historically usually made from clay, they can be made from any material that withstands temperatures high enough to melt or otherwise alter its contents. History Typology and chronology The form of the crucible has varied through time, with designs reflecting the process for which they are used, as well as regional variation. The earliest crucible forms derive from the sixth/fifth millennium B.C. in Eastern Europe and Iran. Chalcolithic Crucibles used for copper smelting were generally wide shallow vessels made from clay that lacks refractory properties which is similar to the types of clay used in other ceramics of the time. During the Chalcolithic period, crucibles were heated from the top by using blowpipes.Hauptmann A., 2003, ''Developments in copper Metallurgy During the Fourth and Third Millennia B.C. at Feinan'', Jorda ...
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Crucible Steel
Crucible steel is steel made by melting pig iron (cast iron), iron, and sometimes steel, often along with sand, glass, ashes, and other fluxes, in a crucible. In ancient times steel and iron were impossible to melt using charcoal or coal fires, which could not produce temperatures high enough. However, pig iron, having a higher carbon content and thus a lower melting point, could be melted, and by soaking wrought iron or steel in the liquid pig-iron for a long time, the carbon content of the pig iron could be reduced as it slowly diffused into the iron, turning both into steel. Crucible steel of this type was produced in South and Central Asia during the medieval era. This generally produced a very hard steel, but also a composite steel that was inhomogeneous, consisting of a very high-carbon steel (formerly the pig-iron) and a lower-carbon steel (formerly the wrought iron). This often resulted in an intricate pattern when the steel was forged, filed or polished, with possibly t ...
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Brass
Brass is an alloy of copper (Cu) and zinc (Zn), in proportions which can be varied to achieve different mechanical, electrical, and chemical properties. It is a substitutional alloy: atoms of the two constituents may replace each other within the same crystal structure. Brass is similar to bronze, another copper alloy, that uses tin instead of zinc. Both bronze and brass may include small proportions of a range of other elements including arsenic (As), lead (Pb), phosphorus (P), aluminium (Al), manganese (Mn), and silicon (Si). Historically, the distinction between the two alloys has been less consistent and clear, and modern practice in museums and archaeology increasingly avoids both terms for historical objects in favor of the more general "copper alloy". Brass has long been a popular material for decoration due to its bright, gold-like appearance; being used for drawer pulls and doorknobs. It has also been widely used to make utensils because of its low melti ...
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Hessian Crucible
A Hessian crucible is a type of ceramic crucible that was manufactured in the Hesse region of Germany from the late Middle Ages through the Renaissance period. They were renowned for their ability to withstand very high temperatures, rapid changes in temperature, and strong reagents. These crucibles were widely used for alchemy and early metallurgy. Millions of the vessels were exported throughout Europe, Scandinavia, and the colonies in the Americas. The crucibles were made by firing kaolinitic clay at temperatures greater than 1100℃, forming mullite. Mullite is an aluminum silicate only described in the 20th century and is responsible for the excellent properties of the Hessian crucible. Main production centre of the Hessian crucibles was the village of Großalmerode Großalmerode (or ''Grossalmerode'') is a town in the Werra-Meißner-Kreis in Hesse, Germany. Geography Location The small town, which has had town rights since 1775, lies 21 km east of Kassel in the M ...
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Wootz Steel
Wootz steel, also known as Seric steel, is a crucible steel characterized by a pattern of bands and high carbon content. These bands are formed by sheets of microscopic carbides within a tempered martensite or pearlite matrix in higher carbon steel, or by ferrite and pearlite banding in lower carbon steels. It was a pioneering steel alloy developed in India in the mid-1st millennium BC and exported globally. History Wootz steel originated in the mid-1st millennium BC in South India, in present-day Tiruchirappalli, Kodumanal, Erode, Tamil Nadu. There are several ancient Tamil, North Indian, Greek, Chinese and Roman literary references to high carbon Tamil steel. In later times, wootz steel was also made in Golconda in Telangana, Karnataka and Sri Lanka. The steel was exported as cakes of steely iron that came to be known as "Wootz". The method was to heat black magnetite ore in the presence of carbon in a sealed clay crucible inside a charcoal furnace to completely remove ...
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Alloys
An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductility, opacity, and luster, but may have properties that differ from those of the pure metals, such as increased strength or hardness. In some cases, an alloy may reduce the overall cost of the material while preserving important properties. In other cases, the mixture imparts synergistic properties to the constituent metal elements such as corrosion resistance or mechanical strength. Alloys are defined by a metallic bonding character. The alloy constituents are usually measured by mass percentage for practical applications, and in atomic fraction for basic science studies. Alloys are usually classified as substitutional or interstitial alloys, depending on the atomic arrangement that forms the alloy. They can be further classified as homog ...
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Cementation Process
The cementation process is an obsolete technology for making steel by carburization of iron. Unlike modern steelmaking, it increased the amount of carbon in the iron. It was apparently developed before the 17th century. Derwentcote Steel Furnace, built in 1720, is the earliest surviving example of a cementation furnace. Another example in the UK is the cementation furnace in Doncaster Street, Sheffield. Origins The process was described in a treatise published in Prague in 1574. It was again invented by Johann Nussbaum of Magdeburg, who began operations at Nuremberg (with partners) in 1601. The process was patented in England by William Ellyot and Mathias Meysey in 1614. At that date, the "invention" could consist merely of the introduction of a new industry or product, or even a mere monopoly. They evidently soon transferred the patent to Sir Basil Brooke, but he was forced to surrender it in 1619. A clause in the patent prohibiting the import of steel was found to be ...
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Iron Age
The Iron Age is the final epoch of the three-age division of the prehistory and protohistory of humanity. It was preceded by the Stone Age ( Paleolithic, Mesolithic, Neolithic) and the Bronze Age ( Chalcolithic). The concept has been mostly applied to Iron Age Europe and the Ancient Near East, but also, by analogy, to other parts of the Old World. The duration of the Iron Age varies depending on the region under consideration. It is defined by archaeological convention. The "Iron Age" begins locally when the production of iron or steel has advanced to the point where iron tools and weapons replace their bronze equivalents in common use. In the Ancient Near East, this transition took place in the wake of the Bronze Age collapse, in the 12th century BC. The technology soon spread throughout the Mediterranean Basin region and to South Asia (Iron Age in India) between the 12th and 11th century BC. Its further spread to Central Asia, Eastern Europe, and Central Europe is ...
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Metallurgical Assay
A metallurgical assay is a compositional analysis of an ore, metal, or alloy, usually performed in order to test for purity or quality. Some assay methods are suitable for raw materials; others are more appropriate for finished goods. Raw precious metals (bullion) are assayed by an assay office. Silver is assayed by titration, gold by cupellation and platinum by inductively coupled plasma optical emission spectrometry (ICP OES). Precious metal items of art or jewelry are frequently hallmarked (depending upon the requirements of the laws of either the place of manufacture or the place of import). Where required to be hallmarked, semi-finished precious metal items of art or jewelry pass through the official testing channels where they are analyzed or assayed for precious metal content. While different nations permit a variety of legally acceptable finenesses, the assayer is actually testing to determine that the fineness of the product conforms with the statement or claim of ...
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Refractory
In materials science, a refractory material or refractory is a material that is resistant to decomposition by heat, pressure, or chemical attack, and retains strength and form at high temperatures. Refractories are polycrystalline, polyphase, inorganic, non-metallic, porous, and heterogeneous. They are typically composed of oxides or carbides, nitrides etc. of the following materials: silicon, aluminium, magnesium, calcium, boron, chromium and zirconium. ASTM C71 defines refractories as "...non-metallic materials having those chemical and physical properties that make them applicable for structures, or as components of systems, that are exposed to environments above ." Refractory materials are used in furnaces, kilns, incinerators, and reactors. Refractories are also used to make crucibles and moulds for casting glass and metals and for surfacing flame deflector systems for rocket launch structures. Today, the iron- and steel-industry and metal casting sectors use a ...
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Bronze Casting
Lost-wax casting (also called "investment casting", "precision casting", or ''cire perdue'' which has been adopted into English from the French, ) is the process by which a duplicate metal sculpture (often silver, gold, brass, or bronze) is cast from an original sculpture. Intricate works can be achieved by this method. The oldest known examples of this technique are approximately 6,500-year-old (4550–4450 BC) and attributed to gold artefacts found at Bulgaria's Varna Necropolis. A copper amulet from Mehrgarh, Indus Valley civilization, in Pakistan, is dated to circa 4,000 BC. Cast copper objects, found in the Nahal Mishmar hoard in southern Israel, which belong to the Chalcolithic period (4500–3500 BC), are estimated, from carbon-14 dating, to date to circa 3500 BC. In Other examples from somewhat later periods are from Mesopotamia in the third millennium BC. Lost-wax casting was widespread in Europe until the 18th century, when a piece-moulding process came to ...
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Cupellation
Cupellation is a refining process in metallurgy where ores or alloyed metals are treated under very high temperatures and have controlled operations to separate noble metals, like gold and silver, from base metals, like lead, copper, zinc, arsenic, antimony, or bismuth, present in the ore. The process is based on the principle that precious metals do not oxidise or react chemically, unlike base metals. When they are heated at high temperatures, the precious metals remain apart, and the others react, forming slags or other compounds.Bayley, J. 2008 Since the Early Bronze Age, the process was used to obtain silver from smelted lead ores.Rehren, Th., Eckstein, K. 2002 By the Middle Ages and the Renaissance, cupellation was one of the most common processes for refining precious metals. By then, fire assays were used for assaying minerals: testing fresh metals such as lead and recycled metals to know their purity for jewellery and coin making. Cupellation is still in use today.Hoove ...
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Ceramic
A ceramic is any of the various hard, brittle, heat-resistant and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcelain, and brick. The earliest ceramics made by humans were pottery objects (''pots,'' ''vessels or vases'') or figurines made from clay, either by itself or mixed with other materials like silica, hardened and sintered in fire. Later, ceramics were glazed and fired to create smooth, colored surfaces, decreasing porosity through the use of glassy, amorphous ceramic coatings on top of the crystalline ceramic substrates. Ceramics now include domestic, industrial and building products, as well as a wide range of materials developed for use in advanced ceramic engineering, such as in semiconductors. The word "'' ceramic''" comes from the Greek word (), "of pottery" or "for pottery", from (), "potter's clay, tile, pottery". The earliest kno ...
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