Thorium-232 () is the main naturally occurring

isotope Isotopes are distinct nuclear species (or ''nuclides'') of the same chemical element. They have the same atomic number (number of protons in their Atomic nucleus, nuclei) and position in the periodic table (and hence belong to the same chemica ...

thorium Thorium is a chemical element; it has symbol Th and atomic number 90. Thorium is a weakly radioactive light silver metal which tarnishes olive grey when it is exposed to air, forming thorium dioxide; it is moderately soft, malleable, and ha ...

, with a relative abundance of 99.98%. It has a half life of 14.05 billion years, which makes it the longest-lived isotope of thorium. It decays by

alpha decay Alpha decay or α-decay is a type of radioactive decay in which an atomic nucleus emits an alpha particle (helium nucleus). The parent nucleus transforms or "decays" into a daughter product, with a mass number that is reduced by four and an a ...

to radium-228; its

decay chain In nuclear science a decay chain refers to the predictable series of radioactive disintegrations undergone by the nuclei of certain unstable chemical elements. Radioactive isotopes do not usually decay directly to stable isotopes, but rather ...

terminates at stable

lead-208 Lead (82Pb) has four observationally stable isotopes: 204Pb, 206Pb, 207Pb, 208Pb. Lead-204 is entirely a primordial nuclide and is not a radiogenic nuclide. The three isotopes lead-206, lead-207, and lead-208 represent the ends of three decay ...

. Thorium-232 is a fertile material; it can capture a neutron to form thorium-233, which subsequently undergoes two successive

beta decay In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which an atomic nucleus emits a beta particle (fast energetic electron or positron), transforming into an isobar of that nuclide. For example, beta decay of a neutron ...

s to

uranium-233 Uranium-233 ( or U-233) is a fissile isotope of uranium that is bred from thorium-232 as part of the thorium fuel cycle. Uranium-233 was investigated for use in nuclear weapons and as a Nuclear fuel, reactor fuel. It has been used successfully ...

, which is

fissile In nuclear engineering, fissile material is material that can undergo nuclear fission when struck by a neutron of low energy. A self-sustaining thermal Nuclear chain reaction#Fission chain reaction, chain reaction can only be achieved with fissil ...

. As such, it has been used in the thorium fuel cycle in nuclear reactors; various prototype thorium-fueled reactors have been designed. However, as of 2024, thorium fuel has not been widely adopted for commercial-scale nuclear power.

Natural occurrence

The

half-life Half-life is a mathematical and scientific description of exponential or gradual decay. Half-life, half life or halflife may also refer to: Film * Half-Life (film), ''Half-Life'' (film), a 2008 independent film by Jennifer Phang * ''Half Life: ...

of thorium-232 (14 billion years) is more than three times the

age of the Earth The age of Earth is estimated to be 4.54 ± 0.05 billion years. This age may represent the age of Earth's accretion (astrophysics), accretion, or Internal structure of Earth, core formation, or of the material from which Earth formed. This dating ...

; thorium-232 therefore occurs in nature as a primordial nuclide. Other thorium isotopes occur in nature in much smaller quantities as intermediate products in the

s of uranium-238,

uranium-235 Uranium-235 ( or U-235) is an isotope of uranium making up about 0.72% of natural uranium. Unlike the predominant isotope uranium-238, it is fissile, i.e., it can sustain a nuclear chain reaction. It is the only fissile isotope that exists in nat ...

, and thorium-232. Some minerals that contain thorium include

apatite Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of Hydroxide, OH−, Fluoride, F− and Chloride, Cl− ion, respectively, in the crystal. The formula of the admixture of ...

, sphene, zircon, allanite, monazite, pyrochlore, thorite, and xenotime.

Decay

Thorium-232 has a half-life of 14 billion years and mainly decays by

to radium-228 with a decay energy of 4.0816 MeV. The decay chain follows the thorium series, which terminates at stable

. The intermediates in the thorium-232 decay chain are all relatively short-lived; the longest-lived intermediate decay products are radium-228 and thorium-228, with half lives of 5.75 years and 1.91 years, respectively. All other intermediate decay products have half lives of less than four days. The following table lists the intermediate decay products in the thorium-232 decay chain:

Rare decay modes

Although thorium-232 mainly decays by alpha decay, it also undergoes spontaneous fission 1.1% of the time. In addition, it is capable of

cluster decay Cluster decay, also named heavy particle radioactivity, heavy ion radioactivity or heavy cluster decay," is a rare type of nuclear decay in which an atomic nucleus emits a small "cluster" of neutrons and protons, more than in an alpha particle, ...

, splitting into ytterbium-182, neon-24, and neon-26; the upper limit for the branching ratio of this decay mode is 2.78%.

Double beta decay In nuclear physics, double beta decay is a type of radioactive decay in which two neutrons are simultaneously transformed into two protons, or vice versa, inside an atomic nucleus. As in single beta decay, this process allows the atom to move cl ...

to uranium-232 is also theoretically possible, but has not been observed.

Use in nuclear power

Thorium-232 is not

; it therefore cannot be used directly as fuel in

nuclear reactor A nuclear reactor is a device used to initiate and control a Nuclear fission, fission nuclear chain reaction. They are used for Nuclear power, commercial electricity, nuclear marine propulsion, marine propulsion, Weapons-grade plutonium, weapons ...

s. However, is fertile: it can capture a neutron to form , which undergoes

with a half-life of 21.8 minutes to . This nuclide subsequently undergoes beta decay with a half-life of 27 days to form

. One potential advantage of a thorium-based nuclear fuel cycle is that thorium is three times more abundant than

uranium Uranium is a chemical element; it has chemical symbol, symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Ura ...

, the current fuel for commercial nuclear reactors. It is also more difficult to produce material suitable for

nuclear weapon A nuclear weapon is an explosive device that derives its destructive force from nuclear reactions, either fission (fission or atomic bomb) or a combination of fission and fusion reactions (thermonuclear weapon), producing a nuclear exp ...

s from the thorium fuel cycle compared to the uranium fuel cycle. Some proposed designs for thorium-fueled nuclear reactors include the molten salt reactor and a fast neutron reactor, among others. Although thorium-based nuclear reactors have been proposed since the 1960s and several prototype reactors have been built, there has been relatively little research on the thorium fuel cycle compared to the more established uranium fuel cycle; thorium-based nuclear power has not seen large-scale commercial use as of 2024. Nevertheless, some countries such as

India India, officially the Republic of India, is a country in South Asia. It is the List of countries and dependencies by area, seventh-largest country by area; the List of countries by population (United Nations), most populous country since ...

have actively pursued thorium-based nuclear power.

References

{{Isotope sequence , element=thorium , lighter= thorium-231 , heavier= thorium-233 , before=

uranium-236 Uranium-236 ( or U-236) is an isotope of uranium that is neither fissile with thermal neutrons, nor very good fertile material, but is generally considered a nuisance and long-lived radioactive waste. It is found in spent nuclear fuel and in ...

actinium-232 , after= radium-228 Actinides Isotopes of thorium Fertile materials IARC Group 1 carcinogens Radionuclides used in radiometric dating