HOME

TheInfoList



OR:

In metallurgy and materials science, annealing is a
heat treatment Heat treating (or heat treatment) is a group of industrial process, industrial, thermal and metalworking, metalworking processes used to alter the physical property, physical, and sometimes chemical property, chemical, properties of a material. ...
that alters the physical and sometimes chemical properties of a material to increase its
ductility Ductility is a mechanical property commonly described as a material's amenability to drawing (e.g. into wire). In materials science, ductility is defined by the degree to which a material can sustain plastic deformation under tensile str ...
and reduce its
hardness In materials science, hardness (antonym: softness) is a measure of the resistance to localized plastic deformation induced by either mechanical indentation or abrasion. In general, different materials differ in their hardness; for example hard ...
, making it more workable. It involves heating a material above its recrystallization temperature, maintaining a suitable temperature for an appropriate amount of time and then cooling. In annealing, atoms migrate in the crystal lattice and the number of dislocations decreases, leading to a change in ductility and hardness. As the material cools it recrystallizes. For many alloys, including carbon steel, the crystal grain size and phase composition, which ultimately determine the material properties, are dependent on the heating rate and cooling rate. Hot working or cold working after the annealing process alters the metal structure, so further
heat treatment Heat treating (or heat treatment) is a group of industrial process, industrial, thermal and metalworking, metalworking processes used to alter the physical property, physical, and sometimes chemical property, chemical, properties of a material. ...
s may be used to achieve the properties required. With knowledge of the composition and phase diagram,
heat treatment Heat treating (or heat treatment) is a group of industrial process, industrial, thermal and metalworking, metalworking processes used to alter the physical property, physical, and sometimes chemical property, chemical, properties of a material. ...
can be used to adjust from harder and more brittle to softer and more ductile. In the case of
ferrous metals In chemistry, the adjective Ferrous indicates a compound that contains iron(II), meaning iron in its +2 oxidation state, possibly as the divalent cation Fe2+. It is opposed to "ferric" or iron(III), meaning iron in its +3 oxidation state, such a ...
, such as steel, annealing is performed by heating the material (generally until glowing) for a while and then slowly letting it cool to room temperature in still air.
Copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...
,
silver Silver is a chemical element with the symbol Ag (from the Latin ', derived from the Proto-Indo-European ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, white, lustrous transition metal, it exhibits the highest electrical ...
and
brass Brass is an alloy of copper (Cu) and zinc (Zn), in proportions which can be varied to achieve different mechanical, electrical, and chemical properties. It is a substitutional alloy: atoms of the two constituents may replace each other wit ...
can be either cooled slowly in air, or quickly by
quenching In materials science, quenching is the rapid cooling of a workpiece in water, oil, polymer, air, or other fluids to obtain certain material properties. A type of heat treating, quenching prevents undesired low-temperature processes, such as pha ...
in water. In this fashion, the metal is softened and prepared for further work such as shaping, stamping, or forming.


Thermodynamics

Annealing occurs by the
diffusion Diffusion is the net movement of anything (for example, atoms, ions, molecules, energy) generally from a region of higher concentration to a region of lower concentration. Diffusion is driven by a gradient in Gibbs free energy or chemica ...
of atoms within a solid material, so that the material progresses towards its equilibrium state. Heat increases the rate of diffusion by providing the energy needed to break bonds. The movement of atoms has the effect of redistributing and eradicating the
dislocations In materials science, a dislocation or Taylor's dislocation is a linear crystallographic defect or irregularity within a crystal structure that contains an abrupt change in the arrangement of atoms. The movement of dislocations allow atoms to sl ...
in metals and (to a lesser extent) in ceramics. This alteration to existing dislocations allows a metal object to deform more easily, increasing its ductility. The amount of process-initiating
Gibbs free energy In thermodynamics, the Gibbs free energy (or Gibbs energy; symbol G) is a thermodynamic potential that can be used to calculate the maximum amount of work that may be performed by a thermodynamically closed system at constant temperature and ...
in a deformed metal is also reduced by the annealing process. In practice and industry, this reduction of Gibbs free energy is termed ''stress relief''. The relief of internal stresses is a thermodynamically
spontaneous process In thermodynamics, a spontaneous process is a process which occurs without any external input to the system. A more technical definition is the time-evolution of a system in which it releases free energy and it moves to a lower, more thermodynamic ...
; however, at room temperatures, it is a very slow process. The high temperatures at which annealing occurs serve to accelerate this process. The reaction that facilitates returning the cold-worked metal to its stress-free state has many reaction pathways, mostly involving the elimination of lattice vacancy gradients within the body of the metal. The creation of lattice vacancies is governed by the
Arrhenius equation In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates. The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1 ...
, and the migration/diffusion of lattice vacancies are governed by Fick's laws of diffusion. In steel, there is a decarburation mechanism that can be described as three distinct events: the reaction at the steel surface, the interstitial diffusion of carbon atoms and the dissolution of carbides within the steel.


Stages

The three stages of the annealing process that proceed as the temperature of the material is increased are: recovery, recrystallization, and grain growth. The first stage is recovery, and it results in softening of the metal through removal of primarily linear defects called ''dislocations'' and the internal stresses they cause. Recovery occurs at the lower temperature stage of all annealing processes and before the appearance of new strain-free grains. The grain size and shape do not change.Verhoeven, J.D. ''Fundamentals of Physical Metallurgy'', Wiley, New York, 1975, p. 326 The second stage is recrystallization, where new strain-free grains
nucleate In thermodynamics, nucleation is the first step in the formation of either a new thermodynamic phase or structure via self-assembly or self-organization within a substance or mixture. Nucleation is typically defined to be the process that dete ...
and grow to replace those deformed by internal stresses. If annealing is allowed to continue once recrystallization has completed, then
grain growth In materials science, grain growth is the increase in size of grains (crystallites) in a material at high temperature. This occurs when recovery and recrystallisation are complete and further reduction in the internal energy can only be achieved ...
(the third stage) occurs. In grain growth, the microstructure starts to coarsen and may cause the metal to lose a substantial part of its original strength. This can however be regained with hardening.


Controlled atmospheres

The high temperature of annealing may result in oxidation of the metal's surface, resulting in scale. If scale must be avoided, annealing is carried out in a special atmosphere, such as with
endothermic gas Endothermic gas is a gas that inhibits or reverses oxidation on the surfaces it is in contact with. This gas is the product of incomplete combustion in a controlled environment. An example mixture is hydrogen gas (H2), nitrogen gas (N2), and carbo ...
(a mixture of
carbon monoxide Carbon monoxide (chemical formula CO) is a colorless, poisonous, odorless, tasteless, flammable gas that is slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simple ...
,
hydrogen gas Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic, a ...
, and
nitrogen gas Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at seventh ...
). Annealing is also done in
forming gas Forming gas is a mixture of hydrogen (mole fraction varies) and nitrogen. It is sometimes called a "dissociated ammonia atmosphere" due to the reaction which generates it: :2 NH3 → 3 H2 + N2 It can also be manufactured by thermal cra ...
, a mixture of hydrogen and nitrogen. The
magnet A magnet is a material or object that produces a magnetic field. This magnetic field is invisible but is responsible for the most notable property of a magnet: a force that pulls on other ferromagnetic materials, such as iron, steel, nicke ...
ic properties of mu-metal (Espey cores) are introduced by annealing the alloy in a hydrogen atmosphere.


Setup and equipment

Typically, large ovens are used for the annealing process. The inside of the oven is large enough to place the workpiece in a position to receive maximum exposure to the circulating heated air. For high volume process annealing, gas fired conveyor furnaces are often used. For large workpieces or high quantity parts, car-bottom furnaces are used so workers can easily move the parts in and out. Once the annealing process is successfully completed, workpieces are sometimes left in the oven so the parts cool in a controllable way. While some workpieces are left in the oven to cool in a controlled fashion, other materials and alloys are removed from the oven. Once removed from the oven, the workpieces are often quickly cooled off in a process known as quench hardening. Typical methods of quench hardening materials involve media such as air, water, oil, or salt. Salt is used as a medium for quenching usually in the form of brine (salt water). Brine provides faster cooling rates than water. This is because when an object is quenched in water steam bubbles form on the surface of the object reducing the surface area the water is in contact with. The salt in the brine reduces the formation of steam bubbles on the object's surface, meaning there is a larger surface area of the object in contact with the water, providing faster cooling rates. Quench hardening is generally applicable to some ferrous alloys, but not copper alloys.


Diffusion annealing of semiconductors

In the
semiconductor A semiconductor is a material which has an electrical conductivity value falling between that of a conductor, such as copper, and an insulator, such as glass. Its resistivity falls as its temperature rises; metals behave in the opposite way. ...
industry,
silicon Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic ta ...
wafers are annealed to repair atomic level disorder from steps like
ion implantation Ion implantation is a low-temperature process by which ions of one element are accelerated into a solid target, thereby changing the physical, chemical, or electrical properties of the target. Ion implantation is used in semiconductor device fa ...
. In the process step,
dopant A dopant, also called a doping agent, is a trace of impurity element that is introduced into a chemical material to alter its original electrical or optical properties. The amount of dopant necessary to cause changes is typically very low. When ...
atoms, usually boron,
phosphorus Phosphorus is a chemical element with the symbol P and atomic number 15. Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Ear ...
or
arsenic Arsenic is a chemical element with the symbol As and atomic number 33. Arsenic occurs in many minerals, usually in combination with sulfur and metals, but also as a pure elemental crystal. Arsenic is a metalloid. It has various allotropes, ...
, move into substitutional positions in the crystal lattice, which allows these dopant atoms to function properly as dopants in the semiconducting material.


Specialized cycles


Normalization

''Normalization'' is an annealing process applied to ferrous alloys to give the material a uniform fine-grained structure and to avoid excess softening in steel. It involves heating the steel to 20–50 °C above its upper critical point, soaking it for a short period at that temperature and then allowing it to cool in air. Heating the steel just above its upper critical point creates austenitic grains (much smaller than the previous ferritic grains), which during cooling, form new ferritic grains with a further refined grain size. The process produces a tougher, more ductile material, and eliminates columnar grains and dendritic segregation that sometimes occurs during casting. Normalizing improves
machinability Machinability is the ease with which a metal can be cut (machined) permitting the removal of the material with a satisfactory finish at low cost.Degarmo, p. 542. Materials with good machinability (free machining materials) require little power to c ...
of a component and provides dimensional stability if subjected to further heat treatment processes.


Process annealing

Process annealing, also called ''intermediate annealing'', ''subcritical annealing'', or ''in-process annealing'', is a heat treatment cycle that restores some of the ductility to a product being cold-worked so it can be cold-worked further without breaking. The temperature range for process annealing ranges from 260 °C (500 °F) to 760 °C (1400 °F), depending on the alloy in question. This process is mainly suited for low-carbon steel. The material is heated up to a temperature just below the lower critical temperature of steel. Cold-worked steel normally tends to possess increased hardness and decreased ductility, making it difficult to work. Process annealing tends to improve these characteristics. This is mainly carried out on cold-rolled steel like wire-drawn steel, centrifugally cast ductile iron pipe etc.


Full annealing

A full annealing typically results in the second most ductile state a metal can assume for metal alloy. Its purpose is to originate a uniform and stable microstructure that most closely resembles the metal's phase diagram equilibrium microstructure, thus letting the metal attain relatively low levels of hardness, yield strength and ultimate strength with high plasticity and toughness. To perform a full anneal on a steel for example, steel is heated to slightly above the austenitic temperature and held for sufficient time to allow the material to fully form
austenite Austenite, also known as gamma-phase iron (γ-Fe), is a metallic, non-magnetic allotrope of iron or a solid solution of iron with an alloying element. In plain-carbon steel, austenite exists above the critical eutectoid temperature of 1000 K ...
or austenite-cementite grain structure. The material is then allowed to cool very slowly so that the equilibrium microstructure is obtained. In most cases this means the material is allowed to furnace cool (the furnace is turned off and the steel is let cool down inside) but in some cases it is air cooled. The cooling rate of the steel has to be sufficiently slow so as to not let the
austenite Austenite, also known as gamma-phase iron (γ-Fe), is a metallic, non-magnetic allotrope of iron or a solid solution of iron with an alloying element. In plain-carbon steel, austenite exists above the critical eutectoid temperature of 1000 K ...
transform into
bainite Bainite is a plate-like microstructure that forms in steels at temperatures of 125–550 °C (depending on alloy content). First described by E. S. Davenport and Edgar Bain, it is one of the products that may form when austenite (the face-c ...
or
martensite Martensite is a very hard form of steel crystalline structure. It is named after German metallurgist Adolf Martens. By analogy the term can also refer to any crystal structure that is formed by diffusionless transformation. Properties M ...
, but rather have it completely transform to
pearlite Pearlite is a two-phased, lamellar (or layered) structure composed of alternating layers of ferrite (87.5 wt%) and cementite (12.5 wt%) that occurs in some steels and cast irons. During slow cooling of an iron-carbon alloy, pearlite form ...
and ferrite or
cementite Cementite (or iron carbide) is a compound of iron and carbon, more precisely an intermediate transition metal carbide with the formula Fe3C. By weight, it is 6.67% carbon and 93.3% iron. It has an orthorhombic crystal structure. It is a hard, bri ...
. This means that steels that are very hardenable (i.e. tend to form martensite under moderately low cooling rates) have to be furnace cooled. The details of the process depend on the type of metal and the precise alloy involved. In any case the result is a more ductile material but a lower
yield strength In materials science and engineering, the yield point is the point on a stress-strain curve that indicates the limit of elastic behavior and the beginning of plastic behavior. Below the yield point, a material will deform elastically and ...
and a lower
tensile strength Ultimate tensile strength (UTS), often shortened to tensile strength (TS), ultimate strength, or F_\text within equations, is the maximum stress that a material can withstand while being stretched or pulled before breaking. In brittle materials t ...
. This process is also called LP annealing for ''lamellar pearlite'' in the steel industry as opposed to a ''process anneal'', which does not specify a microstructure and only has the goal of softening the material. Often the material to be machined is annealed, and then subject to further heat treatment to achieve the final desired properties.


Short cycle anneal

Short cycle annealing is used for turning normal ferrite into malleable ferrite. It consists of heating, cooling and then heating again from 4 to 8 hours.


Resistive heating

Resistive heating can be used to efficiently anneal
copper wire Copper has been used in electrical wiring since the invention of the electromagnet and the telegraph in the 1820s. The invention of the telephone in 1876 created further demand for copper wire as an electrical conductor. Copper is the electri ...
; the heating system employs a controlled electrical
short circuit A short circuit (sometimes abbreviated to short or s/c) is an electrical circuit that allows a current to travel along an unintended path with no or very low electrical impedance. This results in an excessive current flowing through the circui ...
. It can be advantageous because it does not require a
temperature Temperature is a physical quantity that expresses quantitatively the perceptions of hotness and coldness. Temperature is measurement, measured with a thermometer. Thermometers are calibrated in various Conversion of units of temperature, temp ...
-regulated furnace like other methods of annealing. The process consists of two conductive pulleys (''step pulleys''), which the wire passes across after it is drawn. The two pulleys have an
electrical potential The electric potential (also called the ''electric field potential'', potential drop, the electrostatic potential) is defined as the amount of work energy needed to move a unit of electric charge from a reference point to the specific point in ...
across them, which causes the wire to form a short circuit. The
Joule effect Joule effect and Joule's law are any of several different physical effects discovered or characterized by English physicist James Prescott Joule. These physical effects are not the same, but all are frequently or occasionally referred to in the lit ...
causes the temperature of the wire to rise to approximately 400 °C. This temperature is affected by the rotational speed of the pulleys, the ambient temperature, and the voltage applied. Where ''t'' is the temperature of the wire, ''K'' is a constant, ''V'' is the
voltage Voltage, also known as electric pressure, electric tension, or (electric) potential difference, is the difference in electric potential between two points. In a static electric field, it corresponds to the work needed per unit of charge to ...
applied, ''r'' is the number of rotations of the pulleys per minute, and ''t''''a'' is the ambient temperature, :t = \frac KV^2 + t_a. The constant ''K'' depends on the diameter of the pulleys and the resistivity of the copper. Purely in terms of the temperature of the copper wire, an increase in the speed of the wire through the pulley system has the same effect as a decrease in resistance.


See also

*
Annealing (glass) Annealing is a process of slowly cooling hot glass objects after they have been formed, to relieve residual internal stresses introduced during manufacture. Especially for smaller, simpler objects, annealing may be incidental to the process of ...
* Annealing by short circuit * Hollomon–Jaffe parameter * Low hydrogen annealing *
Simulated annealing Simulated annealing (SA) is a probabilistic technique for approximating the global optimum of a given function. Specifically, it is a metaheuristic to approximate global optimization in a large search space for an optimization problem. ...
*
Tempering (metallurgy) Tempering is a process of heat treating, which is used to increase the toughness of iron-based alloys. Tempering is usually performed after hardening, to reduce some of the excess hardness, and is done by heating the metal to some temperature be ...


References


Further reading

* Thesis of Degree, ''Cable Manufacture and Tests of General Use and Energy''. Jorge Luis Pedraz (1994), UNI, Files, Peru. * "Dynamic annealing of the Copper wire by using a Controlled Short circuit." Jorge Luis Pedraz (1999), Peru: Lima, CONIMERA 1999, INTERCON 99,


External links


Annealing
– efunda – engineering fundamentals
Annealing
– Aluminum and Aircraft Metal Alloys {{DEFAULTSORT:Annealing (Metallurgy) Metal heat treatments