The state postulate is a term used in
thermodynamics that defines the given number of properties to a
thermodynamic system
A thermodynamic system is a body of matter and/or radiation, confined in space by walls, with defined permeabilities, which separate it from its surroundings. The surroundings may include other thermodynamic systems, or physical systems that are ...
in a state of
equilibrium. It is also sometimes referred to as the state principle.
The state postulate allows a finite number of properties to be specified in order to fully describe a state of thermodynamic equilibrium. Once the state postulate is given the other unspecified properties must assume certain values.
The state postulate says:
A more general statement of the state postulate says:
''the state of a simple system is completely specified by r+1 independent, intensive properties where r is the number of significant work interactions.
''
A system is considered to be a simple compressible one in the absence of certain effects which are uncommon in many engineering applications. These are electromagnetic and gravitational fields, surface tension, and motion. For such a system, only two independent
intensive variable
Physical properties of materials and systems can often be categorized as being either intensive or extensive, according to how the property changes when the size (or extent) of the system changes. According to IUPAC, an intensive quantity is one ...
s are sufficient to derive all the others by use of an
equation of state. In the case of a more complex system, additional variables must be measured in order to solve for the complete state. For example, if gravitation is significant then an elevation may be required.
Two properties are considered independent if one can be varied while the other is held constant. For example, temperature and specific volume are always independent. However, temperature and pressure are independent only for a single-phase system; for a
multiphase system (such as a mixture of gas and liquid) this is not the case. (e.g., boiling point (temperature) depends on elevation (ambient pressure)).
See also
*
Gibbs' phase rule
In thermodynamics, the phase rule is a general principle governing "pVT" systems, whose thermodynamic states are completely described by the variables pressure (), volume () and temperature (), in thermodynamic equilibrium. If is the number of ...
References
Thermodynamics
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