Spiegeleisen (literally "mirror-iron", —

mirror A mirror or looking glass is an object that reflects an image. Light that bounces off a mirror will show an image of whatever is in front of it, when focused through the lens of the eye or a camera. Mirrors reverse the direction of the im ...

specular Specular reflection, or regular reflection, is the mirror-like reflection of waves, such as light, from a surface. The law of reflection states that a reflected ray of light emerges from the reflecting surface at the same angle to the surfac ...

; —

iron Iron () is a chemical element with Symbol (chemistry), symbol Fe (from la, Wikt:ferrum, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 element, group 8 of the periodic table. It is, Abundanc ...

) is a

ferromanganese Ferromanganese is a ferroalloy with high manganese content (high-carbon ferromanganese can contain as much as 80% Mn by weight). It is made by heating a mixture of the oxides MnO2 and Fe2O3, with carbon (usually as coal and coke) in either a bla ...

alloy An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductilit ...

containing approximately 15%

manganese Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy use ...

and small quantities of

carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon mak ...

and

silicon Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic ta ...

. Spiegeleisen is sometimes also referred to as ''specular pig iron'', ''Spiegel iron'', just ''Spiegel'', or ''Bisalloy''.

Usage

Historically, this was the standard form in which manganese was traded and used in

steel making Steelmaking is the process of producing steel from iron ore and carbon/or scrap. In steelmaking, impurities such as nitrogen, silicon, phosphorus, sulfur and excess carbon (the most important impurity) are removed from the sourced iron, and alloy ...

. Manganese is useful in steel manufacture because it binds with

phosphorus Phosphorus is a chemical element with the symbol P and atomic number 15. Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Ear ...

, sulfur, and

silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is ...

, removing them (to a degree) from the iron. It was much used in conjunction with the

Bessemer process The Bessemer process was the first inexpensive industrial process for the mass production of steel from molten pig iron before the development of the open hearth furnace. The key principle is removal of impurities from the iron by oxidation ...

both to introduce carbon and manganese, and also to reduce impurities.

Manufacture

In the 19th-century spiegeleisen was made either by mixing iron ores with appropriate levels of manganese and smelting them directly, or by adding pyrolusite or

manganite Manganite is a mineral composed of manganese oxide-hydroxide, MnO(OH), crystallizing in the monoclinic system (pseudo-orthorhombic). Crystals of manganite are prismatic and deeply striated parallel to their length; they are often grouped togethe ...

to previously smelted iron in a

cupellation furnace Cupellation is a Refining (metallurgy), refining process in metallurgy where ores or alloyed metals are treated under very high temperatures and have controlled operations to separate noble metals, like gold and silver, from base metals, like lea ...

. Today, manganese is usually traded and used in more concentrated form, 80% manganese content being typical.

References

{{Alloy-stub Ferrous alloys Manganese

Usage

Manufacture

See also

References